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Ta có: \(n_{H_2}=\dfrac{1,344}{22,4}=0,06\left(mol\right)\)
PTHH:
2Al + 6HCl ---> 2AlCl3 + 3H2 (1)
Al2O3 + 6HCl ---> 2AlCl3 + 3H2 (2)
Theo PT(1): \(n_{Al}=\dfrac{2}{3}.n_{H_2}=\dfrac{2}{3}.0,06=0,04\left(mol\right)\)
\(\Rightarrow m_{Al}=0,04.27=1,08\left(g\right)\)
\(\Rightarrow m_{Al_2O_3}=2,1-1,08=1,02\left(g\right)\)
\(\Rightarrow n_{Al_2O_3}=\dfrac{1,02}{102}=0,01\left(mol\right)\)
Theo PT(1): \(n_{HCl}=3.n_{Al}=3.0,04=0,12\left(mol\right)\)
Theo PT(2): \(n_{HCl}=6.n_{Al_2O_3}=6.0,01=0,06\left(mol\right)\)
\(\Rightarrow m_{HCl}=\left(0,06+0,12\right).36,5=6,57\left(g\right)\)
Ta có: \(C_{\%_{HCl}}=\dfrac{6,57}{m_{dd_{HCl}}}.100\%=7,3\%\)
\(\Rightarrow m_{dd_{HCl}}=90\left(g\right)\)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1(mol)\\ Mg+2HCl\to MgCl_2+H_2\\ MgO+2HCl\to MgCl_2+H_2O\\ \Rightarrow n_{Mg}=0,1(mol)\\ \Rightarrow \%_{Mg}=\dfrac{0,1.24}{6,4}.100\%=37,5\%\\ \Rightarrow \%_{MgO}=100\%-37,5\%=62,5\%\)
\(b,n_{MgO}=\dfrac{6,4-0,1.24}{40}=0,1(mol)\\ \Rightarrow n_{HCl}=2.0,1+2.0,1=0,4(mol)\\ \Rightarrow V_{dd_{HCl}}=\dfrac{0,4}{0,5}=0,8(l)\\ c,n_{MgCl_2}=0,1+0,1=0,2(mol)\\ \Rightarrow C_{M_{MgCl_2}}=\dfrac{0,2}{0,8}=0,25M\)
1.1. Al + NaOH + H2O ==> NaAlO2 + 3/2H2
nH2(1)=3,36/22,4=0.15(mol)
=> nAl(1)= nH2(1):3/2= 0.15:3/2= 0.1(mol)
2.Mg + 2HCl ==> MgCl2 + H2
3.2Al + 6HCl ==> 2AlCl3 + 3H2
4.Fe + 2HCl ==> FeCl2 + H2
=> \(n_{H_2\left(2,3,4\right)}=\) 10.08/22.4= 0.45(mol)
=> nH2(3)=0.1*3/2=0.15(mol)
MgCl2 + 2NaOH ==> Mg(OH)2 + 2NaCl
AlCl3 + 3NaOH ==> Al(OH)3 + 3NaCl
FeCl2 + 2NaOH ==> Fe(OH)2 + 2NaCl
Vì Cu không tác dụng với dung dịch axit clohidric loãng :
\(n_{H2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Pt : \(Mg+2HCl\rightarrow MgCl_2+H_2|\)
1 2 1 1
0,2 0,2
\(n_{Mg}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
\(m_{Mg}=0,2.24=4,8\left(g\right)\)
\(m_{Cu}=6-4,8=1,2\left(g\right)\)
Chúc bạn học tốt
2al+ 6hcl-> 2alcl3+3h2
a-> 3a a 1,5a
fe+2hcl-> fecl2+h2
b->2b b b
27a+56b= 5,5
1,5a+b=4,48/22,4
=> a=0,1; b=0,05
=> %mal=0,1*27/5,5*100=49,09%
=>%mfe= 100-49,09=50,9%
mhcl= 3a+2b= 3*0,1+2*0,05=0,4
=>mddhcl= 0,4*36,5*100/14,6=100g
-> vddhcl=100/ 1,08=92,592ml
mddsau pư= 5,5+100-0,2*2=105,1
C% alcl3= 133,5*0,1/105,1*100=12,7
Cfecl2= 127* 0,05/105,1*100=6,04
\(a,Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\\ n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ b,n_{Fe}=n_{H_2}=0,2\left(mol\right)\\ \%m_{Fe}=\dfrac{0,2.56}{12,8}.100\%=87,5\%\\ \%m_{Fe_2O_3}=100\%-87,5\%=12,5\%\\ c,n_{Fe_2O_3}=\dfrac{12,8-11,2}{160}=0,01\left(mol\right)\\ n_{H_2SO_4}=n_{Fe}+3n_{Fe_2O_3}=0,2+3.0,01=0,23\left(mol\right)\\ V_{ddH_2SO_4}=\dfrac{0,23}{0,46}=0,5\left(M\right)\)