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a) PTHH: Fe + H2SO4 \(\rightarrow\) FeSO4 + H2 \(\uparrow\)
nFe = \(\frac{11,2}{56}=0,2\left(mol\right)\)
Theo PT: n\(H_2\) = n\(FeSO_4\) = nFe = 0,2 (mol)
=> m\(FeSO_4\) = 0,2.152 = 30,4 (g)
=> m\(H_2\) = 0,2.2 = 0,4(g)
mdd sau pứ = 11,2 + m - 0,4 =10,8 + m (g)
Áp dụng CT : C% FeSO4 = \(\frac{m_{FeSO_4}}{md_dsau}pứ\).100%
=> 14,7% = \(\frac{30,4}{10,8+m}\).100%
=> 0,147 ( 10,8+m ) = 30,4
=> 1,5876 + 0,147m = 30,4
=> 0,147m = 28,8124
=> m \(\approx\) 196 (g)
b) Theo PT: n\(H_2SO_4\) = nFe = 0,2 (mol)
=> m\(H_2SO_4\) = 0,2.98 = 19,6 (g)
Áp dụng CT: C% = \(\frac{m_{ct}}{md_d}\).100%
=> C%dd axit = \(\frac{19,6}{196}.100\%\) = 10%
nFe= 11.2/56=0.2 mol
Fe + H2SO4 --> FeSO4 + H2
0.2___0.2______0.2_____0.2
mH2SO4= 0.2*98=19.6g
mFeSO4= 0.2*152=30.4g
mH2= 0.2*2=0.4g
mdd sau phản ứng= mFe + mdd H2SO4 -mH2= 11.2+m-0.4=10.8+m (g)
C%FeSO4= 30.4/ (10.8+m) *100%= 14.7%
<=> 10.8+m= 206.8
<=> m= 196g
C%H2SO4= 19.6/196*100%= 10%
`Fe + H_2 SO_4 -> FeSO_4 + H_2 ↑`
`0,3` `0,3` `0,3` `0,3` `(mol)`
`n_[Fe] = [ 16,8 ] / 56 = 0,3 (mol)`
`a) m_[dd H_2 SO_4] = [ 0,3 . 98 ] / [ 9,8 ] . 100 = 300 (g)`
`b) V_[H_2] = 0,3 . 22,4 = 6,72 (l)`
`c) C%_[FeSO_4] = [ 0,3 . 152 ] / [ 16,8 + 300 - 0,3 . 2 ] . 100 ~~ 14,42%`
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\a, PTHH:Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ b,n_{H_2}=n_{H_2SO_4}=n_{Fe}=0,2\left(mol\right)\\ V_{H_2\left(đkc\right)}=0,2.24,79=4,958\left(l\right)\\ c,C_{MddH_2SO_4}=\dfrac{0,2}{0,4}=0,5\left(M\right)\)
a) PTHH: \(Ca+H_2SO_4\rightarrow CaSO_4+H_2\uparrow\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
b) Ta có: \(\Sigma n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
Theo các PTHH, ta thấy \(n_{H_2SO_4}=n_{H_2}=0,5\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}=0,5\cdot98=49\left(g\right)\)
Mặt khác: \(m_{H_2}=0,5\cdot2=1\left(g\right)\)
Bảo toàn khối lượng: \(m_{hh}=m_{muối}+m_{H_2}-m_{H_2SO_4}=68+1-49=20\left(g\right)\)
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\ Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\\ n_{H_2SO_4}=n_{H_2}=n_{FeSO_4}=n_{Fe}=0,2\left(mol\right)\\ a,m_{H_2SO_4}=0,2.98=19,6\left(g\right)\\ b,C\%_{ddH_2SO_4}=\dfrac{19,6}{200}.100=9,8\%\\ c,m_{FeSO_4}=152.0,2=30,4\left(g\right)\\ d,V_{H_2\left(đktc\right)}=0,2.22,4=4,48\left(l\right)\)
\(n_{NaOH}=\dfrac{200\cdot4\%}{40}=0.2\left(mol\right)\)
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\)
\(0.2..............0.1..............0.1\)
\(V_{dd_{H_2SO_4}}=\dfrac{0.1}{0.2}=0.5\left(l\right)\)
\(m_{Na_2SO_4}=0.1\cdot142=14.2\left(g\right)\)
\(m_{dd}=200+510=710\left(g\right)\)
\(C\%_{Na_2SO_4}=\dfrac{14.2}{710}\cdot100\%=2\%\)
Ta có: mNaOH = 200.4% = 8 (g)
\(\Rightarrow n_{NaOH}=\dfrac{8}{40}=0,2\left(mol\right)\)
PT: \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
_____0,2______0,1_______0,1 (mol)
a, \(V_{ddH_2SO_4}=\dfrac{0,1}{0,2}=0,5\left(l\right)\)
b, Chất có trong dd sau pư là Na2SO4.
Ta có: m dd sau pư = m dd NaOH + m dd H2SO4 = 200 + 510 = 710 (g)
\(\Rightarrow C\%_{Na_2SO_4}=\dfrac{0,1.142}{710}.100\%=2\%\)
Bạn tham khảo nhé!
Fe+H2SO4->FeSO4+H2
0,15---0,15-----0,15---0,15 mol
n Fe=8,4\56=0,15 mol
=>VH2=0,15.22,4=3,36l
=>m H2SO4=0,15.98=14,7g
=>C% H2SO4=14,7\245 .100=6%
=>m dd muối=8,4+245-0,15.2=253,1g
=>C% muối =0,15.152\253,1 .100=9%
