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a)PTHH:
HCl + NaOH → NaCl + H2O
nHCl = 0,04 (mol) = nNaOH = nNaCl
=>VddNaOH = 0,04/0,1 = 0,4 (l) = 400 (ml)
Vdd = VddNaOH + VddHCl = 0,6 (l)
=>C(M) ≈ 0,067 (M)
b) 2HCl + Ca(OH)2 → CaCl2 + 2H2O
nCa(OH)2 = nCaCl2 = (1/2)nHCl = 0,02 (mol)
(Nồng độ phần trăm = 25% ????)
mCa(OH)2 = 1,48 (g)
=>mdd(Ca(OH)2) = 5,92 (g)
mddHCl = 220 (g)
=>mdd = 225,92 (g)
mCaCl2 = 2,22 (g)
=>%mCaCl2 ≈ 0,98%
a) nHNO3 = 0,2.0,25 = 0,05 mol
HNO3 + KOH ---> KNO3 + H2O
0,05 0,05 0,05
VKOH = 0,05/0,2 = 0,25 l
Vdd KNO3 = 0,25 + 0,2 = 0,45 l
CM KNO3 = 0,05/0,45 = 0,(1) M
b) 2HNO3 + Ba(OH)2 ---> Ba(NO3)2 + 2H2O
0,05 0,025 0,025
mBa(OH)2 = 0,025.171 = 4,275 g
mdd Ba(OH)2 = \(\frac{4,275.100\%}{20\%}\) = 21,375 g
mBa(NO3)2 = 0,025.261 = 6,525 g
C%dd Ba(NO3)2 = \(\frac{6,525}{21,375+200.1,02}.100\%\) \(\approx\) 2,9 %
Theo đề bài ta có : nHCl = 0,2.0,2=0,04(mol)
a) Ta có PTHH :
\(HCl+NaOH\rightarrow NaCl+H2O\)
0,04mol.....0,04mol....0,04mol
Ta có :
\(V_{\text{dd}HCl\left(c\text{ần}-d\text{ùng}\right)}=\dfrac{0,04}{0,1}=0,4\left(lit\right)=400\left(ml\right)\)
CMNaCl = \(\dfrac{0,04}{0,2}=0,2\left(M\right)\)
b) Theo đề bài ta có : mddHCl=\(200.1=200\left(g\right)\)
Ta có PTHH :
\(Ca\left(OH\right)2+2HCl\rightarrow CaCl2+2H2O\)
0,02mol...........0,04mol....0,02mol
Ta có :
\(m\text{dd}Ca\left(OH\right)2\left(c\text{ần}-d\text{ùng}\right)=\dfrac{0,02.74}{5}.100=29,6\left(g\right)\)
C%CaCl2 = \(\dfrac{0,02.111}{0,02.74+200}.100\%\approx1,102\%\)
Vậy..............
