Hòa tan hoàn toàn 2,4 gam Fe vào dd HCl 14,6%. Tính khối lượng dd HCl đã dùng? Tính nồng độ phần trăm dd sau pư?
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a) $CaSO_3 + 2HCl \to CaCl_2 + SO_2 + H_2O$
b)
$n_{SO_2} = n_{CaSO_3} = \dfrac{12}{120} = 0,1(mol)$
$m_{SO_2} = 0,1.64 = 6,4(gam)$
c)
$n_{HCl} = 2n_{SO_2} = 0,2(mol)$
$\Rightarrow m_{dd\ HCl} = \dfrac{0,2.36,5}{14,6\%} = 50(gam)$
d)
$m_{dd\ sau\ pư} = m_{CaSO_3} + m_{dd\ HCl} - m_{SO_2} = 12 + 50 - 6,4 = 55,6(gam)$
$C\%_{CaCl_2} = \dfrac{0,1.111}{55,6}.100\% = 19,96\%$
Ta có: \(n_{CaSO_3}=\dfrac{12}{120}=0,1\left(mol\right)\)
a. PTHH: CaSO3 + 2HCl ---> CaCl2 + H2O + SO2
b. Theo PT: \(n_{SO_2}=n_{CaSO_3}=0,1\left(mol\right)\)
=> \(m_{SO_2}=0,1.64=6,4\left(g\right)\)
c. Theo PT: \(n_{HCl}=2.n_{CaSO_3}=2.0,1=0,2\left(mol\right)\)
=> \(m_{HCl}=0,2.36,5=7,3\left(g\right)\)
Ta có: \(C_{\%_{HCl}}=\dfrac{7,3}{m_{dd_{HCl}}}.100\%=14,6\%\)
=> \(m_{dd_{HCl}}=50\left(g\right)\)
d. Ta có: \(m_{dd_{CaCl_2}}=12+50-0,1.64=55,6\left(g\right)\)
Theo PT: \(n_{CaCl_2}=n_{SO_2}=0,1\left(mol\right)\)
=> \(m_{CaCl_2}=0,1.111=11,1\left(g\right)\)
=> \(C_{\%_{CaCl_2}}=\dfrac{11,1}{55,6}.100\%=19,96\%\)
nAl= 0,5(mol)
a) PTHH: 2 Al + 6 HCl -> 2 AlCl3 + 3 H2
nHCl= 6/2 . 0,5= 1,5(mol)
=>mHCl= 1,5.36,5=54,75(mol)
=> mddHCl= (54,75.100)/18,25=300(g)
b) nH2= 3/2. 0,5=0,75(mol)
=>V(H2,đktc)=0,75.22,4=16,8(l)
c) nAlCl3= nAl= 0,5(mol) -> mAlCl3=0,5. 133,5=66,75(g)
mddAlCl3=mAl+ mddHCl - mH2= 13,5 + 300-0,75.2=312(g)
=> \(C\%ddAlCl3=\dfrac{66,75}{312}.100\approx21,394\%\)
\(n_{Fe}=\dfrac{11.2}{56}=0.2\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(0.2...................0.2..........0.2\)
\(V_{H_2}=0.2\cdot22.4=4.48\left(l\right)\)
\(m_{FeCl_2}=0.2\cdot127=25.4\left(g\right)\)
\(m_{\text{dung dịch sau phản ứng}}=11.2+200-0.2\cdot2=210.8\left(g\right)\)
\(C\%_{FeCl_2}=\dfrac{25.4}{210.8}\cdot100\%=12.05\%\)
\(n_{Zn}=\dfrac{4,55}{65}=0,07(mol)\\ Zn+2HCl\to ZnCl_2+H_2\\ a,n_{HCl}=0,14(mol)\\ \Rightarrow C_{M_{HCl}}=\dfrac{0,14}{0,2}=0,7M\\ b,n_{H_2}=0,07(mol)\\ \Rightarrow V_{H_2}=0,07.22,4=1,568(l)\\ c,n_{ZnCl_2}=0,07(mol)\\ \Rightarrow m_{ZnCl_2}=0,07.136=9,52(g)\\ c,ZnCl_2+2AgNO_3\to 2AgCl\downarrow+Zn(NO_3)_2\)
\(m_{dd_{ZnCl_2}}=200.0,8+4,55-0,07.2=164,41(g)\\ n_{AgCl}=0,14(mol);n_{Zn(NO_3)_2}=0,07(mol)\\ \Rightarrow C\%_{Zn(NO_3)_2}=\dfrac{0,07.189}{164,41+200-0,14.143,5}.100\%=3,84%\)
PTHH
Mg + 2HCl ----> MgCl2 + H2 (1)
MgO + 2HCl -----> MgCl2 + H2O (2)
a) Theo pt(1) n Mg = n H2 = \(\frac{1,12}{22,4}\) = 0,05 (mol)
==> m Mg = 0,005 . 24=1,2 (g)
%m Mg = \(\frac{1,2}{3,2}\). 100%= 37,5%
%m MgO= 100% - 37,5%= 62,5%
b)m dd sau pư = 3,2 + 246,9 - 0,05 . 2=250 (g)
Theo pt(1)(2) n MgCl2(1) = n Mg = 0,05 mol
n MgCl2 (2) = n MgO=\(\frac{3,2-1,2}{40}\)=0,05(mol)
==> tổng n MgCl2 = 0,1 (mol) ---->m MgCl2 = 9,5 (g)
C%(MgCl2)= \(\frac{9,5}{250}\) .100% = 3,8%
1.
