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mFe= 8,4/56= 0,15 mol
m HCl = 14,6/36,5=0,4 mol
PTHH: Fe +2HCl →FeCl2 +H2
Bđ: 0,15 0,4 0 0 mol
Pứ: o,15→0,3 0,15 0,15 mol
Sau pứ:0 0,1 0,15 0,15 mol
a. HCl dư: m =0,1.36,5=3,65 g
b. m FeCl2 = 0,15.127=19,05 g
c. m H2 = 0,15.2= 0,3 g
V H2= 0,15.22,4=3,36 (l)
\(a,n_{Zn}=\dfrac{0,65}{65}=0,01(mol)\\ n_{HCl}=\dfrac{7,3}{36,5}=0,2(mol)\\ PTHH:Zn+2HCl\to ZnCl_2+H_2\)
Vì \(\dfrac{n_{Zn}}{1}<\dfrac{n_{HCl}}{2}\) nên \(HCl\) dư
\(\Rightarrow n_{HCl(dư)}=0,2-0,02=0,18(mol)\\ \Rightarrow m_{HCl(dư)}=0,18.36,5=6,57(g)\\ b,n_{H_2}=n_{Zn}=0,01(mol)\\ \Rightarrow V_{H_2}=0,01.22,4=0,224(l)\)
a, PT: \(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
Ta có: \(n_{KClO_3}=\dfrac{24,5}{122,5}=0,2\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{3}{2}n_{KClO_3}=0,3\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,3.24,79=7,437\left(g\right)\)
b, PT: \(2Cu+O_2\underrightarrow{t^o}2CuO\)
Ta có: \(n_{Cu}=\dfrac{32}{64}=0,5\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,5}{2}< \dfrac{0,3}{1}\), ta được O2 dư.
Theo PT: \(\left\{{}\begin{matrix}n_{O_2\left(pư\right)}=\dfrac{1}{2}n_{Cu}=0,25\left(mol\right)\\n_{CuO}=n_{Cu}=0,5\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{O_2\left(dư\right)}=0,3-0,25=0,05\left(mol\right)\)
\(\Rightarrow m_{O_2\left(dư\right)}=0,05.32=1,6\left(g\right)\)
\(m_{CuO}=0,5.80=40\left(g\right)\)
\(n_{Na}=\dfrac{6,9}{23}=0,3\left(mol\right)\\ 2Na+2H_2O\rightarrow2NaOH+H_2\\ n_{H_2}=\dfrac{0,3}{2}=0,15\left(mol\right)\\ a,V_{H_2\left(đktc\right)}=0,15.22,4=3,36\left(l\right)\\ b,m_{ddsaup.ứ}=m_{Na}+m_{H_2O}-m_{H_2}=6,9+100-0,15.2=106,6\left(g\right)\)
Bài 1:
a) 2CuFeS2 + \(\dfrac{13}{2}\)O2 --to--> 2CuO + Fe2O3 + 4SO2
b) \(n_{CuFeS_2}=\dfrac{3,68}{184}=0,02\left(mol\right)\)
\(n_{O_2}=\dfrac{1,68}{22,4}=0,075\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,02}{2}< \dfrac{0,075}{\dfrac{13}{2}}\) => CuFeS2 hết, O2 dư
PTHH: 2CuFeS2 + \(\dfrac{13}{2}\)O2 --to--> 2CuO + Fe2O3 + 4SO2
0,02----->0,065------->0,02---->0,01---->0,04
=> \(\left\{{}\begin{matrix}n_{O_2\left(dư\right)}=0,075-0,065=0,01\left(mol\right)\\n_{SO_2}=0,04\left(mol\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}\%V_{O_2}=\dfrac{0,01}{0,01+0,04}.100\%=20\%\\\%V_{SO_2}=\dfrac{0,04}{0,01+0,04}.100\%=80\%\end{matrix}\right.\)
- \(\left\{{}\begin{matrix}m_{CuO}=0,02.80=1,6\left(g\right)\\m_{Fe_2O_3}=0,01.160=1,6\left(g\right)\end{matrix}\right.\)
=> mrắn = 1,6 + 1,6 = 3,2 (g)
Bài 2:
a)
2CuS + 3O2 --to--> 2CuO + 2SO2
4FeS + 7O2 --to--> 2Fe2O3 + 4SO2
b) Gọi số mol CuS, FeS là a, b (mol)
=> 96a + 88b = 22,8 (1)
\(n_{SO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
=> a + b = 0,25 (2)
(1)(2) => a = 0,1; b = 0,15
=> \(\left\{{}\begin{matrix}n_{CuO}=0,1\left(mol\right)\\n_{Fe_2O_3}=0,075\left(mol\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}\%m_{CuO}=\dfrac{0,1.80}{0,1.80+0,075.160}.100\%=40\%\\\%m_{Fe_2O_3}=\dfrac{0,075.160}{0,1.80+0,075.160}.100\%=60\%\end{matrix}\right.\)
a) PTHH: 2Cu + O2 ==(nhiệt)=> 2CuO
b) nCu = 6,4 / 64 = 0,1 (mol)
=> nO2 = 0,05 (mol)
=> VO2(đktc) = 0,05 x 22,4 = 1,12 lít
c) nCuO = nCu = 0,1 (mol)
=> mCuO = 0,1 x 80 = 8 (gam)
a) 2Cu + O2 ---> 2CuO
b) nCu = 6,4/64 =0,1 ( mol )
Theo PTHH : nO2 = 1/2 nCu = 0,1/2=0,05( mol )
VO2 = 0,05 x 22.4 = 1,12 ( l )
c)Theo PTHH : nCuO = nCu = 0,1 ( mol)
Khối lượng đồng oxit thu được sau phản ứng là : mCuO = 0,1 x 80 = 8 (g)
a. \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
\(n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH : 2Mg + O2 -> 2MgO
0,2 0,1 0,2
Xét tỉ lệ : \(\dfrac{0,2}{2}< \dfrac{0,3}{1}\) => Mg đủ , O2 dư
\(m_{O_2\left(dư\right)}=\left(0,3-0,1\right).32=6,4\left(g\right)\)
b) \(m_{MgO}=0,2.40=8\left(g\right)\)
Bài 2 :
a) \(n_{Al}=\dfrac{9,2}{27}=0,34\left(mol\right)\)
\(PTHH:2Na+2H_2O->2NaOH+H_2\)
0,17 0,17 0,17 0,17
\(V_{H_2}=0,17.22,4=3,808\left(l\right)\)
\(m_{NaOH}=0,17.40=6,8\left(g\right)\)
nó dễ mà nó dài ghê