\(n_{H_2SO_4}=0,2.0,25=0,05
mol
\)
a) \(H_2SO_4+2KOH
\rightarrow
K_2SO_4+2H_2O\)
Theo PTHH ta có: \(n_{KOH}=2n_{H_2SO_4}=0,05.2=0,1
mol\)
\(\rightarrow V_{dd
KOH}=\frac{n}{C_M}=\frac{0,1}{0,5}=0,2
\left(l\right)=200\left(ml\right)\)
\(n_{K_2SO_4}=n_{H_2SO_4}=0,05\left(mol\right)\)
\(m_{dd
sau}=250+200=450=0,45\left(l\right)\)
\(\rightarrow C_{M
K_2SO_4}=\frac{0,05}{0,45}=\frac{1}{9}M\)
b)\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)
\(n_{NaOH}=2.n_{H_2SO_4}=0,1\left(mol\right)\rightarrow m_{NaOH}=0,1.40=4\left(g\right)\)
\(m_{dd
NaOH}=\frac{4.100}{20}=20\left(g\right)\)
\(n_{Na_2SO_4}=0,05\left(mol\right)\rightarrow m_{Na_2SO_4}=0,05.142=7,1\left(g\right)\)
Do D=1ml/g -> mdd H2SO4=250(g)
\(C\%_{Na_2SO_4}=\frac{7,1}{250+20}.100=2,63\%\)
\(n_{Ca\left(OH\right)_2}=0,3.1=0,3\left(mol\right)\\ n_{HCl}=0,2.0,2=0,04\left(mol\right)\)
a
\(Ca\left(OH\right)_2+2HCl\rightarrow CaCl_2+2H_2O\)
0,02<------0,04----->0,02
Xét \(\dfrac{0,3}{1}>\dfrac{0,04}{2}\Rightarrow Ca\left(OH\right)_2.dư\)
\(m_{CaCl_2}=0,02.111=2,22\left(g\right)\)
b
Muốn pứ xảy ra hoàn toàn phải thêm dung dịch HCl 0,2 M
\(n_{HCl.cần}=2n_{Ca\left(OH\right)_2}=0,3.2=0,6\left(mol\right)\\ n_{HCl.cần.thêm}=0,6-0,04=0,56\left(mol\right)\)
\(V_{cần.\left(HCl\right)}=\dfrac{0,56}{0,2}=2,8\left(l\right)=280\left(ml\right)\\ V_{cần.thêm\left(HCl\right)}=280-200=80\left(ml\right)\)
c
\(CM_{CaCl_2}=\dfrac{0,02}{0,3+0,28}=\dfrac{1}{29}M\)
Theo đề bài ta có :
VddHCl=200ml=0,2 l
nHCl = 0,2.0,2=0,04 mol
a) Ta có PTHH 1:
HCl + NaOH \(\rightarrow\) NaCl + H2O
0,04mol...0,04mol....0,04mol
=> \(\left\{{}\begin{matrix}V\text{dd}NaOH=\dfrac{0,04}{0,1}=0,4\left(l\right)=400\left(ml\right)\\CM_{\text{dd}NaCl\left(c\text{ần}-d\text{ùng}\right)}=\dfrac{0,04}{0,2}=0,2\left(M\right)\end{matrix}\right.\)
b) Ta có PTHH 2 :
2HCl + Ca(OH)2 -> CaCl2 + 2H2O
0,04mol...0,02mol.....0,02mol
Ta có : mdd(sau-p/ư) = 200.1 + 0,02.74 = 201,48 g
=> C%CaCl2 = \(\dfrac{\left(0,02.111\right)}{201,48}.100\%\approx1,102\%\)
Vậy....
\(n_{HCl}=0,2.0,2=0,04\left(mol\right)\)
Pt: \(NaOH+HCl\rightarrow NaCl+H_2O\)
0,04mol <---0,04mol
\(V_{NaOH}=\dfrac{0,04}{0,1}=0,4\left(l\right)=400\left(ml\right)\)
b) Pt: \(Ca\left(OH\right)_2+2HCl\rightarrow CaCl_2+2H_2O\)
0,02mol<--- 0,04mol
\(m_{dd_{Ca\left(OH\right)_2}}=\dfrac{0,02.74.100}{6}=24,67\left(g\right)\)
Ta có: \(n_{Ba\left(OH\right)_2}=0,025.0,02=0,0005\left(mol\right)\)
\(n_{NaOH}=0,025.0,05=0,00125\left(mol\right)\)
\(\Rightarrow n_{OH^-}=2n_{Ba\left(OH\right)_2}+n_{NaOH}=0,00225\left(mol\right)\)
\(H^++OH^-\rightarrow H_2O\)
\(\Rightarrow n_{H^+}=n_{OH^-}=0,00225\left(mol\right)\)
Gọi: VX = x (l)
Ta có: \(n_{HCl}=0,1x\left(mol\right)\)
\(n_{CH_3COOH}=0,2x\left(mol\right)\)
\(\Rightarrow n_{H^+}=n_{HCl}+n_{CH_3COOH}=0,1x+0,2x=0,00225\)
\(\Rightarrow x=0,0075\left(l\right)=7,5\left(ml\right)\)