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nFe = 33,6 : 56 = 0,6 (mol)
pthh : 3Fe + 2O2 -t--> Fe3O4
0,6--> 0,4------->0,2 (mol)
=> vO2 = 0,4.22,4 = 8,96 (mol)
=> mFe3O4 = 0,2.232 = 46,4 (g)
pthh : 2KClO3 -t--> 2KClO3 + 3O2
0,267<-----------------------0,4(mol)
mKClO3= 0,267 .122,5 = 32,67 (g)
a, \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, Ta có: \(n_{Fe}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=0,6\left(mol\right)\Rightarrow V_{O_2}=0,6.22,4=13,44\left(l\right)\)
c, \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,3\left(mol\right)\Rightarrow m_{Fe_3O_4}=0,3.232=69,6\left(g\right)\)
d, \(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
Theo PT: \(n_{KClO_3}=\dfrac{2}{3}n_{O_2}=0,4\left(mol\right)\Rightarrow m_{KClO_3}=0,4.122,5=49\left(g\right)\)
\(n_{Fe}=\dfrac{m}{M}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
\(a.PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
3 2 1
0,9 0,6 0,3
\(b.V_{O_2}=n.24,79=0,6.24,79=14,874\left(l\right)\)
\(c.m_{Fe_3O_4}=n.M=0,3.\left(56.3+16.4\right)=69,6\left(g\right)\)
\(d.V_{O_2}=14,874\left(l\right)\\ \Rightarrow n_{O_2}=\dfrac{V}{24,79}=\dfrac{14,874}{24,79}=0,6\left(mol\right)\\ PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
2 2 3
0,6 0,6 0,9
\(m_{KClO_3}=n.M=0,6.\left(39+35,5+16.3\right)=55,5\left(g\right).\)
\(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
\(PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\\ Mol:0,4\rightarrow\dfrac{4}{15}\rightarrow\dfrac{2}{15}\)
\(\rightarrow\left\{{}\begin{matrix}V_{O_2}=\dfrac{4}{15}.22,4=\dfrac{448}{75}\left(l\right)\rightarrow V_{kk}=\dfrac{448}{75}.5=\dfrac{448}{15}\left(l\right)\\m_{Fe_3O_4}=\dfrac{2}{15}.232=\dfrac{464}{15}\left(g\right)\end{matrix}\right.\)
2KClO3 --to--> 2KCl + 3O2
\(\dfrac{8}{45}\) \(\dfrac{4}{15}\)
\(m_{KClO_3}=\dfrac{8}{45}.122,5=\dfrac{196}{9}\left(g\right)\)
a, \(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
PTHH: 3Fe + 2O2 ---to---> Fe3O4
Mol: 0,4 \(\dfrac{0,8}{3}\) \(\dfrac{0,4}{3}\)
b, \(V_{O_2}=\dfrac{0,8}{3}.22,4=5,973\left(l\right)\)
c, \(V_{kk}=\dfrac{448}{75}.5=29,867\left(l\right)\)
d, \(m_{Fe_3O_4}=\dfrac{0,4}{3}.232=30,93\left(g\right)\)
e,
PTHH: 2KClO3 ---to---> 2KCl + 3O2
Mol: \(\dfrac{0,16}{9}\) \(\dfrac{0,8}{3}\)
\(m_{KClO_3}=\dfrac{0,16}{9}.122,5=2,178\left(g\right)\)
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ pthh:3Fe+2O_2\underrightarrow{t^o}Fe_3O_{\text{4}}\)
0,15 0,1 0,05
\(m_{Fe_2O_4}=0,05.232=11,6\left(g\right)\\
V_{O_2}=0,1.11,4=2,24\left(l\right)\\
pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
0,2 0,1
\(m_{KMnO_4}=0,2.158=31,6\left(g\right)\)
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ pthh:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
