dẫn khí H2 đến dư qua 4 gam bột CuO nóng. Hãy tính khối lượng Cu sinh ra sau phản ứng?
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\(n_{Zn}=\dfrac{m}{M}=\dfrac{3,25}{65}=0,05\left(mol\right)\)
\(PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\)
1 2 1 1
0,05 0,1 0,05 0,05
a) \(V_{H_2}=n.24,79=0,05.24,79=1,2395\left(l\right)\)
\(m_{ZnCl_2}=n.M=0,05.\left(65+35,5.2\right)=6,8\left(g\right)\)
b) \(PTHH:CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Ta cos tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,05}{1}\Rightarrow\) CuO dư.
Theo ptr, ta có: \(n_{Cu}=n_{H_2}=0,05mol\\ \Rightarrow m_{Cu}=n.M=0,05.64=3,2\left(g\right).\)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Ta có: \(n_{Zn}=\dfrac{3,25}{65}=0,05\left(mol\right)\)
THeo PT: \(n_{ZnCl_2}=n_{H_2}=n_{Zn}=0,05\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,05.24,79=1,2395\left(l\right)\)
\(m_{ZnCl_2}=0,05.136=6,8\left(g\right)\)
b, Ta có: \(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)
PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,05}{1}\), ta được CuO dư.
Theo PT: \(n_{Cu}=n_{H_2}=0,05\left(mol\right)\Rightarrow m_{Cu}=0,05.64=3,2\left(g\right)\)
\(a.n_{CuO}=\dfrac{40}{80}=0,5\left(mol\right)\\ n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\\ PTHH:CuO+H_2\underrightarrow{t^o}Cu+H_2O\\ Vì:\dfrac{0,15}{1}< \dfrac{0,5}{1}\\ \rightarrow CuOdư\\ n_{CuO\left(p.ứ\right)}=n_{Cu}=n_{H_2}=0,15\left(mol\right)\\ \rightarrow n_{CuO\left(dư\right)}=0,5-0,15=0,35\left(mol\right)\\ m_{CuO\left(DƯ\right)}=0,35.80=28\left(g\right)\\ b.m_{Cu}=0,35.64=22,4\left(g\right)\\ c.m_{hh_{rắn}}=m_{Cu}+m_{CuO\left(dư\right)}=22,4+28=50,4\left(g\right)\)
a) PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
a_____________________\(\dfrac{3}{2}\)a (mol)
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
b____________________b (mol)
Ta lập HPT: \(\left\{{}\begin{matrix}27a+56b=11\\\dfrac{3}{2}a+b=\dfrac{8,96}{22,4}=0,4\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,2\cdot27}{11}\cdot100\%\approx49,09\%\\\%m_{Fe}=50,91\%\end{matrix}\right.\)
b) PTHH: \(CuO+H_2\xrightarrow[]{t^o}Cu+H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\\n_{H_2}=\dfrac{3}{2}a+b=0,4\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) H2 còn dư, tính theo CuO
\(\Rightarrow n_{Cu}=0,2\left(mol\right)\) \(\Rightarrow m_{Cu}=0,2\cdot64=12,8\left(g\right)\)
Gọi n Al = a ( mol ) , n Fe = b ( mol )
Có: n H2 = 0,4 ( mol )
PTHH
2AL + 6HCL ===> 2ALCL3 + 3H2
a--------------------------------------a
Fe + 2HCl ====> FeCL2 + H2
b------------------------------------b
Ta có hpt:
\(\left\{{}\begin{matrix}27a+56b=11\\1,5a+b=0,4\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\)
=> m AL = 5,4 ( g ) ; m Fe = 5,6 ( g )
b) Có : n CuO = 0,2 ( mol )
PTHH:
CuO + H2 ====> Cu +H2O
0,2----0,2-----------0,2
theo pthh: n Cu = 0,2 ( mol ) => m Cu = 12,8 ( g )
\(nAl=\dfrac{8,1}{27}=0,3\left(mol\right)\)
\(nHCl=\dfrac{21,9}{36,5}=0,6\left(mol\right)\)
PTHH:
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
2 6 2 3 (mol)
0,2 0,6 0,2 0,3 (mol)
LTL : 0,3 / 2 > 0,6/6
=> Al dư sau pứ , HCl đủ vs pứ
\(mAl_{\left(dư\right)}=\left(0,3-0,2\right).27=2,7\left(g\right)\)
\(mAlCl_3=0,2.98=19,6\left(g\right)\)