\(\%C=\dfrac{12}{44}.100\simeq22,73\%\)
2.
\(n_{Fe}=\dfrac{2,8}{56}=0,05\left(mol\right)\\ PTHH:Fe+2HCl\rightarrow FeCl_2+H_2\\ V=\dfrac{n}{C_M}=\dfrac{0,1}{2}=0,05\left(M\right)\)
\(C_{M\left(FeCl_2\right)}=\dfrac{n}{V}=\dfrac{0,05}{0,05}=1\left(M\right)\)
\(n_{Zn}=\dfrac{26}{65}=0,4\left(mol\right)\)
Pt : \(Zn+2HCl\rightarrow ZnCl_2+H_2|\)
1 2 1 1
0,4 0,8 0,4 0,4
a) \(n_{H2}=\dfrac{0,4.1}{1}=0,4\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,4.22,4=8,96\left(l\right)\)
b) \(n_{HCl}=\dfrac{0,4.2}{1}=0,8\left(mol\right)\)
⇒ \(m_{HCl}=0,8.36,5=29,2\left(g\right)\)
\(m_{ddHCl}=\dfrac{29,2.100}{14,6}=200\left(g\right)\)
c) \(n_{ZnCl2}=\dfrac{0,4.1}{1}=0,4\left(mol\right)\)
⇒ \(m_{ZnCl2}=0,4.136=54,4\left(g\right)\)
\(m_{ddspu}=26+200-\left(0,4.2\right)=225,2\left(g\right)\)
\(C_{ZnCl2}=\dfrac{54,4.100}{225,2}=24,16\)0/0
Chúc bạn học tốt
\(\text{Đặt }n_{Al}=x(mol);n_{Fe}=y(mol)\\ \Rightarrow 27x+56y=13,9(1)\\ n_{H_2}=\dfrac{7,84}{22,4}=0,35(mol)\\ a,PTHH:2Al+6HCl\to 2AlCl_3+3H_2(1)\\ Fe+2HCl\to FeCl_2+H_2(2)\\ b,\text{Từ 2 PT: }1,5x+y=0,35(2)\\ (1)(2)\Rightarrow x=0,1(mol);y=0,2(mol)\\ \Rightarrow m_{Al}=0,1.27=2,7(g)\\ m_{Fe}=0,2.56=11,2(g)\)
\(c,n_{HCl(1)}=3n_{Al}=0,3(mol);n_{AlCl_3}=0,1(mol);n_{H_2(1)}=0,15(mol)\\ \Rightarrow m_{dd_{HCl(1)}}=\dfrac{0,3.36,5}{14,6\%}=75(g)\\ \Rightarrow C\%_{AlCl_3}=\dfrac{0,1.133,5}{2,7+75-0,15.2}.100\%=17,25\%\)
\(n_{HCl(2)}=2n_{Fe}=0,4(mol);n_{FeCl_2}=n_{H_2(2)}=n_{Fe}=0,2(mol)\\ \Rightarrow m{dd_{HCl(2)}}=\dfrac{0,4.36,5}{14,6\%}=100(g)\\ \Rightarrow C\%_{FeCl_2}=\dfrac{0,2.127}{11,2+100-0,2.2}.100\%=22,92\%\)
a) 2Al + 6HCl --> 2AlCl3 + 3H2
Fe + 2HCl --> FeCl2 + H2
b) Gọi số mol Al, Fe lần lượt là a,b
=> 27a + 56b = 13,9
\(n_{H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\)
2Al + 6HCl --> 2AlCl3 + 3H2
a----->3a--------->a------->1,5a______(mol)
Fe + 2HCl --> FeCl2 + H2
b------>2b-------->b----->b__________(mol)
=> 1,5a + b = 0,35
