Đốt cháy hoàn toàn một hỗn hợp gồm H2 và CO có khối lượng là 68gam thì dùng hết 89,6 lít O2 ở đktc. a.Viết các PTHH xảy ra. b.Tính TPPT theo khối lượng các chất có trong hỗn hợp chất ban đầu.
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a) PTHH: \(2CO+O_2\underrightarrow{t^o}2CO_2\) (1)
\(4H_2+O_2\underrightarrow{t^o}2H_2O\) (2)
b) Ta có: \(\left\{{}\begin{matrix}\Sigma n_{O_2}=\dfrac{9,6}{32}=0,3\left(mol\right)\\n_{CO_2}=\dfrac{8,8}{44}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{O_2\left(1\right)}=0,1mol\\n_{O_2\left(2\right)}=0,2mol\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{CO}=0,1\cdot28=2,8\left(g\right)\\m_{H_2}=0,2\cdot2=0,4\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{CO}=\dfrac{2,8}{2,8+0,4}\cdot100\%=87,5\%\\\%m_{H_2}=12,5\%\end{matrix}\right.\)
c) PTHH: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
Theo PTHH: \(n_{KMnO_4}=2n_{O_2}=0,6mol\)
\(\Rightarrow m_{KMnO_4}=0,6\cdot158=94,8\left(g\right)\)
\(n_{O_2}=\dfrac{89.6}{22.4}=4\left(mol\right)\)
\(n_{H_2O}=3a\left(mol\right)\)
\(n_{CO_2}=a\left(mol\right)\)
\(2H_2+O_2\underrightarrow{^{^{t^0}}}2H_2O\)
\(2CO+O_2\underrightarrow{^{^{t^0}}}2CO_2\)
\(n_{O_2}=1.5a+0.5a=4\left(mol\right)\)
\(\Leftrightarrow a=2\)
\(n_{H_2}=3\left(mol\right),n_{CO}=1\left(mol\right)\)
\(\%V_{H_2}=\dfrac{3}{4}\cdot100\%=75\%\)
\(\%V_{CO}=25\%\)
\(\%m_{H_2}=\dfrac{3\cdot2}{3\cdot2+1\cdot28}\cdot100\%=17.64\%\)
\(\%m_{CO}=100-17.64=82.36\%\)
\(n_{CO_2}=\dfrac{8.8}{44}=0.2\left(mol\right)\)
\(n_{O_2}=\dfrac{9.6}{32}=0.3\left(mol\right)\)
\(2CO+O_2\underrightarrow{t^0}2CO_2\)
\(0.2.......0.1.......0.2\)
\(2H_2+O_2\underrightarrow{t^0}2H_2O\)
\(0.4......0.3-0.1\)
\(\%m_{CO}=\dfrac{0.2\cdot28}{0.2\cdot28+0.4\cdot2}\cdot100\%=87.5\%\)
\(\%m_{H_2}=100-87.5=12.5\%\)
a)
\(2CO + O_2 \xrightarrow{t^o} 2CO_2(1)\\ 2H_2 + O_2 \xrightarrow{t^o} 2H_2O(2) \)
b)
\(n_{CO_2} = \dfrac{8,8}{44} = 0,2(mol)\\ n_{O_2} = \dfrac{9,6}{32} = 0,3(mol)\)
Theo PTHH :
\(n_{CO} = n_{CO_2} = 0,2(mol)\\ n_{O_2(1)} = \dfrac{1}{2}n_{CO_2} = 0,1(mol)\\ n_{H_2} = 2n_{O_2(2)} = 2(0,3-0,1) = 0,4(mol)\)
Vậy :
\(\%m_{CO} = \dfrac{0,2.28}{0,2.28+0,4.2}.100\% = 87,5\%\\ \%m_{H_2} = 100\% - 87,5\% = 12,5\%\)
$n_{CO_2} = \dfrac{8,8}{44} = 0,2(mol)$
\(2CO+O_2\xrightarrow[]{t^o}2CO_2\)
0,2 0,1 0,2 (mol)
$n_{O_2} = \dfrac{9,6}{32} = 0,3(mol)$
\(2H_2+O_2\xrightarrow[]{t^o}2H_2O\)
0,4 0,2 0,2 (mol)
\(\%m_{CO}=\dfrac{0,2.44}{0,2.44+0,4.2}.100\%=91,67\%\\ \%m_{H_2}=100\%-91,67\%=8,33\%\)
\(\%n_{CO}=\dfrac{0,2}{0,2+0,4}.100\%=33,33\%\\ \%n_{H_2}=100\%-33,33\%=66,67\%\)
a: \(C+O_2\rightarrow CO_2\)(ĐK: t độ)
x x x
\(S+O_2\rightarrow SO_2\)(ĐK: t độ)
y y y
b: \(n_{O_2}=\dfrac{11.2}{22.4}=0.5\left(mol\right)\)
Theo đề, ta có hệ:
12x+32y=10 và x+y=0,5
=>x=0,3 và y=0,2
\(m_C=0.3\cdot12=3.6\left(g\right)\)
\(m_S=0.2\cdot32=6.4\left(g\right)\)
c: \(n_{CO_2}=n_C=0.3\left(mol\right)\)
\(n_{SO_2}=n_S=0.2\left(mol\right)\)
\(V_{khí}=22.4\left(0.3+0.2\right)=11.2\left(lít\right)\)
\(n_{O_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH :
\(C+O_2\rightarrow\left(t^o\right)CO_2\)
x x x
\(S+O_2\rightarrow\left(t^o\right)SO_2\)
y y y
Gọi n C = x
