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10 tháng 2 2023

a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

Gọi: \(\left\{{}\begin{matrix}n_{Zn}=x\left(mol\right)\\n_{Al}=y\left(mol\right)\end{matrix}\right.\) ⇒ 65x + 27y = 17,05 (1)

Ta có: \(n_{H_2}=\dfrac{9,52}{22,4}=0,425\left(mol\right)\)

Theo PT: \(n_{H_2}=n_{Zn}+\dfrac{3}{2}n_{Al}=x+\dfrac{3}{2}y=0,425\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Zn}=0,2\left(mol\right)\\n_{Al}=0,15\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{Zn}=0,2.65=13\left(g\right)\\m_{Al}=0,15.27=4,05\left(g\right)\end{matrix}\right.\)

b, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\\n_{AlCl_3}=n_{Al}=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{ZnCl_2}}=\dfrac{0,2}{0,5}=0,4\left(M\right)\\C_{M_{AlCl_3}}=\dfrac{0,15}{0,5}=0,3\left(M\right)\end{matrix}\right.\)

c, Ta có: m dd HCl = 1,05.500 = 525 (g)

m dd sau pư = mhh + m dd HCl - mH2 = 541,2 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,2.136}{541,2}.100\%\approx5,03\%\\C\%_{AlCl_3}=\dfrac{0,15.133,5}{541,2}.100\%\approx3,7\%\end{matrix}\right.\)

28 tháng 4 2022

a.\(n_{H_2}=\dfrac{7,28}{22,4}=0,325mol\)

Gọi \(\left\{{}\begin{matrix}n_{Al}=x\\n_{Zn}=y\end{matrix}\right.\) \(\left(mol\right)\)  \(\rightarrow27x+65y=10,55\left(g\right)\) (1)

\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

 x                                 1/2 x          3/2 x       ( mol )

\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)

 y                            y               y     ( mol )

\(\rightarrow\dfrac{3}{2}x+y=0,325\left(mol\right)\) (2)

\(\left(1\right);\left(2\right)\rightarrow\left\{{}\begin{matrix}x=0,15\\y=0,1\end{matrix}\right.\)

\(\rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,15.27}{10,55}.100\%=38,38\%\\\%m_{Zn}=100\%-38,38\%=61,62\%\end{matrix}\right.\)

b.\(\left\{{}\begin{matrix}n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}.0,15=0,075\\n_{ZnSO_4}=0,1\end{matrix}\right.\) ( mol )

\(\left\{{}\begin{matrix}C_{M_{Al_2\left(SO_4\right)_3}}=\dfrac{0,075}{0,8}=0,09M\\C_{M_{ZnSO_4}}=\dfrac{0,1}{0,8}=0,125M\end{matrix}\right.\)

19 tháng 1 2022

$a)PTHH:2Al+6HCl\to 2AlCl_3+3H_2$

$n_{H_2}=\dfrac{5,04}{22,4}=0,225(mol)$

$\Rightarrow n_{Al}=0,15(mol)$

$\Rightarrow \%m_{Al}=\dfrac{0,15.27}{9,45}.100\%\approx 42,86\%$

$\Rightarrow \%m_{Cu}=100-42,86=57,14\%$

$b)$ Theo PT: $n_{HCl}=2n_{H_2}=0,45(mol)$

$\Rightarrow C_{M_{HCl}}=\dfrac{0,45.110\%}{0,5}=0,99M$

25 tháng 12 2023

a, Ta có: 27nAl + 56nFe = 22 (1)

PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}+n_{Fe}=\dfrac{19,832}{24,79}=0,8\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}m_{Al}=0,4\left(mol\right)\\n_{Fe}=0,2\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,4.27}{22}.100\%\approx49,09\%\\\%m_{Fe}\approx50,91\%\end{matrix}\right.\)

b, \(n_{HCl}=2n_{H_2}=1,6\left(mol\right)\)

\(\Rightarrow C_{M_{HCl}}=\dfrac{1,6}{0,5}=3,2\left(M\right)\)

15 tháng 9 2017

a) PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)

                   a_____2a______a_____a      (mol)

                \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)

                    b_____3b_______b_____\(\dfrac{3}{2}\)b         (mol)

Ta lập HPT: \(\left\{{}\begin{matrix}56a+27b=36,1\\a+\dfrac{3}{2}b=\dfrac{21,28}{22,4}=0,95\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,5\\b=0,3\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,5\cdot56=28\left(g\right)\\m_{Al}=8,1\left(g\right)\end{matrix}\right.\)

b+c) Theo các PTHH: \(\left\{{}\begin{matrix}n_{HCl}=2a+3b=1,9\left(mol\right)\\n_{FeCl_2}=0,5\left(mol\right)\\n_{AlCl_3}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{HCl}}=\dfrac{1,9}{0,2}=9,5\left(M\right)\\C_{M_{FeCl_2}}=\dfrac{0,5}{0,2}=2,5\left(M\right)\\C_{M_{AlCl_3}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\end{matrix}\right.\)

1 tháng 4 2021

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13 tháng 4 2022

a) Do dd sau pư có 3 chát tan với nồng độ % bằng nhau

=> \(m_{Al_2\left(SO_4\right)_3}=m_{ZnSO_4}=m_{H_2SO_4\left(dư\right)}\)

Gọi số mol Al, Zn là a, b (mol)

PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2

             a----->1,5a------->0,5a----->1,5a

            Zn + H2SO4 --> ZnSO4 + H2

             b----->b--------->b----->b

=> \(\left\{{}\begin{matrix}m_{Al_2\left(SO_4\right)_3}=342.0,5a=171a\left(g\right)\\m_{ZnSO_4}=161b\left(g\right)\end{matrix}\right.\)

=> 171a = 161b 

=> \(\dfrac{a}{b}=\dfrac{161}{171}\) (1)

Có: \(\dfrac{m_{Al}}{m_{Zn}}=\dfrac{27.n_{Al}}{65.n_{Zn}}=\dfrac{27}{65}.\dfrac{161}{171}=\dfrac{483}{1235}\)

b) \(n_{H_2}=1,5a+b=\dfrac{11,2}{22,4}=0,5\left(mol\right)\) (2)

(1)(2) => \(\left\{{}\begin{matrix}a=\dfrac{161}{825}\left(mol\right)\\b=\dfrac{57}{275}\left(mol\right)\end{matrix}\right.\)

=> \(x=\dfrac{161}{825}.27+\dfrac{57}{275}.65=\dfrac{5154}{275}\left(g\right)\)

\(m_{H_2SO_4\left(dư\right)}=m_{Al_2\left(SO_4\right)_3}=342.0,5\dfrac{161}{825}=\dfrac{9177}{275}\left(g\right)\)

=> \(m_{H_2SO_4\left(bđ\right)}=98\left(1,5a+b\right)+\dfrac{9177}{275}=\dfrac{22652}{275}\left(g\right)\)

=> \(y=\dfrac{\dfrac{22652}{275}.100}{10}=\dfrac{45304}{55}\left(g\right)\)