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Bài 1:
PTHH: \(BaO+H_2SO_4\rightarrow BaSO_4+H_2O\)
Bđ____0,05___0,2
Pư____0,05___0,05_______0,05
Kt____0______0,15_______0,05
\(m_{kt}=m_{BaSO_4}=0,05.233=11,65\left(g\right)\)
\(m_{ddsaupư}=7,65+200-11,65=196\left(g\right)\)
\(C\%ddH_2SO_4=7,5\%\)
Bài 2: \(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)
bđ___0,1_______0,5
pư__1/12_______0,5_____1/6
kt ___1/60______0_______1/6
\(m_{FeCl_3}=\dfrac{1}{6}.162,5\approx27g\)
\(C_{MddFeCl_3}=\dfrac{1}{6}:0,5\approx0,3M\)
\(n_{CO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PT: \(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\)
Theo PT: \(n_{Ca\left(OH\right)_2}=n_{CaCO_3}=n_{CO_2}=0,25\left(mol\right)\)
a, \(C_{M_{Ca\left(OH\right)_2}}=\dfrac{0,25}{0,1}=2,5\left(M\right)\)
b, \(m_{CaCO_3}=0,25.100=25\left(g\right)\)
c, \(Ca\left(OH\right)_2+2HCl\rightarrow CaCl_2+2H_2O\)
Theo PT: \(n_{HCl}=2n_{Ca\left(OH\right)_2}=0,5\left(mol\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{0,5.36,5}{20\%}=91,25\left(g\right)\)
a) \(n_{CO_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: CO2 + 2NaOH → Na2CO3 + H2O
Mol: 0,15 0,3 0,15
\(C_{M_{ddNaOH}}=\dfrac{0,3}{0,2}=1,5M\)
b) Na2CO3: natri cacbonat
\(m_{Na_2CO_3}=0,15.106=15,9\left(g\right)\)
c)
PTHH: 2NaOH + H2SO4 → Na2SO4 + 2H2O
Mol: 0,15 0,075
\(V_{ddH_2SO_4}=\dfrac{0,075}{1}=0,075\left(l\right)=75\left(ml\right)\)
PTHH: \(H_2SO_4+2KOH\rightarrow K_2SO+2H_2O\)
Ta có: \(n_{H_2SO_4}=0,2\cdot1=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{KOH}=0,4\left(mol\right)\\n_{K_2SO_4}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{ddKOH}=\dfrac{\dfrac{0,4\cdot56}{6\%}}{1,048}\approx356,2\left(ml\right)\\C_{M_{K_2SO_4}}=\dfrac{0,2}{0,2+0,3562}\approx0,36\left(M\right)\end{matrix}\right.\)
\(n_{H_2SO_4}=1.0,2=0,2\left(mol\right)\\ H_2SO_4+2KOH\rightarrow K_2SO_4+2H_2O\\ 0,2.........0,4........0,2.......0,2\left(mol\right)\\ a.m_{ddKOH}=\dfrac{0,4.56.100}{6}=\dfrac{1120}{3}\left(g\right)\\ V_{ddKOH}=\dfrac{\dfrac{1120}{3}}{1,048}=\dfrac{140000}{393}\left(ml\right)\approx0,356\left(l\right)\)
\(b.C_{MddK_2SO_4}=\dfrac{0,2}{\dfrac{140000}{393}+0,2}\approx0,00056\left(M\right)\)
a) \(NaOH+HCl\rightarrow NaCl+H_2O\)
0,1................0,3
LẬp tỉ lệ : \(\dfrac{0,1}{1}< \dfrac{0,3}{1}\)=> Sau pứ HCl dư
\(m_{NaCl}=0,1.58,5=5,85\left(g\right)\)
b) \(CM_{NaCl}=\dfrac{0,1}{0,2+0,3}=0,2M\)
\(CM_{HCl\left(dư\right)}=\dfrac{\left(0,3-0,1\right)}{0,2+0,3}=0,4M\)
a)
$K_2SO_4 + BaCl_2 \to BaSO_4 + 2KCl$
b)
$n_{K_2SO_4} = 0,2.2 = 0,4(mol)$
$n_{BaCl_2} = 0,3.1 = 0,3(mol)$
Ta thấy :
$n_{K_2SO_4} : 1 > n_{BaCl_2} : 1$ nên $K_2SO_4$ dư
$n_{BaSO_4} = n_{BaCl_2} = 0,3(mol)$
$m_{BaSO_4} = 0,3.233 = 69,9(gam)$
c) $n_{K_2SO_4} = 0,4 - 0,3 = 0,1(mol)$
$V_{dd\ sau\ pư} = 0,2 + 0,3 = 0,5(lít)$
$C_{M_{K_2SO_4} } = \dfrac{0,1}{0,5} = 0,2M$
$C_{M_{KCl}} = \dfrac{0,6}{0,5} = 1,2M$
Bài 1: \(n_{H_2SO_4}=\frac{9}{49}\left(mol\right)\)
H2SO4 + 2KOH -> K2SO4 + 2H2O
=> nKOH= 2nH2SO4 = \(\frac{18}{49}\left(mol\right)\)
=> Vdd KOH = \(\frac{18}{49}:\frac{2}{1000}=\frac{9000}{49}\left(ml\right)\)
b) nK2SO4 = nH2SO4 = \(\frac{9}{49}\left(mol\right)\)
=> mK2SO4= \(\frac{9}{49}\cdot174=\frac{1566}{49}\left(g\right)\)
mdd KOH = \(\frac{9000}{49}\cdot1,12=\frac{1440}{7}\left(g\right)\)
c) \(\%m_{K_2SO_4}=\frac{1566}{49}:\left(200+\frac{1440}{7}\right)\cdot100\%\approx7,87\%\)
bài 2: nNa2CO3 = 0,05 (mol)
PTHH:
Na2CO3 + 2HCl -> 2NaCl + H2O + CO2
=> nHCl = n NaCl = 2nNa2CO3 = 0,1 (mol)
=> mNaCl= 0,1 . 58,5 = 5,85 (g)
b) nCO2 = nNa2CO3 = 0,05 (mol)
=> mCO2 = 0,05 . 44 = 2,2 (g)
mdd HCl = 0,1 . 36,5 :20% = 18,25 (g)
=> %mNaCl = \(\frac{5,85}{53+18,25-2,2}\approx8,47\%\)
a, PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_{2\downarrow}\)
\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)
b, Ta có: \(n_{Mg}=\dfrac{9,6}{24}=0,4\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Mg}=0,8\left(mol\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{0,8}{0,2}=4\left(M\right)\)
c, Theo PT: \(n_{MgO}=n_{Mg}=0,4\left(mol\right)\)
\(\Rightarrow m_{MgO}=0,4.40=16\left(g\right)\)
a: \(n_{H_2SO_4}=0.25\cdot2=0.5\left(mol\right)\)
\(n_{Al_2O_3}=\dfrac{10.2}{27\cdot2+16\cdot3}=0.1\left(mol\right)\)
\(Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)
0,1 0,5
Vì 0,1/1<0,5/3
nên Al2O3 hết, H2SO4 dư
=>Tính theo Al2O3
b:
\(Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)
0,1 0,3 0,1
\(m_{H_2SO_4\left(pư\right)}=0.3\cdot98=29.4\left(g\right)\)
\(m_{muối}=0.1\left(54+3\cdot96\right)=34.2\left(g\right)\)
Làm nhanh zùm mk