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Đáp án:
Giải thích các bước giải:
a,PTHH:Na2CO3+2HCl→2NaCl+H2O+CO2a,PTHH:Na2CO3+2HCl→2NaCl+H2O+CO2
nCO2=1,1222,4=0,05(mol)nCO2=1,1222,4=0,05(mol)
→mNa2CO3=0,05.106=5,3(g)→mNa2CO3=0,05.106=5,3(g)
mNa2SO4=10−5,3=4,7(g)mNa2SO4=10−5,3=4,7(g)
b, Đổi 200ml = 0,2l
→CMHCl=0,20,1=2M
PTHH:
\(Zn+H_2SO_4--->ZnSO_4+H_2\)
\(Cu+H_2SO_4--\times-->\)
a. Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow m_{Zn}=0,1.65=6,5\left(g\right)\)
\(\Rightarrow\%_{m_{Zn}}=\dfrac{6,5}{19,3}.100\%=33,7\%\)
\(\%_{m_{Cu}}=100\%-33,7\%=66,3\%\)
b. Theo PT: \(n_{H_2SO_4}=n_{Zn}=0,1\left(mol\right)\)
Đổi 200ml = 0,2 lít
\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,1}{0,2}=0,5M\)
c. Ta có: \(V_{dd_{ZnSO_4}}=V_{dd_{H_2SO_4}}=0,2\left(lít\right)\)
Theo PT: \(n_{ZnSO_4}=n_{Zn}=0,1\left(mol\right)\)
\(\Rightarrow C_{M_{ZnSO_4}}=\dfrac{0,1}{0,2}=0,5M\)
PTHH\(Na_2CO_3+2HCl\rightarrow2NaCl+H_2O+CO_2\)
tl............1................2.............2.............1.............1..(mol
br 0,1.................0,2......................................0,1(mol)
NaCl không phản ứng đc vsHCl
b)\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(C_{MHCl}=\dfrac{0,2}{0,4}=0,5\left(M\right)\)(đổi 400ml=0,4(l))
c)\(Tacom_{Na_2CO_3}=0,1.106=10,6\left(g\right)\)
\(\Rightarrow\%m_{Na_2CO_3}=\dfrac{10,6}{20}.100=53\%\)
\(\Rightarrow\%mNaCl=100\%-53\%=47\%\)
a, PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(MgO+H_2SO_4\rightarrow MgSO_4+H_2O\)
Ta có: \(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,4\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,4.27}{14,8}.100\%\approx72,97\%\\\%m_{MgO}\approx27,03\%\end{matrix}\right.\)
b, Ta có: \(n_{MgO}=\dfrac{14,8-0,4.27}{40}=0,1\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{H_2}+n_{MgO}=0,7\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}=0,7.98=68,6\left(g\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{68,6}{10\%}=686\left(g\right)\)
c, Theo PT: \(\left\{{}\begin{matrix}n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=0,2\left(mol\right)\\n_{MgSO_4}=n_{MgO}=0,1\left(mol\right)\end{matrix}\right.\)
Ta có: m dd sau pư = 14,8 + 686 - 0,6.2 = 699,6 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{Al_2\left(SO_4\right)_3}=\dfrac{0,2.342}{699,6}.100\%\approx9,78\%\\C\%_{MgSO_4}=\dfrac{0,1.120}{699,6}.100\%\approx1,72\%\end{matrix}\right.\)
a, \(Na_2CO_3+2HCl\rightarrow2NaCl+CO_2+H_2O\)
b, \(n_{CO_2}=\dfrac{0,896}{22,4}=0,04\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{CO_2}=0,08\left(mol\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{0,08}{0,2}=0,4\left(M\right)\)
c, \(n_{Na_2CO_3}=0,04\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Na_2CO_3}=\dfrac{0,04.106}{10}.100\%=42,4\%\\\%m_{NaCl}=57,6\%\end{matrix}\right.\)
Chỉ có Na2CO3 phản ứng với dung dịch HCl nên chắc chắn khí đó là CO2
=> nCO2=V/22,4=1,12/22,4=0,05(mol)
\(PT:Na_2CO_3+2HCl\rightarrow2NaCl+CO_2\uparrow+H_2O\)
Do đó: 0,05<---------0,1<----------0,1<-------0,05(mol)
\(\Rightarrow m_{Na_2CO_3}=n.M=0,05.\left(23.2+12+48\right)=5,3\left(g\right)\)
\(\Rightarrow m_{Na_2SO_4}=m_{hh}-m_{Na_2CO_3}=10-5,3=4,7\left(g\right)\)
b) \(C_{M_{HCl}}=\dfrac{n}{V}=\dfrac{0,1}{0,2}=0,5\left(M\right)\)