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a/ \(n_{KOH}=0,2.1=0,2\left(mol\right);n_{H_2SO_4}=0,3.1=0,3\left(mol\right)\)
PTHH: 2KOH + H2SO4 → K2SO4 + 2H2O
Mol: 0,2 0,1 0,1
Ta có: \(\dfrac{0,2}{2}< \dfrac{0,3}{1}\) ⇒ KOH hết, H2SO4 dư
b/ \(m_{H_2SO_4dư}=\left(0,3-0,1\right).98=19,6\left(g\right)\)
c/ Vdd sau pứ = 0,2 + 0,3 = 0,5 (l)
d/ \(C_{M_{ddK_2SO_4}}=\dfrac{0,1}{0,5}=0,2M\)
\(C_{M_{ddH_2SO_4dư}}=\dfrac{0,3-0,1}{0,5}=0,4M\)
PTHH: \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
Ta có: \(n_{Na_2SO_4}=n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=\dfrac{1}{2}\cdot\dfrac{10}{40}=0,125\left(mol\right)\) \(\Rightarrow\left\{{}\begin{matrix}m_{ddH_2SO_4}=\dfrac{0,125\cdot98}{10\%}=122,5\left(g\right)\\m_{Na_2SO_4}=0,125\cdot142=17,75\left(g\right)\end{matrix}\right.\)
\(\Rightarrow C\%_{Na_2SO_4}=\dfrac{17,75}{10+122,5}\cdot100\%\approx13,4\%\)
a)
$Mg + H_2SO_4 \to MgSO_4 + H-2$
b) $n_{H_2SO_4} = n_{Mg} = \dfrac{4,8}{24} = 0,2(mol)$
$C\%_{H_2SO_4} = \dfrac{0,2.98}{200}.100\% = 9,8\%$
$n_{H_2} = n_{Mg} = 0,2(mol)$
$\Rightarrow m_{dd\ A} = 4,8 + 200 - 0,2.2 = 204,4(gam)$
$C\%_{MgSO_4} = \dfrac{0,2.120}{204,4}.100\% = 11,7\%$
c) $V_{H_2} = 0,2.22,4 = 4,48(lít)$
a)
PTHH :
\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
b)
\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4}=0,1\left(mol\right)\)
\(\Rightarrow m_{\text{dd}H_2SO_4}=\dfrac{0,1\cdot98}{9,8\%}=100\left(g\right)\)
c)
\(m_{\text{dd}\left(sau\right)}=100+6,5-0,1.2=106,3\left(g\right)\)
\(\Rightarrow C\%_{\text{dd}\left(sau\right)}=\dfrac{0,1\cdot161}{106,3}\cdot100\%=15,15\left(\%\right)\)
\(n_{Fe}=\dfrac{11,2}{56}=0,2(mol)\\ Fe+H_2SO_4\to FeSO_4+H_2\\ \Rightarrow n_{H_2SO_4}=n_{FeSO_4}=n_{H_2}=0,2(mol)\\ a,V_{H_2}=0,2.22,4=4,48(l)\\ b,m_{dd_{H_2SO_4}}=\dfrac{0,2.98}{9,8\%}=200(g)\\ c,C\%_{FeSO_4}=\dfrac{0,2.152}{11,2+200-0,2.2}.100\%=14,42\%\)
\(n_{Ba\left(OH\right)_2}=0,5.0,2=0,1\left(mol\right);n_{H_2SO_4}=0,3.0,4=0,12\left(mol\right)\)
PTHH: Ba(OH)2 + H2SO4 → BaSO4↓ + 2H2O
Mol: 0,1 0,1 0,1
Ta có: \(\dfrac{0,1}{1}< \dfrac{0,12}{1}\) ⇒ Ba(OH)2 hết, H2SO4 dư
\(C_{M_{H_2SO_4dư}}=\dfrac{0,12-0,1}{0,2+0,3}=0,04M\)
mdd sau pứ = 200.2,3+300.1,6-0,1.233 = 916,7 (g)
\(C\%_{H_2SO_4dư}=\dfrac{0,02.98.100\%}{916,7}=0,21\%\)