n S = y (mol)
Ta có hệ PT :
\(\left\{{}\begin{matrix}12x+32y=10\\x+y=0,5\end{matrix}\right.\)
\(\rightarrow x=0,3;y=0,2\)
\(m_C=0,3.12=3,6\left(g\right)\)
\(m_S=0,2.32=6,4\left(g\right)\)
\(c,V_{hhk}=\left(0,3+0,2\right).22,4=11,2\left(l\right)\)
Đặt \(\left\{{}\begin{matrix}n_{CuO}=x\left(mol\right)\\n_{Fe_2O_3}=y\left(mol\right)\end{matrix}\right.\)
\(m_{CuO}+m_{Fe_2O_3}=40\\ \Rightarrow80x+160y=40\left(1\right)\)
\(PTHH:CuO+H_2\underrightarrow{t^o}Cu+H_2O\\ \left(mol\right)......x\rightarrow.x\\ PTHH:Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\\ \left(mol\right).....y\rightarrow....3y\\ V_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\\ \Rightarrow x+3y=0,6\left(2\right)\)
\(\xrightarrow[\left(2\right)]{\left(1\right)}\left\{{}\begin{matrix}80x+160y=40\\x+3y=0,6\end{matrix}\right.\\ \Leftrightarrow\left\{{}\begin{matrix}x=0,3\\y=0,1\end{matrix}\right.\)
a) \(\left\{{}\begin{matrix}m_{CuO}=80.0,3=24\left(g\right)\\m_{Fe_2O_3}=40-24=16\left(g\right)\end{matrix}\right.\)
b) \(\left\{{}\begin{matrix}\%m_{CuO}=\dfrac{24}{40}.100\%=60\%\\\%m_{Fe_2O_3}=100\%-60\%=40\%\end{matrix}\right.\)
\(n_{hhk}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
\(n_{O_2}=\dfrac{26,88}{22,4}=1,2\left(mol\right)\)
Đặt \(\left\{{}\begin{matrix}n_{CH_4}=x\\n_{C_2H_4}=y\end{matrix}\right.\) ( mol ) \(\Rightarrow n_{hhk}=x+y=0,5\left(1\right)\)
\(CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\)
x 2x ( mol )
\(C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\)
y 3y ( mol )
\(\rightarrow n_{O_2}=2x+3y=1,2\left(2\right)\)
\(\left(1\right);\left(2\right)\Rightarrow\left\{{}\begin{matrix}x=0,3\\y=0,2\end{matrix}\right.\)
\(\%V_{CH_4}=\dfrac{0,3}{0,5}.100=60\%\)
\(\%V_{C_2H_4}=100-60=40\%\)
PTHH: 2CO+O2to→2CO2 (1)
4H2+O2to→2H2O (2)
b) Ta có:
ΣnO2=\(\dfrac{9,6}{32}\)=0,3(mol)
nCO2=\(\dfrac{8,8}{44}\)=0,2(mol)
⇒{nO2(1)=0,1mol
nO2(2)=0,2mol
⇒{mCO=0,1⋅28=2,8(g)
mH2=0,2⋅2=0,4(g)
⇒%mCO=\(\dfrac{2,8}{2,8+0,4}\)⋅100%=87,5%
%mH2=12,5%
\(nO_2=\dfrac{9,6}{32}=0,3\left(mol\right)\)
\(nCO_2=\dfrac{8,8}{44}=0,2\left(mol\right)\)
\(2CO+O_2\underrightarrow{t^o}2CO_2\)
2 1 2 (mol)
0,2 0,1 0,2 (mol)
\(4H_2+O_2\underrightarrow{t^o}2H_2O\)
4 1 2 (mol)
0,8 0,2 0,4 (mol)
\(mCO=0,2.28=5,6\left(g\right)\)
\(mH_2=0,8.2=0,16\left(g\right)\)
\(\%mCO=\dfrac{5,6.100}{5,6+0,16}=97,22\%\)
\(\%mH_2=100-97,22=2,78\%\)
PTHH: \(C+O_2\xrightarrow[]{t^o}CO_2\)
a___a______a (mol)
\(S+O_2\xrightarrow[]{t^o}SO_2\)
b___b_______b (mol)
Ta lập HPT: \(\left\{{}\begin{matrix}12a+32b=10\\a+b=\dfrac{11,2}{22,4}=0,5\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,3\\b=0,2\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_C=0,3\cdot12=3,6\left(g\right)\\m_S=6,4\left(g\right)\\V_{khí}=0,5\cdot22,4=11,2\left(l\right)\end{matrix}\right.\)
a)
2H2 + O2 --to--> 2H2O
2CO + O2 --to--> 2CO2
b)
Gọi số mol H2, CO là a, b
=> 2a + 28b = 68
PTHH: 2H2 + O2 --to--> 2H2O
a--->0,5a
2CO + O2 --to--> 2CO2
b----->0,5b
=> 0,5a + 0,5b = \(\dfrac{89,6}{22,4}=4\)
=> a = 6(mol); b = 2(mol)
\(\left\{{}\begin{matrix}\%m_{H_2}=\dfrac{6.2}{68}.100\%=17,65\%\\\%m_{CO}=\dfrac{2.28}{68}.100\%=82,35\%\end{matrix}\right.\)