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nFe = 5.6/56 = 0.1 (mol)
nHCl = 0.2*2 = 0.4 (mol)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
LTL : 0.1/1 < 0.4/2 => HCl dư
mHCl dư = ( 0.4 - 0.2 ) * 36.5 = 7.3 (g)
VH2 = 0.2*22.4 = 4.48 (l)
CM FeCl2 = 0.1/0.2 = 0.5(M)
CM HCl dư = 0.2 / 0.2 = 1(M)
nAl = 5.4 / 27 = 0.2 (mol)
2Al + 6HCl => 2AlCl3 + 3H2
0.2......0.6............0.2.......0.3
a) VH2 = 0.3 * 22.4 = 6.72 (l)
b) mAlCl3 = 0.2 * 133.5 = 26.7 (g)
c) VddHCl = 0.6 / 1.5 = 0.4 (l)
d) CMAlCl3 = 0.2 / 0.4 = 0.5 (M)
PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,6\left(mol\right)\\n_{AlCl_3}=0,2\left(mol\right)\\n_{H_2}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\\m_{AlCl_3}=0,2\cdot133,5=26,7\left(g\right)\\V_{HCl}=\dfrac{0,6}{1,5}=0,4\left(l\right)=400\left(ml\right)\\C_{M_{AlCl_3}}=\dfrac{0,2}{0,4}=0,5\left(M\right)\end{matrix}\right.\)
\(n_{HCl}=0,2.2=0,4\left(mol\right)\\ PTHH:Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{Fe}=n_{H_2}=n_{FeCl_2}=\dfrac{0,4}{2}=0,2\left(mol\right)\\ a,m_{Fe}=0,2.56=11,2\left(g\right)\\ b,V_{H_2\left(đktc\right)}=0,2.22,4=4,48\left(l\right)\\ c,V_{ddFeCl_2}=V_{ddHCl}=0,2\left(l\right)\\ C_{MddFeCl_2}=\dfrac{0,2}{0,2}=1\left(M\right)\)
\(a,n_{HCl}=0,1.1=0,1\left(mol\right)\\ n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH: Fe + 2HCl ---> FeCl2 + H2
LTL: \(0,1>\dfrac{0,1}{2}\) => Fe dư
Theo pthh: \(n_{H_2}=n_{FeCl_2}=n_{Fe\left(pư\right)}=\dfrac{1}{2}n_{HCl}=\dfrac{1}{2}.0,1=0,05\left(mol\right)\)
=> VH2 = 0,05.22,4 = 1,12 (l)
b, Chất dư là Fe
mFe (dư) = (0,1 - 0,05).56 = 2,8 (g)
c, \(C_{M\left(FeCl_2\right)}=\dfrac{0,05}{0,1}=0,5M\)
\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\ PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\\ n_{AlCl_3}=n_{Al}=0,1\left(mol\right)\\ a,m_{AlCl_3}=133,5.0,1=13,35\left(g\right)\\ n_{H_2}=\dfrac{3}{2}.0,1=0,15\left(mol\right)\\ b,V_{H_2\left(đktc\right)}=0,15.22,4=3,36\left(l\right)\\ c,n_{HCl}=\dfrac{6}{2}.0,1=0,3\left(mol\right)\\ c,C_{MddHCl}=\dfrac{0,3}{0,2}=1,5\left(M\right)\)
\(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\\ PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{ZnCl_2}=n_{Zn}=n_{H_2}=0,15\left(mol\right);n_{HCl}=2.0,15=0,3\left(mol\right)\\ a,m=m_{Zn}=0,15.65=9,75\left(g\right)\\ b,C_{MddHCl}=\dfrac{0,3}{0,15}=0,2\left(l\right)\\ c,m_{ZnCl_2}=0,15.136=20,4\left(g\right)\)
a. Đổi 200 ml = 0,2 lít
\(n_{Fe}=\dfrac{11.2}{56}=0,2\left(mol\right)\)
\(n_{HCl}=2.0,2=0,2\left(mol\right)\)
PTHH : Fe + 2HCl -> FeCl2 + H2
0,1 0,2 0,1 0,1
Ta thấy : \(\dfrac{0.2}{1}>\dfrac{0.2}{2}\) => Fe dư , HCl đủ
\(m_{Fe\left(dư\right)}=\left(0,2-0,1\right).56=5,6\left(g\right)\)
b. \(V_{H_2}=0,1.22,4=2,24\left(l\right)\)
c. Sau phản ứng chất tan là FeCl2
\(V_{FeCl_2}=0,1.2=0,2\left(l\right)\)
\(\Rightarrow C_{M_{FeCl_2}}=\dfrac{0.1}{0,2}=0,5\left(M\right)\)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,2\left(mol\right)\\n_{FeCl_2}=0,1\left(mol\right)=n_{H_2}\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,1\cdot22,4=2,24\left(l\right)\\m_{FeCl_2}=0,1\cdot127=12,7\left(g\right)\\C_{M_{FeCl_2}}=\dfrac{0,1}{0,1}=1\left(M\right)\\C_{M_{HCl}}=\dfrac{0,2}{0,1}=2\left(M\right)\end{matrix}\right.\)