Cho 200 gam dung dịch CH3COOH 12% tác dụng với 3,6 gam Mg, sau phản ứng thu được (CH3COO)2Mg và khí H2. Tính nồng độ phần trăm của dung dịch muối sau phản ứng
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a) \(n_{\left(CH_3COO\right)_2Mg}=\dfrac{7,1}{142}=0,05\left(mol\right)\)
PTHH: 2CH3COOH + Mg --> (CH3COO)2Mg + H2
0,1<----------------------0,05------->0,05
=> VH2 = 0,05.22,4 = 1,12 (l)
b) \(C_{M\left(dd.CH_3COOH\right)}=\dfrac{0,1}{0,025}=4M\)
a) $n_{Fe} = \dfrac{11,2}{56} = 0,2(mol)$
$Fe + 2HCl \to FeCl_2 + H_2$
$n_{HCl} =2 n_{Fe} = 0,2.2 = 0,4(mol)$
$C\%_{HCl} = \dfrac{0,4.36,5}{200}.100\% = 7,3\%$
b) $n_{H_2} = n_{FeCl_2} = n_{Fe} = 0,2(mol)
Sau phản ứng, $m_{dd} = 11,2 + 200 - 0,2.2 = 210,8(gam)$
$C\%_{FeCl_2} = \dfrac{0,2.127}{210,8}.100\% = 12,05\%$
\(nAl=\dfrac{2,7}{27}=0,1\left(mol\right)\)
\(mHCl=\dfrac{200.7,3\%}{100\%}=14,6\left(g\right)\)
\(nHCl=\dfrac{14,6}{36,5}=0,4\left(mol\right)\)
PTHH:
\(2Al+6HCl\rightarrow2AlCl_2+3H_2\)
2 6 2 3 (mol)
0,1 0,3 0,1 0,15 (mol)
LTL : 0,1 / 2 < 0,4/6
=> Al đủ , HCl dư
1. \(VH_2=0,15.22,4=3,36\left(l\right)\)
2. \(mH_2=0,15.2=0,3\left(g\right)\)
mdd = mAl + mddHCl - mH2 = 2,7 + 200 - 0,3 = 202,4 (g)
\(mH_2SO_{4\left(dưsaupứ\right)}=0,1.98=9,8\left(g\right)\)
\(mAlCl_2=0,1.98=9,8\left(g\right)\)
\(C\%_{ddH_2SO_4}=\dfrac{9,8.100}{202,4}=4,84\%\)
\(C\%_{AlCl_2}=\dfrac{9,8.100}{202,4}=4,84\%\)
Ta có: \(n_{CuO}=\dfrac{40}{80}=0,5\left(mol\right)\)
PT: \(CuO+2HCl\rightarrow CuCl_2+H_2O\)
____0,5____________0,5 (mol)
a, \(m_{CuCl_2}=0,5.135=67,5\left(g\right)\)
b, Có: m dd sau pư = mCuO + m dd HCl = 40 + 200 = 240 (g)
\(\Rightarrow C\%_{CuCl_2}=\dfrac{67,5}{240}.100\%=28,125\%\)
Bạn tham khảo nhé!
