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a) $n_{Al} = \dfrac{5,4}{27} = 0,2(mol)$
$4Al + 3O_2 \xrightarrow{t^o} 2Al_2O_3$
Theo PTHH : $n_{O_2} = \dfrac{3}{4}n_{Al} = 0,15(mol)$
$V_{O_2} = 0,15.22,4 = 3,36(lít)$
b) $2 KClO_3 \xrightarrow{t^o} 2KCl + 3O_2$
$n_{KClO_3} = \dfrac{2}{3}n_{O_2} = 0,1(mol)$
$m_{KClO_3} = 0,1.122,5 = 12,25(gam)$
\(n_{Al}=\dfrac{m}{M}=\dfrac{5,4}{27}=0,2\left(mol\right)\\ PTHH:4Al+3O_2-^{t^o}>2Al_2O_3\)
tỉ lệ: 4 : 3 : 2
n(mol) 0,2---->0,15---->0,1
\(V_{O_2\left(dktc\right)}=n\cdot22,4=0,15\cdot22,4=3,36\left(l\right)\\ PTHH:2KClO_3-^{t^o}>2KCl+3O_2\)
tỉ lệ: 2 : 2 : 3
n(mol) 0,1<-------------------------0,15
\(m_{KClO_3}=n\cdot M=0,1\cdot\left(39+35,5+16\cdot3\right)=12,25\left(g\right)\)
4Al+3O2-to>2Al2O3
0,04---0,03------0,02 mol
n Al=\(\dfrac{1,08}{27}\)=0,04 mol
=>VO2=0,03.22,4=0,672l
b)
2A+O2-to>2AO
0,06--0,03 mol
=>\(\dfrac{3,84}{A}=0,06\)
=>A=64 :=>Al là Đồng
mMg = 3.6/24 = 0.15 (mol)
2Mg + O2 -to-> 2MgO
0.15__0.075____0.15
mMgO= 0.15*40 = 6 (g)
VO2 = 0.075*22.4 = 1.68 (l)
2KClO3 -to-> 2KCl + 3O2
0.05_______________0.075
mKClO3 = 0.05*122.5 = 6.125 (g)
PTHH: \(2Mg+O_2\underrightarrow{t^o}2MgO\)
a+b) Ta có: \(n_{Mg}=\dfrac{3,6}{24}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{O_2}=0,075\left(mol\right)\\n_{MgO}=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{O_2}=0,075\cdot22,4=1,68\left(l\right)\\m_{MgO}=0,15\cdot40=6\left(g\right)\end{matrix}\right.\)
c) PTHH: \(2KClO_3\xrightarrow[MnO_2]{t^o}2KCl+3O_2\uparrow\)
Theo PTHH: \(n_{KClO_3}=0,05\left(mol\right)\)
\(\Rightarrow m_{KClO_3}=0,05\cdot122,5=6,125\left(g\right)\)
a, PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, Ta có: \(n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Theo PT: \(n_{Fe_3O_4}=\dfrac{1}{2}n_{O_2}=0,1\left(mol\right)\)
\(\Rightarrow m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)
c, PT: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
Có: O2 hao hụt 40% → H% = 100 - 40 = 60%
Theo PT: \(n_{KMnO_4}=2n_{O_2}=0,4\left(mol\right)\)
\(\Rightarrow n_{KMnO_4\left(TT\right)}=\dfrac{0,4}{60\%}=\dfrac{2}{3}\left(mol\right)\)
\(\Rightarrow m_{KMnO_4}=\dfrac{2}{3}.158\approx105,3\left(g\right)\)
nP = 3,1 : 31 = 0,1 (mol)
pthh : 4P + 5O2 -t--> 2P2O5 (1)
0,1--> 0,125 (mol)
=> VO2 = 0,125 .22,4 = 2,8(l)
pthh : 2KMnO4 -t--> K2MnO4 + MnO2 +O2 (2)
0,25<--------------------------- 0,125(mol)
=> mKMnO4 = 0,25 .158 = 39,5(g)
d ) (1) là Phản ứng hóa hợp
(2) là phản ứng phân hủy
nP = 3,1/31 = 0,1 (mol)
PTHH: 4P + 5O2 -> (t°) 2P2O5 (phản ứng hóa hợp)
Mol: 0,1 ---> 0,125
VO2 = 0,125 . 22,4 = 2,8 (l)
PTHH: 2KMnO4 -> (t°) K2MnO4 + MnO2 + O2 (phản ứng phân hủy)
nKMnO4 = 0,125 . 2 = 0,25 (mol)
mKMnO4 = 0,25 . 158 = 39,5 (g)
nKMnO4=94,8:158=0,6(mol)
PTHH: 2KMnO4-t--> K2MnO4+MnO2+O2
0,6----------------------------------->0,3(mol)
=>V= VO2=0,3. 22,4= 6,72(l)
b ) 40%nO2 =40%.0,3=0,12(mol)
2R + O2 -t--->2RO
0,24(mol)<- 0,12
=> M(Khối lượng Mol ) R= m:n=5,76:0,24=24(G/MOL)
=> R là Mg
a)-\(n_{KMnO_4}=\dfrac{m}{M}=\dfrac{94,8}{158}=0,6\left(mol\right)\)
-PTHH: \(2KMnO_4\rightarrow^{t^0}K_2MnO_4+MnO_2+O_2\uparrow\)
2 1
0,6 0,3
\(\Rightarrow V_{O_2\left(đktc\right)}=n.22,4=0,3.22,4=6,72\left(l\right)\)
b)-\(V_{O_2\left(cd\right)}=6,72.\dfrac{40}{100}=2,688\left(l\right)\)
\(\Rightarrow n_{O_2}=\dfrac{V}{22,4}=\dfrac{2,688}{22,4}=0,12\left(mol\right)\)
-PTHH: \(2R+O_2\rightarrow^{t^0}2RO\)
2 1
0,24 0,12
\(m_R=n.M=5,76\left(g\right)\)
\(\Rightarrow0,24.M_R=5,76\)
\(\Rightarrow M_R=24\) (g/mol)
-Vậy R là Crom
nO2 = 3,36 : 22,4 = 0,15 (mol)
pthh : 2Mg + O2 -t--> 2MgO
0,3<----0,15---> 0,3 (mol)
=> mMg= 0,3 . 24 = 7,2 (g)
=> mMgO = 0,3 . 40 =12 (g)
pthh : 2KMnO4 -t--> K2MnO4 + MnO2 + O2
0,3<-------------------------------------0,15 (mol)
=> mKMnO4 = 0,3 . 158 = 47,4 (g)
