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PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
Ta có: \(n_{H_2}=\dfrac{3,7185}{24,79}=0,15\left(mol\right)\)
a, \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,1\left(mol\right)\Rightarrow m_{Al}=0,1.27=2,7\left(g\right)\)
b, \(n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{3}n_{H_2}=0,05\left(mol\right)\)
\(\Rightarrow m_{Al_2\left(SO_4\right)_3}=0,05.342=17,1\left(g\right)\)
c, \(n_{H_2SO_4}=n_{H_2}=0,15\left(mol\right)\)
\(\Rightarrow V_{H_2SO_4}=\dfrac{0,15}{1,5}=0,1\left(l\right)=100\left(ml\right)\)
Fe+2HCl->FeCl2+H2
0,3----0,6--0,3------0,3
n H2=0,3 mol
=>m Fe=0,3.56=16.8g
=>CM=0,6\0,1=6M
CuO+H2-tO>Cu+H2O
0.3---------------0,3
=>m Cu=0,3.64=19,2g
a, \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
____0,1_____0,2______0,1_____0,1 (mol)
\(V_{H_2}=0,1.24,79=2,479\left(l\right)\)
\(m_{ZnCl_2}=0,1.136=13,6\left(g\right)\)
b, \(C_{M_{HCl}}=\dfrac{0,2}{0,1}=1\left(M\right)\)
c, \(n_{CuO}=\dfrac{12}{80}=0,15\left(mol\right)\)
PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Xét tỉ lệ: \(\dfrac{0,15}{1}>\dfrac{0,1}{1}\), ta được CuO dư.
Theo PT: \(n_{CuO\left(pư\right)}=n_{Cu}=n_{H_2}=0,1\left(mol\right)\Rightarrow n_{CuO\left(dư\right)}=0,05\left(mol\right)\)
⇒ m chất rắn = mCuO (dư) + mCu = 0,05.80 + 0,1.64 = 10,4 (g)
\(n_{Fe}=\dfrac{6,72}{56}=0,12\left(mol\right)\\ Fe+H_2SO_{4\left(loãng\right)}\rightarrow FeSO_4+H_2\uparrow\\ Mol:0,12\rightarrow0,12\rightarrow0,12\rightarrow0,12\\ V_{H_2}=0,12.22,4=2,688\left(l\right)\\ m_{FeSO_4}=0,12.152=18,24\left(g\right)\\ PTHH:Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\\ Mol:0,04\leftarrow0,12\rightarrow0,08\\ m_{Fe}=0,08.56=4,48\left(g\right)\)
\(a,Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ b,n_{FeSO_4}=n_{H_2SO_4}=n_{H_2}=n_{Fe}=\dfrac{44,8}{56}=0,8\left(mol\right)\\ m_{FeSO_4}=152.0,8=121,6\left(g\right)\\ m_{H_2}=0,8.2=1,6\left(g\right)\\ c,SO_3+H_2O\rightarrow H_2SO_4\\ m_{ddH_2SO_4}=0,8.98:10\%=784\left(g\right)\)