\(n_{CH_3COOH}=\dfrac{100.12\%}{60}=0,2\left(mol\right)\)
PTHH: CH3COOH + NaHCO3 --> CH3COONa + CO2 + H2O
0,2------>0,2-------------->0,2------->0,2
=> \(m_{dd.NaHCO_3.8,4\%}=\dfrac{0,2.84.100}{8,4}=200\left(g\right)\)
mdd sau pư = 100 + 200 - 0,2.44 = 291,2 (g)
\(m_{CH_3COONa}=0,2.82=16,4\left(g\right)\)
=> \(C\%_{CH_3COONa}=\dfrac{16,4}{291,2}.100\%=5,632\%\)
Bài 4 :
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
a) Pt : \(Zn+2HCl\rightarrow ZnCl_2+H_2|\)
1 2 1 1
0,2 0,4 0,2 0,2
b) \(n_{H2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,2.22,4=4,48\left(l\right)\)
c) \(n_{HCl}=\dfrac{0,2.2}{1}=0,4\left(mol\right)\)
⇒ \(m_{HCl}=0,4.36,5=14,6\left(g\right)\)
\(C_{ddHCl}=\dfrac{14,6.100}{100}=14,6\)0/0
d) \(n_{ZnCl2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
⇒ \(m_{ZnCl2}=0,2.136=27,2\left(g\right)\)
\(m_{ddspu}=13+100-\left(0,2.2\right)=112,6\left(g\right)\)
\(C_{ZnCl2}=\dfrac{27,2.100}{112,6}=24,16\)0/0
Chúc bạn học tốt
Bài 3 :
\(n_{Mg}=\dfrac{12}{24}=0,5\left(mol\right)\)
a) Pt : \(Mg+H_2SO_4\rightarrow MgSO_4+H_2|\)
1 1 1 1
0,5 0,5 0,5 0,5
b) \(n_{H2}=\dfrac{0,5.1}{1}=0,5\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,5.22,4=11,2\left(l\right)\)
c) \(n_{H2SO4}=\dfrac{0,5.1}{1}=0,5\left(mol\right)\)
⇒ \(m_{H2SO4}=0,5.98=49\left(g\right)\)
\(C_{ddH2SO4}=\dfrac{49.100}{200}=24,5\)0/0
d) \(n_{MgSO4}=\dfrac{0,5.1}{1}=0,5\left(mol\right)\)
⇒ \(m_{MgSO4}=0,5.120=60\left(g\right)\)
\(m_{ddspu}=12+200-\left(0,5.2\right)=211\left(g\right)\)
\(C_{MgSO4}=\dfrac{60.100}{211}=28,44\)0/0
Chúc bạn học tốt
Bài 6:
\(n_{Fe\left(OH\right)_3}=\dfrac{21,4}{107}=0,2\left(mol\right)\)
PT: \(Fe\left(OH\right)_3+3HCl\rightarrow FeCl_3+3H_2O\)
_______0,2________0,6______0,2 (mol)
a, \(C\%_{HCl}=\dfrac{0,6.36,5}{200}.100\%=10,95\%\)
b, \(C\%_{FeCl_3}=\dfrac{0,2.162,5}{21,4+200}.100\%\approx14,68\%\)
Bài 7:
\(m_{H_2SO_4}=100.9,8\%=9,8\left(g\right)\Rightarrow n_{H_2SO_4}=\dfrac{9,8}{98}=0,1\left(mol\right)\)
PT: \(ZnO+H_2SO_4\rightarrow ZnSO_4+H_2O\)
______0,1______0,1_______0,1 (mol)
a, \(m_{ZnO}=0,1.81=8,1\left(g\right)\)
b, \(C\%_{ZnSO_4}=\dfrac{0,1.161}{8,1+100}.100\%\approx14,89\%\)
`a)PTHH:`
`Zn + 2HCl -> ZnCl_2 + H_2`
`0,02` `0,02` `0,02` `(mol)`
`n_[Zn]=[1,3]/65=0,02(mol)`
`b)V_[H_2]=0,02.22,4=0,448(l)`
`c)C%_[ZnCl_2]=[0,02.136]/[1,3+50-0,02.2].100~~5,31%`
\(n_{Zn}=\dfrac{1,3}{65}=0,02\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,02 0,04 0,02 0,02 ( mol )
\(V_{H_2}=0,02.22,4=0,448\left(l\right)\)
\(C\%_{ZnCl_2}=\dfrac{0,02.136}{1,3+50-0,02.2}.100=5,3\%\)
Mg+2CH3COOH->(CH3COO)2Mg+H2
0,15------0,3-------------0,15-------------0,15
n Mg=\(\dfrac{3,6}{24}\)=0,15 mol
m CH3COOH=24g =>n CH3COOH=\(\dfrac{24}{60}\)=0,6 mol
->CH3COOH dư
=>C% (CH3COO)2Mg=\(\dfrac{0,15.142}{200+3,6-0,15.2}\).100=10,48%
=>C% CH3COOH dư= \(\dfrac{0,3.60}{200+3,6-0,15.2}\).100=8,85%