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a.
\(Na_2CO_3+Ba\left(OH\right)_2\rightarrow BaCO_3+2NaOH\)
b.
\(n_{BaCO_3}=n_{Na_2CO_3}=0,2.1=0,2\left(mol\right)\\ m_{kt}=197.0,2=39,4\left(g\right)\)
c.
\(n_{Ba\left(OH\right)_2}=n_{Na_2CO_3}=0,2\left(mol\right)\\ C\%_{Ba\left(OH\right)_2}=\dfrac{0,2.171.100\%}{200}=17,1\%\)
\(m_{HCl}=100.7,3\%=7,3\left(g\right)\Rightarrow n_{HCl}=\dfrac{7,3}{36,5}=0,2\left(mol\right)\)
PT: \(Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)
Theo PT: \(n_{BaCl_2}=\dfrac{1}{2}n_{HCl}=0,1\left(mol\right)\)
\(\Rightarrow C\%_{BaCl_2}=\dfrac{0,1.208}{100+100}.100\%=10,4\%\)
\(n_{Na_2CO_3}=0,1.1=0,1\left(mol\right)\)
a. \(Na_2CO_3+Ba\left(OH\right)_2\rightarrow BaCO_3+2NaOH\)
0,1 0,1 0,1 0,2
b. \(m_{kt}=m_{BaCO_3}=0,1.197=19,7\left(g\right)\)
c. \(C\%_{Ba\left(OH\right)_2}=\dfrac{0,1.171.100}{200}=8,55\%\)
d. \(BaCO_3+2HCl\rightarrow BaCl_2+H_2O+CO_2\)
0,1 0,2
=> \(a=m_{dd.HCl}=\dfrac{0,2.36,5.100}{30}=\dfrac{73}{3}\left(g\right)\)
\(a.n_{CO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ a.Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\\ 0,25.......0,25............0,25..........0,25\left(mol\right)\\ C_{MddCa\left(OH\right)_2}=\dfrac{0,25}{0,1}=2,5\left(M\right)\\ b.m_{\downarrow}=m_{CaCO_3}=100.0,25=25\left(g\right)\)
\(n_{Na_2SO_4}=\dfrac{142.10}{100.142}=0,1(mol)\\ Na_2SO_4+Ba(OH)_2\to BaSO_4\downarrow+2NaOH\\ \Rightarrow n_{BaSO_4}=n_{Ba(OH)_2}=0,1(mol);n_{NaOH}=0,2(mol)\\ a,m_{BaSO_4}=0,1.233=23,3(g)\\ b,m_{dd_{Ba(OH)_2}}=\dfrac{0,1.171}{15\%}=114(g)\\ c,C\%_{NaOH}=\dfrac{0,2.40}{142+114-23,3}.100\%=3,44\%\)
Ta có: \(n_{Na_2SO_4}=\dfrac{\dfrac{10\%.142}{100\%}}{142}=0,1\left(mol\right)\)
\(PTHH:Na_2SO_4+Ba\left(OH\right)_2--->BaSO_4\downarrow+2NaOH\)
a. Theo PT: \(n_{BaSO_4}=n_{Ba\left(OH\right)_2}=n_{Na_2SO_4}=0,1\left(mol\right)\)
\(\Rightarrow m_{BaSO_4}=0,1.233=23,3\left(g\right)\)
b. Ta có: \(m_{Ba\left(OH\right)_2}=0,1.171=17,1\left(g\right)\)
Mà: \(C_{\%_{Ba\left(OH\right)_2}}=\dfrac{17,1}{m_{dd_{Ba\left(OH\right)_2}}}.100\%=15\%\)
\(\Leftrightarrow m_{dd_{Ba\left(OH\right)_2}}=114\left(g\right)\)
c. Ta có: \(m_{dd_{NaOH}}=114+14,2-23,3=104,9\left(g\right)\)
Theo PT: \(n_{NaOH}=2.n_{Ba\left(OH\right)_2}=2.0,1=0,2\left(mol\right)\)
\(\Rightarrow m_{NaOH}=0,2.40=8\left(g\right)\)
\(\Rightarrow C_{\%_{NaOH}}=\dfrac{8}{104,9}.100\%=7,63\%\)
\(a.n_{Mg\left(OH\right)_2}=\dfrac{17,4}{58}=0,3\left(mol\right)\\ Mg\left(OH\right)_2+2HCl\rightarrow MgCl_2+2H_2O\\ n_{HCl}=2n_{Mg\left(OH\right)_2}=0,6\left(mol\right)\\ CM_{HCl}=\dfrac{0,6}{0,2}=3M\\b. n_{Mg\left(OH\right)_2}=n_{MgCl_2}=0,3\left(mol\right)\\ m_{MgCl_2}=0,3.85=25,5\left(g\right)\\c.CM_{MgCl_2}=\dfrac{0,3}{0,2}=1,5M \)
Bài 1 :
nNaOH = 0,6 (mol)
NaOH + HCl -> NaCl + H2O
0,6...........0,6........0,6 (mol)
mdd HCl = \(\frac{0,6.36,5}{7,3\%}=300\left(g\right)\)
\(C\%_{NaCl}=\frac{0,6.58,5}{300+200}.100\%=7,02\%\)
1.