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\(m_{rượu} = 10.1000.0,8 = 8000(gam)\\ n_{rượu} = \dfrac{8000}{46} = \dfrac{4000}{23}(mol)\\ C_2H_5OH + O_2 \xrightarrow{t^o} CH_3COOH + H_2O\\ n_{CH_3COOH} = n_{C_2H_5OH} =\dfrac{4000}{23}.80\% = \dfrac{3200}{23}(mol)\\ C_{M_{CH_3COOH}} = \dfrac{\dfrac{3200}{23}}{10} =13,91M \)
\(n_{CO2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
Pt : \(C_6H_{12}O_6\xrightarrow[30-35^oC]{Menrượu}2C_2H_5OH+2CO_2\)
0,5 0,5
a) \(m_{C2H5OH}=0,5.46=23\left(g\right)\)
b) Pt : \(C_2H_5OH+O_2\xrightarrow[]{Mengiấm}CH_3COOH+H_2O\)
0,5 0,5
\(m_{CH3COOH\left(lt\right)}=0,5.60=30\left(g\right)\)
⇒ \(m_{CH3COOH\left(tt\right)}=30.80\%=24\left(g\right)\)
Chúc bạn học tốt
\(C_6H_{12}O_6\underrightarrow{t^o}2C_2H_5OH+2CO_2\uparrow\)(xt : men rượu )
0,5 0,5
\(n_{CO_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
\(m_{C_2H_5OH}=0,5.46=23\left(g\right)\)
\(C_2H_5OH+O_2\underrightarrow{t^o}CH_3COOH+H_2O\) (men giấm )
0,5 0,5
\(m_{CH_3COOH}=0,5.60=30\left(g\right)\)
\(m_{CH_3COOHtt}=30.80\%=24\left(g\right)\)
\(nC_2H_5OH=\dfrac{2,9}{46}=0,06\left(mol\right)\)
\(C_2H_5OH+Na\rightarrow C_2H_5ONa+\dfrac{1}{2}H_2\)
0,06 0,06 0,06 0,03 (mol)
VH2 = 0,03.22,4= 0,672 (l)
V = m /D
=> V rượu etylic = 2,9 / 0,8 = 3,625 (ml)
1) \(n_{C_2H_4}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
PTHH: C2H4 + H2O --axit--> C2H5OH
0,4-------------------->0,4
=> mC2H5OH = 0,4.46.70% = 12,88 (g)
\(V_{C_2H_5OH}=\dfrac{12,88}{0,8}=16,1\left(ml\right)\\ \rightarrowĐ_r=\dfrac{16,1}{50}.100=32,2^o\)
2) \(\left\{{}\begin{matrix}n_{C_2H_5OH}=\dfrac{36,8}{46}=0,8\left(mol\right)\\n_{CH_3COOH}=\dfrac{36}{60}=0,6\left(mol\right)\\n_{CH_3COOC_2H_5}=\dfrac{44}{88}=0,5\left(mol\right)\end{matrix}\right.\)
PTHH: CH3COOH + C2H5OH --H2SO4(đặc), to--> CH3COOC2H5 + H2O
0,5<-------------------------------------------------0,5
LTL: 0,6 < 0,8 => Hiệu suất phản ứng tính theo CH3COOH
=> \(H=\dfrac{0,5}{0,6}.100\%=83,33\%\)
\(CaCO_3+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Ca+CO_2+H_2O\\ a,n_{CH_3COOH}=0,2.1=0,2\left(mol\right)\Rightarrow n_{CO_2}=\dfrac{0,2}{2}=0,1\left(mol\right)\Rightarrow V_{CO_2\left(đktc\right)}=0,1.22,4=2,24\left(l\right)\\ b,CH_3COOH+C_2H_5OH⇌\left(H^+,t^o\right)CH_3COOC_2H_5+H_2O\\ n_{CH_3COOH}=\dfrac{50}{200}.0,2=0,05\left(mol\right)\\ n_{C_2H_5OH}=\dfrac{23}{46}=0,5\left(mol\right)\\ Vì:\dfrac{0,5}{1}>\dfrac{0,05}{1}\Rightarrow Rượu.dư\\ \Rightarrow n_{este\left(LT\right)}=n_{axit}=0,05\left(mol\right)\\ \Rightarrow n_{este\left(TT\right)}=80\%.0,05=0,04\left(mol\right)\\ m_{CH_3COOC_2H_5}=88.0,04=3,52\left(g\right)\)
a)
\(V_{C_2H_5OH}=\dfrac{96.20}{100}=19,2\left(ml\right)\)
=> \(m_{C_2H_5OH}=19,2.0,8=15,36\left(g\right)\)
b) \(n_{C_2H_5OH}=\dfrac{15,36}{46}=\dfrac{192}{575}\left(mol\right)\)
\(V_{H_2O}=20-19,2=0,8\left(ml\right)\)
=> \(m_{H_2O}=0,8.1=0,8\left(g\right)\)
=> \(n_{H_2O}=\dfrac{0,8}{18}=\dfrac{2}{45}\left(mol\right)\)
PTHH: 2C2H5OH + 2Na --> 2C2H5ONa + H2
\(\dfrac{192}{575}\)------------------------->\(\dfrac{96}{575}\)
2H2O + 2Na --> 2NaOH + H2
\(\dfrac{2}{45}\)----------------------->\(\dfrac{1}{45}\)
=> \(V_{H_2}=22,4.\left(\dfrac{96}{575}+\dfrac{1}{45}\right)=4,238\left(l\right)\)
C2H5OH + Na -- > C2H5OHNa + 1/2 H2
Na+H2O --- > NaOH + 1/2H2
Vr = 20x96/100 = 19,2ml = 0.0192 (l)
mC2H5OH = D.V = 19,2 x 0.8 = 15.36 (g)
nC2H5OH = m/M = 15.36 / 46 = 0.43 (mol)
=> nH2 = 0.215 (mol)
VH2O = 1 ml => mH2O = 1 (g)
=> nH2O = m/M = 1/18 = 0.056 (mol)
=> nH2 = 0.028 (mol)
nH2 = 0.215 + 0.028 = 0.243 (mol)
=> VH2 = 22.4 x 0,243 = 5,4432 (l)
\(m_{C_2H_5OH}=88.0,8=70,4\left(kg\right)\)
\(C_2H_5OH+O_2\rightarrow\left(t^o,men.giấm\right)CH_3COOH+H_2O\)
46g `->` 32g `->` 60g
70,4kg `->` ?kg `->` ?kg
\(m_{O_2}=\dfrac{70,4.32}{46}=48,97\left(g\right)\)
\(V_{O_2}=\dfrac{48,97}{32}.22,4.90\%=30,85\left(m^3\right)\)
\(m_{CH_3COOH}=\dfrac{70,4.60.90}{46.100}=82,64\left(kg\right)\)
\(n_{C_2H_4}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: C2H4 + H2O \(\xrightarrow[Axit]{Men.rượu}\) C2H5OH
0,2 0,2
\(m_{C_2H_5OH}=0,2.46.80\%=7,36\left(g\right)\\ V_{C_2H_5OH}=\dfrac{7,36}{0,8}=9,2\left(ml\right)\)
\(n_{C_2H_4}=\dfrac{4,48}{22,4}=0,2mol\)
\(C_2H_4+H_2O\xrightarrow[axit]{lên.men}C_2H_5OH\)
0,2 0,2 ( mol )
\(m_{C_2H_5OH}=0,2.46.80\%=7,36g\)
\(C_{C_2H_5OH}=\dfrac{7,36}{0,8}=9,2ml\)