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Đáp án D.
Chất rắn không tan là Cu.
Zn + 2HCl → ZnCl2 + H2
0,2 ← 0,2 (mol)
mZn = 0,2.65 = 13 (g) => mCu = 15 – 13 = 2 (g)
\(n_{Al}=a\left(mol\right),n_{Fe}=b\left(mol\right)\)
\(m_X=27a+56b=11\left(g\right)\left(1\right)\)
\(n_{H_2}=\dfrac{8.96}{22.4}=0.4\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(\Rightarrow a+1.5b=0.4\left(2\right)\)
\(\left(1\right),\left(2\right):a=0.1,b=0.2\)
\(n_{HCl}=2n_{H_2}=2\cdot0.4=0.8\left(mol\right)\)
\(m_{dd_{HCl}}=\dfrac{0.8\cdot36.5\cdot100}{14.6}=200\left(g\right)\)
\(\%Fe=\dfrac{0.1\cdot56}{11}\cdot100\%=50.91\%\)
\(\%Al=49.09\%\)
a) \(n_{AlCl_3}=\dfrac{6,675}{133,5}=0,05\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
0,05<-----------0,05---->0,075
=> \(\%Al=\dfrac{0,05.27}{14,15}.100\%=9,54\%\)
=> \(\%Cu=\dfrac{14,15-0,05.27}{14,15}.100\%=90,46\%\)
b) \(V_{H_2}=0,075.22,4=1,68\left(l\right)\)
c) \(n_{Cu}=\dfrac{14,15-0,05.27}{64}=0,2\left(mol\right)\)
PTHH: 4Al + 3O2 --to--> 2Al2O3
0,05->0,0375
2Cu + O2 --to--> 2CuO
0,2-->0,1
=> \(V_{O_2}=\left(0,1+0,0375\right).22,4=3,08\left(l\right)\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\\ m_{AlCl_3}=6,675\left(mol\right)\\ n_{AlCl_3}=\dfrac{6,675}{133,5}=0,05\left(mol\right)\\ \Rightarrow n_{Al}=n_{AlCl_3}=0,05\left(mol\right)\\ \Rightarrow m_A=0,05.27=1,35\left(g\right);m_{Cu}=14,15-1,35=12,8\left(g\right)\\ \%m_{Cu}=\dfrac{12,8}{14,15}.100\approx90,459\%\\ \Rightarrow\%m_{Al}\approx9,541\%\\ b,n_{Cu}=\dfrac{12,8}{64}=0,2\left(mol\right)\\ n_{H_2}=\dfrac{3}{2}.n_{Al}=\dfrac{3}{2}.0,05=0,075\left(mol\right)\\ \Rightarrow V=V_{H_2\left(đktc\right)}=0,075.22,4=1,68\left(l\right)\\ 4Al+3O_2\rightarrow\left(t^o\right)2Al_2O_3\\ 2Cu+O_2\rightarrow\left(t^o\right)2CuO\\ n_{O_2}=\dfrac{3}{4}.n_{Al}+\dfrac{1}{2}.n_{Cu}=\dfrac{3}{4}.0,05+\dfrac{1}{2}.0,2=0,0875\left(mol\right)\)
\(\Rightarrow V_{O_2\left(đktc\right)}=0,0875.22,4=1,96\left(l\right)\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\\ n_{H_2}=\dfrac{7,437}{24,79}=0,3\left(mol\right)\\ n_{Al}=\dfrac{2}{3}.0,3=0,2\left(mol\right)\\ m_{rắn}=m_{Cu}=m_{hh}-m_{Al}=12-0,2.27=6,4\left(g\right)\)