\(H_2+CuO\rightarrow Cu+H_2O\)
1 1 1 1 (mol)
0,3 0,3 0,3 0,3 (mol)
=> \(mCu=0,3.64=19,2\left(g\right)\)
\(n_{Al}=\dfrac{8,1}{27}=0,3\left(mol\right)\\
n_{HCl}=\dfrac{21,9}{36,5}=0,6\left(mol\right)\\
pthh:2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
\(LTL:\dfrac{0,3}{2}>\dfrac{0,6}{6}\)
=> Al dư HCl hết
theo pthh : \(n_{Al\left(p\text{ư}\right)}=\dfrac{1}{3}n_{HCl}=0,2\left(mol\right)\\ m_{Al\left(d\right)}=\left(0,3-0,2\right).27=2,7\left(g\right)\)
theo pthh : \(n_{AlCl_3}=\dfrac{1}{3}n_{HCl}=0,1\left(mol\right)\\
m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\)
theo pthh : \(n_{H_2}=\dfrac{1}{2}n_{HCl}=0,3\left(mol\right)\)
pthh: \(CuO+H_2\underrightarrow{t^o}H_2O+Cu\)
0,3 0,3
\(m_{Cu}=0,3.64=19,2\)
\(n_{Al}=\dfrac{16,2}{27}=0,6\left(mol\right)\)
2Al + 3H2SO4 ---> Al2(SO4)3 + 3H2
0,6 0,9 0,3 0,9
\(\rightarrow V_{H_2}=0,9.22,4=20,16\left(l\right)\)
\(n_{Cu}=\dfrac{57}{64}=0,890625\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
0,890625 0,890625
\(H=\dfrac{0,890625}{0,9}=99\%\)
\(n_{Zn}=\dfrac{19.5}{65}=0.3\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{98}{98}=1\left(mol\right)\)
\(n_{CuO}=\dfrac{36}{80}=0.45\left(mol\right)\)
\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
\(0.3.....................................0.3\)
\(CuO+H_2\underrightarrow{t^0}Cu+H_2O\)
\(0.3.......0.3.....0.3....0.3\)
\(m_{Cr}=m_{CuO\left(dư\right)}+m_{Cu}=\left(0.45-0.3\right)\cdot80+0.3\cdot64=31.2\left(g\right)\)
\(m_{H_2O}=0.3\cdot18=5.4\left(g\right)\)
Chúc em học tốt !!
Zn+H2SO4→ZnSO4+H2 bạn biến đổi nó ra phương trình này kiểu gì vậy?
\(n_{Fe}=\dfrac{16.8}{56}=0.3\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(0.3....................0.3.........0.3\)
\(m_{FeCl_2}=0.3\cdot127=38.1\left(g\right)\)
\(V_{H_2}=0.6\cdot22.4=6.72\left(l\right)\)
\(CuO+H_2\underrightarrow{t^0}Cu+H_2O\)
\(.......0.3...0.3\)
\(m_{Cu}=0.3\cdot64=19.2\left(g\right)\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
a, Ta có: \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
Theo PT: \(n_{FeCl_2}=n_{Fe}=0,3\left(mol\right)\)
\(\Rightarrow m_{FeCl_2}=0,3.127=38,1\left(g\right)\)
b, Theo PT: \(n_{H_2}=n_{Fe}=0,3\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,3.22,4=6,72\left(l\right)\)
c, PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Theo PT: \(n_{Cu}=n_{H_2}=0,3\left(mol\right)\)
\(\Rightarrow m_{Cu}=0,3.64=19,2\left(g\right)\)
Bạn tham khảo nhé!
Số mol của khí hidro ở dktc
nH2 = \(\dfrac{V_{H2}}{22,4}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Pt : Fe + 2HCl → FeCl2 + H2\(|\)
1 2 1 1
0,2 0,2
a) Số mol của sắt
nFe = \(\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
Khối lượng của sắt
mFe = nFe .MFe
= 0,2. 56
= 11,2 (g)
Khối lượng của đồng
mCu = 17,6 - 11,2
= 6,4 (g)
0/0Fe = \(\dfrac{m_{Fe}.100}{m_{hh}}=\dfrac{11,2.100}{17,6}=63,64\)0/0
0/0Cu = \(\dfrac{m_{Cu}.100}{m_{hh}}=\dfrac{6,4.100}{17,6}=36,36\)0/0
b) 3H2 + Fe2O3 → (to) 2Fe + 3H2O\(|\)
3 1 2 3
0,2 0,13
Số mol của sắt
nFe = \(\dfrac{0,2.2}{3}=0,13\left(mol\right)\)
Khối lượng của sắt
mFe = nFe . MFe
= 0,13 . 56
= 7,28 (g)
Chúc bạn học tốt
\(n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
0,05-------------->0,05
=> mCu = 0,05.64 = 3,2 (g)