0,15 0,1 0,05
\(m_{Fe_3O_{\text{ 4}}}=0,05.232=11,6\left(g\right)\\ V_{O_2}=0,1.22,4=2,24\left(l\right)\\ pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
0,1 0,05
\(m_{KMnO_4}=0,1.158=15,8\left(g\right)\)
\(n_{Fe}=\dfrac{126}{56}=2,25\left(mol\right)\\
pthh:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
2,25 1,5
=> \(V_{O_2}=1,5.22,4=33,6\left(L\right)\)
\(PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
1 1,5
=> \(m_{KClO3}=122,5\left(g\right)\)
3Fe+2O2-to>Fe3O4
0,225--0,15
n Fe=\(\dfrac{12,6}{56}\)=0,225 mol
VO2=0,15.22,4=3,36l
2KClO3-to>2KCl+3O2
0,1---------------------0,15
=>m KClO3=0,1.122,5=12,25g
\(a,3Fe+2O_2\rightarrow Fe_3O_4\)
\(b,\)
Ta có : \(n_{Fe}=\dfrac{m}{M}=\dfrac{126}{56}=2,25\left(mol\right)\)
\(\Rightarrow n_{O_2}=\dfrac{2}{3}n_{Fe}=\dfrac{2}{3}.2,25=1,5\left(mol\right)\)
\(\Rightarrow VO_2=33,6\left(l\right)\)
\(c,\)
\(PTHH:2KClO_3\rightarrow2KCl+3O_2\)
Theo \(PTHH:n_{KClO_3}=\dfrac{2}{3}n_{O_2}=\dfrac{2}{3}.1,5=1\left(mol\right)\)
\(\Rightarrow m_{KClO_3}=n.M=1,122,5=122,5\left(g\right)\)
a. \(n_{Fe}=\dfrac{11.2}{56}=0,2\left(mol\right)\)
PTHH : 3Fe + 2O2 ---to---> Fe3O4
0,2 \(\dfrac{0.4}{3}\)
b. \(V_{O_2}=\dfrac{0.4}{3}.22,4=\dfrac{8.96}{3}\left(l\right)\)
c. PTHH : 2KClO3 -> 2KCl + 3O2
\(\dfrac{0.8}{3}\) \(\dfrac{0.4}{3}\)
\(m_{KClO_3}=\dfrac{0.8}{3}.122,5=\dfrac{98}{3}\left(g\right)\)
a) 3Fe + 2O2 
Fe3O4
b) nFe = \(\dfrac{8,4}{56}\)= 0,15 mol
nFe3O4 = \(\dfrac{11,6}{232}\) = 0,05 mol
Ta thấy \(\dfrac{nFe}{3}\)= \(\dfrac{nFe_3O_4}{1}\)=> Fe phản ứng hết
<=> nO2 cần dùng = \(\dfrac{2nFe}{3}\)= 0,1 mol
<=> mO2 cần dùng = 0,1.32 = 3,2 gam
c) Oxi chiếm thể tích bằng 1/5 thể tích không khí.
Mà V O2 = 0,1.22,4 = 2,24 lít => V không khí = 2,24 . 5 = 11,2 lít
\(n_{Fe}=\dfrac{25,2}{56}=0,45\left(mol\right)\\ a,PTHH:3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\\ b,n_{O_2}=\dfrac{2}{3}.0,45=0,3\left(mol\right)\\ \Rightarrow V_{O_2\left(đktc\right)}=0,3.22,4=6,72\left(l\right)\\ c,2KClO_3\rightarrow\left(t^o\right)2KCl+3O_2\\ n_{KClO_3}=\dfrac{2}{3}.0,3=0,2\left(mol\right)\\ \Rightarrow m_{KClO_3}=122,5.0,2=24,5\left(g\right)\)
2.
a) mFe pứ = 12,6\56=0,225 (mol)
Pt: 3Fe + 2O2 --to--> Fe3O4
....0,225---0,15--------0,075
b) VO2 cần dùng =0,15. 22,4 = 3,36(lít)
mFe3O4 thu được =0,075. 232 = 17,4(g)
các 2 áp dụng đl bảo toàn khối lượng
=>mFe3O4 thu được = 17,4(g)
1.
3Fe + 2O2 --to--> Fe3O4
0,045--0,03----
nFe=2,52\56=0,045 mol
=>VO2=0,03.22,4=0,672l
2KClO3to->2KCl+3O2
0,02-------------------0,03
2KMnO4->K2MnO4+MnO2+O2
0,06---------------------------------0,02
=>vậy chất KClO3 tạo ra oxi mà dùng ít chất để điều chế >
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