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Câu 4:
a, \(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PT: \(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
Theo PT: \(n_{CH_3COOH}=2n_{H_2}=0,5\left(mol\right)\Rightarrow V_{CH_3COOH}=\dfrac{0,5}{2,5}=0,2\left(l\right)\)
b, \(n_{\left(CH_3COO\right)_2Zn}=n_{H_2}=0,25\left(mol\right)\)
\(\Rightarrow m_{\left(CH_3COO\right)_2Zn}=0,25.183=45,75\left(g\right)\)
a)
2CH3COOH + Mg → (CH3COO)2Mg + H2
b)
nH2 = 0,448 : 22,4 = 0,02 mol
=> n(CH3COO)2Mg = 0,02 mol
<=> m(CH3COO)2Mg = 0,02.142 = 2,84 gam.
c) nCH3COOH = 2 nH2 = 0,04 mol
<=> mCH3COOH = 0,04 . 60 = 2,4 gam
=> C%CH3COOH = \(\dfrac{2,4}{40}.100\%\)= 6%
\(n_{CH_3COOH}=\dfrac{300\cdot5\%}{60}=0.25\left(mol\right)\)
\(2CH_3COOH+Zn\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
\(0.25........................................................0.125\)
\(V_{H_2}=0.125\cdot22.4=2.8\left(l\right)\)
\(n_{C_2H_5OH}=0.1\cdot2=0.2\left(mol\right)\)
\(CH_3COOH+C_2H_5OH⇌CH_3COOC_2H_5+H_2O\left(ĐK:H_2SO_{4\left(đ\right)},t^0\right)\)
\(0.2......................0.2.....................0.2\)
\(\Rightarrow CH_3COOHdư\)
\(m_{CH_3COOC_2H_5}=0.2\cdot88=17.6\left(g\right)\)
a) n CH3COOH = 300.5%/60 = 0,25(mol)
Zn + 2CH3COOH $\to$ (CH3COO)2Zn + H2
Theo PTHH :
n H2 = 1/2 n CH3COOH = 0,25/2 = 0,125(mol)
V H2 = 0,125.22,4 = 2,8(lít)
b) n C2H5OH = 0,1.2 = 0,2(mol)
\(CH_3COOH + C_2H_5OH \buildrel{{H_2SO_4,t^o}}\over\rightleftharpoons CH_3COOC_2H_5 + H_2O\)
Ta thấy :
n CH3COOH = 0,25 > n C2H5OH = 0,2 => CH3COOH dư
n CH3COOC2H5 = n C2H5OH = 0,2 mol
=> m CH3COOC2H5 = 0,2.88 = 17,6 gam
\(a) Zn +2 CH_3COOH \to (CH_3COO)_2Zn + H_2\\ b) n_{H_2} = n_{Zn} = \dfrac{13}{65} = 0,2(mol)\\ V_{H_2} = 0,2.22,4 = 4,48(lít)\\ n_{CH_3COOH} = 2n_{Zn} = 0,4(mol) \Rightarrow V_{dd\ CH_3COOH} = \dfrac{0,4}{1} = 0,4(lít)\\ c) C_2H_5OH + O_2 \xrightarrow{men\ giấm} CH_3COOH + H_2O\\ n_{C_2H_5OH\ pư} = n_{CH_3COOH} = 0,4(mol)\\ m_{C_2H_5OH\ cần dùng} = \dfrac{0,4.46}{90\%} = 20,44(gam)\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PT: \(Fe+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Fe+H_2\)
a, Theo PT: \(n_{CH_3COOH}=2n_{Fe}=0,2\left(mol\right)\Rightarrow m_{CH_3COOH}=0,2.60=12\left(g\right)\)
\(\Rightarrow m_{ddCH_3COOH}=\dfrac{12}{10\%}=120\left(g\right)\)
\(n_{H_2}=n_{Fe}=0,1\left(mol\right)\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, Theo PT: \(n_{\left(CH_3COO\right)_2Fe}=n_{Fe}=0,1\left(mol\right)\)
Ta có: m dd sau pư = 5,6 + 120 - 0,1.2 = 125,4 (g)
\(\Rightarrow C\%_{\left(CH_3COO\right)_2Fe}=\dfrac{0,1.174}{125,4}.100\%\approx13,88\%\)
a) \(n_{\left(CH_3COO\right)_2Mg}=\dfrac{7,1}{142}=0,05\left(mol\right)\)
PTHH: 2CH3COOH + Mg --> (CH3COO)2Mg + H2
0,1<----------------------0,05------->0,05
=> VH2 = 0,05.22,4 = 1,12 (l)
b) \(C_{M\left(dd.CH_3COOH\right)}=\dfrac{0,1}{0,025}=4M\)
a) \(n_{Na_2CO_3}=\dfrac{10,6}{106}=0,1\left(mol\right)\)
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
0,1-------->0,2------------->0,2
=> \(V_{dd.CH_3COOH}=\dfrac{0,2}{0,5}=0,4\left(l\right)\)
b) \(m_{CH_3COONa}=0,2.82=16,4\left(g\right)\)
a, \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
PT: \(2CH_3COOH+Zn\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
Theo PT: \(n_{H_2}=n_{Zn}=0,1\left(mol\right)\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, \(n_{\left(CH_3COO\right)_2Zn}=n_{Zn}=0,1\left(mol\right)\Rightarrow m_{\left(CH_3COO\right)_2Zn}=0,1.183=18,3\left(g\right)\)
c, \(n_{CH_3COOH}=2n_{Zn}=0,2\left(mol\right)\)
\(\Rightarrow m_{CH_3COOH}=0,2.60=12\left(g\right)\)
\(\Rightarrow m_{ddCH_3COOH}=\dfrac{12}{60\%}=20\left(g\right)\)
thanks