đốt cháy 3,5gam kim loại hóa trị I trong khí O2 thu được 7,5 gam oxit. Tìm kim loại hóa trị I
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gọi CTHH đơn giản là \(M_XO_y\)
vì M hóa trị III nên áp dụng QTHT => CTHH: M2O3
\(PTHH:4M+3O_2-^{t^o}>2M_2O_3\)
0,1<---0,075----->0,05 (mol)
áp dụng ĐLBTKL ta có
\(m_M+m_{O_2}=m_{M_2O_3}\\ =>2,7+m_{O_2}=5,1\\ =>m_{O_2}=2,4\left(g\right)\)
\(n_{O_2}=\dfrac{m}{M}=\dfrac{2,4}{32}=0,075\left(mol\right)\)
\(M_M=\dfrac{m}{n}=\dfrac{2,7}{0,1}=27\left(g/mol\right)\)
=> M là nhôm (Al)
Bảo toàn khối lượng: mO2 = mRO - mR = 32,4 - 26 = 6,4 (g)
\(n_{O_2}=\dfrac{6,4}{32}=0,2\left(mol\right)\)
PTHH: 2R + O2 --to--> 2RO
\(M_R=\dfrac{26}{0,2}=65\left(\dfrac{g}{mol}\right)\)
=> R là Zn
\(4M+O_2\rightarrow\left(t^o\right)2M_2O\\ n_{O_2}=\dfrac{0,672}{22,4}=0,03\left(mol\right)\\ n_{oxit}=2.0,03=0,06\left(mol\right)\\ M_{oxit}=2M_M+16=\dfrac{3,72}{0,06}=62\left(\dfrac{g}{mol}\right)\\ \Leftrightarrow M_M=\dfrac{62-16}{2}=23\left(\dfrac{g}{mol}\right)\left(M:Natri\left(Na=23\right)\right)\)
\(4A+nO_2 \xrightarrow{t^{o}} 2A_2O_n\\ Cách 1:\\ BTKL:\\ m_A+m_{O_2}=m_{A_2O_n}\\ 6,4+m_{O_2}=8\\ m_{O_2}=1,6(g)\\ \to n_{O_2}=0,05(mol)\\ n_A=\frac{0,2}{n}(mol)\\ M_A=\frac{6,4.n}{0,2}=32.n\\ n=2; A=64\\ \to Cu\\ Cách 2:\\ n_A=a(mol)\\ \to n_{A_2O_n}=0,5a(mol)\\ \frac{a.A}{0,5a.(2A+16n)}=\frac{6,4}{8}\\ \to \frac{A}{0,5(.2A+16n)}=\frac{6,4}{8}\\ A=32.n n=2; A=64\\ \to Cu\\\)
a, PT: \(4M+3O_2\underrightarrow{t^o}2M_2O_3\)
Ta có: \(n_M=\dfrac{10,8}{M_M}\left(mol\right)\)
\(n_{M_2O_3}=\dfrac{20,4}{2M_M+16.3}\left(mol\right)\)
Theo PT: \(n_M=2n_{M_2O_3}\Rightarrow\dfrac{10,8}{M_M}=2.\dfrac{20,4}{2M_M+16.3}\)
\(\Rightarrow M_M=27\left(g/mol\right)\)
→ M là Nhôm (Al)
b, Ta có: \(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{3}{4}n_{Al}=0,3\left(mol\right)\) \(\Rightarrow V_{O_2}=0,3.22,4=6,72\left(l\right)\)
\(\Rightarrow V_{kk}=\dfrac{V_{O_2}}{20\%}=33,6\left(l\right)\)
c, PT: \(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)
\(n_{Al_2O_3}=\dfrac{1}{2}n_{Al}=0,2\left(mol\right)\)
\(n_{HCl}=6n_{Al_2O_3}=1,2\left(mol\right)\)
\(\Rightarrow V_{ddHCl}=\dfrac{1,2}{2}=0,6\left(l\right)\)
d, PT: \(Al_2O_3+2NaOH\rightarrow2NaAlO_2+H_2O\)
Theo PT: \(n_{NaOH}=2n_{Al_2O_3}=0,4\left(mol\right)\)
\(\Rightarrow m_{NaOH}=0,4.40=16\left(g\right)\Rightarrow m_{ddNaOH}=\dfrac{16}{25\%}=64\left(g\right)\)
\(\Rightarrow V_{ddNaOH}=\dfrac{64}{1,25}=51,2\left(ml\right)\)
\(a,PTHH:4A+3O_2\underrightarrow{t^o}2A_2O_3\\ Áp.dụng.ĐLBTKL,ta.có:\\ m_A+m_{O_2}=m_{A_2O_3}\\ \Rightarrow m_{O_2}=m_{A_2O_3}-m_A=20,4-10,8=9,6\left(g\right)\)
\(\Rightarrow n_{O_2}=\dfrac{m}{M}=\dfrac{9,6}{32}=0,3\left(mol\right)\\ Theo.PTHH:n_A=\dfrac{4}{3}.n_{O_2}=\dfrac{4}{3}.0,3=0,4\left(mol\right)\\ \Rightarrow M_A=\dfrac{m}{n}=\dfrac{10,8}{0,4}=27\left(\dfrac{g}{mol}\right)\\ \Rightarrow A.là.Al\left(nhôm\right)\)
\(b,V_{O_2\left(đktc\right)}=n.22,4=0,4.22,4=8,96\left(l\right)\\ \Rightarrow V_{kk\left(đktc\right)}=V_{O_2\left(đktc\right)}.5=8,96.5=44,8\left(l\right)\)
\(a,4A+3O_2\rightarrow\left(t^o\right)2A_2O_3\\ Theo.ĐLBTKL:\\ m_A+m_{O_2}=m_{A_2O_3}\\ \Leftrightarrow10,8+m_{O_2}=20,4\\ \Leftrightarrow m_{O_2}=9,6\left(g\right)\\ \Rightarrow n_{O_2}=\dfrac{9,6}{32}=0,3\left(mol\right)\\ n_A=\dfrac{4}{3}.0,3=0,4\left(mol\right)\Rightarrow M_A=\dfrac{m_A}{n_A}=\dfrac{10,8}{0,4}=27\left(\dfrac{g}{mol}\right)\\ \Rightarrow A:Nhôm\left(Al=27\right)\\ b,V_{kk\left(đktc\right)}=\dfrac{100}{20}.V_{O_2\left(đktc\right)}=5.\left(0,3.22,4\right)=33,6\left(l\right)\)
Gọi kim loại cần tìm là R
\(n_R=\dfrac{3,5}{M_R}\left(mol\right)\)
PTHH: 4R + O2 --to--> 2R2O
\(\dfrac{3,5}{M_R}\)------------->\(\dfrac{1,75}{M_R}\)
=> \(\dfrac{1,75}{M_R}\left(2.M_R+16\right)=7,5\)
=> MR = 7 (g/mol)
=> R là Li
Gọi kim loại hóa trị I là R
PTHH : 4R + O2 -----to---> 2R2O
0,5 0,125
Theo ĐLBTKL : \(m_R+m_{O_2}=m_{R_2O}\\ \Rightarrow m_{O_2}=7,5-3,5=4\left(g\right)\)
\(n_{O_2}=\dfrac{4}{32}=0,125\left(mol\right)\)
\(M_R=\dfrac{3.5}{0,5}=7\left(\dfrac{g}{mol}\right)\)
Vậy R là Liti