=> \(\left\{{}\begin{matrix}a=0,1=>m_{Al}=0,1.27=2,7\left(g\right)\\b=0,2=>m_{Fe}=0,2.56=11,2\left(g\right)\end{matrix}\right.\)
c) nHCl = 3a + 2b = 0,7 (mol)
=> mHCl = 0,7.36,5 = 25,55(g)
=> \(m_{ddHCl}=\dfrac{25,55.100}{14,6}=175\left(g\right)\)
\(m_{dd\left(saupu\right)}=13,9+175-2.0,35=188,2\left(g\right)\)
\(\left\{{}\begin{matrix}m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\\m_{FeCl_2}=0,2.127=25,4\left(g\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}C\%\left(AlCl_3\right)=\dfrac{13,35}{188,2}.100\%=7,1\%\\C\%\left(FeCl_2\right)=\dfrac{25,4}{188,2}.100\%=13,5\%\end{matrix}\right.\)
a)
$Zn + 2HCl \to ZnCl_2 + H_2$
$n_{ZnCl_2} = n_{Zn} = \dfrac{6,5}{65} = 0,1(mol)$
$m_{ZnCl_2} = 0,1.136 = 13,6(gam)$
b)
$n_{HCl} = 2n_{Zn} = 0,2(mol) \Rightarrow C_{M_{HCl}} = \dfrac{0,2}{0,1} = 2M$
c)
CuO + H_2 \to Cu + H_2O$
$n_{CuO} = 0,125(mol) > n_{H_2} \to $ CuO$ dư
$n_{Cu} = n_{CuO\ pư} = n_{H_2} = 0,1(mol)$
$n_{CuO\ dư} = 0,125 - 0,1 = 0,025(mol)$
$\%m_{Cu} = \dfrac{0,1.64}{0,1.64 + 0,025.80}.100\% = 76,2\%$
$\%m_{CuO} = 23,8\%$
)
Zn+2HCl→ZnCl2+H2Zn+2HCl→ZnCl2+H2
nZnCl2=nZn=6,565=0,1(mol)nZnCl2=nZn=6,565=0,1(mol)
mZnCl2=0,1.136=13,6(gam)mZnCl2=0,1.136=13,6(gam)
b)
nHCl=2nZn=0,2(mol)⇒CMHCl=0,20,1=2MnHCl=2nZn=0,2(mol)⇒CMHCl=0,20,1=2M
c)
CuO + H_2 \to Cu + H_2O$
nCuO=0,125(mol)>nH2→nCuO=0,125(mol)>nH2→ CuO$ dư
nCu=nCuO pư=nH2=0,1(mol)nCu=nCuO pư=nH2=0,1(mol)
nCuO dư=0,125−0,1=0,025(mol)nCuO dư=0,125−0,1=0,025(mol)
%mCu=0,1.640,1.64+0,025.80.100%=76,2%%mCu=0,1.640,1.64+0,025.80.100%=76,2%
%mCuO=23,8%
Sửa thành 2,24 gam cho số đẹp bạn nhé!
Ta có: \(n_{Fe}=\dfrac{2,24}{56}=0,04\left(mol\right)\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
___0,04__0,08____0,04__0,04 (mol)
Ta có: \(m_{HCl}=0,08.36,5=2,92\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{2,92}{14,6\%}=20\left(g\right)\)
Ta có: m dd sau pư = mFe + m dd HCl - mH2 = 2,24 + 20 - 0,04.2 = 22,16 (g)
\(\Rightarrow C\%_{FeCl_2}=\dfrac{0,04.127}{22,16}.100\%\approx22,9\%\)
Bạn tham khảo nhé!