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Gọi: \(\left\{{}\begin{matrix}n_{CO}=x\left(mol\right)\\n_{H_2}=y\left(mol\right)\end{matrix}\right.\)
⇒ 28x + 2y = 11,8 (1)
PT: \(2CO+O_2\underrightarrow{t^o}2CO_2\)
\(2H_2+O_2\underrightarrow{t^o}2H_2O\)
Ta có: \(n_{O_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{CO}+\dfrac{1}{2}n_{H_2}=\dfrac{1}{2}x+\dfrac{1}{2}y\left(mol\right)\)
⇒ x + y = 0,7 (2)
Từ (1) và (2) ⇒ x = 0,4 (mol), y = 0,3 (mol)
a, \(\left\{{}\begin{matrix}\%m_{CO}=\dfrac{0,4.28}{11,8}.100\%\approx94,9\%\\\%m_{H_2}\approx5,1\%\end{matrix}\right.\)
b, Ở cùng điều kiện nhiệt độ và áp suất, % số mol cũng là % thể tích.
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CO}=\dfrac{0,4}{0,7}.100\%\approx57,14\%\\\%V_{H_2}\approx42,86\%\end{matrix}\right.\)
Bạn tham khảo nhé!
PTHH:
\(2CO+O_2\overset{t^o}{--->}2CO_2\left(1\right)\)
\(2H_2+O_2\overset{t^o}{--->}2H_2O\left(2\right)\)
Ta có: \(n_{O_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\)
Gọi x, y lần lượt là số mol của CO và H2
a. Theo PT(1): \(n_{O_2}=\dfrac{1}{2}.n_{CO}=\dfrac{1}{2}x\left(mol\right)\)
Theo PT(2): \(n_{O_2}=\dfrac{1}{2}.n_{H_2}=\dfrac{1}{2}y\left(mol\right)\)
\(\Rightarrow\dfrac{1}{2}x+\dfrac{1}{2}y=0,35\) (*)
Theo đề, ta có: \(28x+2y=11,8\) (**)
Từ (*) và (**), ta có HPT:
\(\left\{{}\begin{matrix}\dfrac{1}{2}x+\dfrac{1}{2}y=0,35\\28x+2y=11,8\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,4\\y=0,3\end{matrix}\right.\)
\(\Rightarrow m_{H_2}=2.0,3=0,6\left(g\right)\)
\(\Rightarrow\%_{m_{H_2}}=\dfrac{0,6}{11,8}.100\%=5,08\%\)
\(\%_{m_{CO}}=100\%-5,08\%=94,92\%\)
b. \(\%_{V_{CO}}=\dfrac{0,4}{0,4+0,3}.100\%=57,1\%\)
\(\%_{V_{H_2}}=100\%-57,1\%=42,9\%\)
a, \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)
Ta có: \(n_{CH_4}+n_{C_2H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\left(1\right)\)
\(n_{CO_2}=n_{CH_4}+2n_{C_2H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,25\left(mol\right)\\n_{C_2H_2}=0,05\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,25.22,4}{6,72}.100\%\approx83,33\%\\\%V_{C_2H_2}\approx16,67\%\end{matrix}\right.\)
Theo PT: \(n_{O_2}=2n_{CH_4}+\dfrac{5}{2}n_{C_2H_2}=0,625\left(mol\right)\Rightarrow m_{O_2}=0,625.32=20\left(g\right)\)
Gọi \(\left\{{}\begin{matrix}n_{H_2}=a\left(mol\right)\\n_{CO}=b\left(mol\right)\end{matrix}\right.\)⇒ 2a + 28b = 6,8(1)
\(2H_2 + O_2 \xrightarrow{t^o} 2H_2O\\ 2CO + O_2 \xrightarrow{t^o} 2CO_2\)
Theo PTHH :
\(n_{O_2} = 0,5a + 0,5b = \dfrac{8,96}{22,4} = 0,4(2)\)
Từ (1)(2) suy ra: a = 0,6 ; b = 0,2
Vậy :
\(\%m_{H_2} = \dfrac{0,6.2}{6,8}.100\% = 17,65\%\\ \%m_{CO} = 100\% - 17,65\% = 82,35\%\)
Cho em hỏi tại sao no2=0.5a+0.5b=0.4
tại sao viết 0.5 mà ko là 1 ạ
a)
\(n_{Br_2}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: C2H4 + Br2 --> C2H4Br2
0,05<-0,05
=> \(n_{CH_4}=\dfrac{3,36}{22,4}-0,05=0,1\left(mol\right)\)
\(\%m_{CH_4}=\dfrac{0,1.16}{0,1.16+0,05.28}.100\%=53,33\%\)
\(\%m_{C_2H_4}=\dfrac{0,05.28}{0,1.16+0,05.28}.100\%=46,67\%\)
b)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
0,1-->0,2
C2H4 + 3O2 --to--> 2CO2 + 2H2O
0,05--->0,15
=> \(V_{O_2}=\left(0,2+0,15\right).22,4=7,84\left(l\right)\)
a, \(CH_4+2O_2\underrightarrow{t^o}CO_2+H_2O\)
\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)
Ta có: \(n_{CH_4}+n_{C_2H_2}=\dfrac{33,6}{22,4}=1,5\left(mol\right)\left(1\right)\)
Theo PT: \(n_{CO_2}=n_{CH_4}+2n_{C_2H_2}=\dfrac{56}{22,4}=2,5\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,5\left(mol\right)\\n_{C_2H_2}=1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,5.22,4}{33,6}.100\%\approx33,33\%\\\%V_{C_2H_2}\approx66,67\%\end{matrix}\right.\)
b, Theo PT: \(n_{O_2}=2n_{CH_4}+\dfrac{5}{2}n_{C_2H_2}=3,5\left(mol\right)\Rightarrow m_{O_2}=3,5.32=112\left(g\right)\)
- Gọi mol metan và etan là x, y ( mol )
\(x+y=n_{hh}=\dfrac{V}{22,4}=0,25\left(mol\right)\)
Lại có : \(x+2y=n_{CO_2}=\dfrac{V}{22,4}=0,4\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,15\end{matrix}\right.\) ( mol )
\(\Rightarrow\left\{{}\begin{matrix}m_{CH_4}=1,6\left(g\right)\\m_{C_2H_6}=4,5\left(g\right)\end{matrix}\right.\)
=> mhh = 6,1 ( g )
=> %mCH4 = ~ 26,22%
=> %mC2H6 = ~73,78%
Ta có : \(\%V_{CH4}=\dfrac{V}{Vhh}=40\%\)
=> %VC2H6 = 100 - %VCH4 = 60% .
PT: \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
\(2C_2H_6+5O_2\underrightarrow{t^o}4CO_2+6H_2O\)
Giả sử: \(\left\{{}\begin{matrix}n_{CH_4}=x\left(mol\right)\\n_{C_2H_6}=y\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow x+y=\dfrac{5,6}{22,4}=0,25\left(1\right)\)
Ta có: \(n_{CO_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
Theo PT: \(\Sigma n_{CO_2}=n_{CH_4}+2n_{C_2H_6}\)
\(\Rightarrow x+2y=0,4\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,1\left(mol\right)\\y=0,15\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,1}{0,25}.100\%=40\%\\\%V_{C_2H_6}=60\%\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{0,1.16}{0,1.16+0,15.30}.100\%\approx26,2\%\\\%m_{C_2H_6}\approx73,8\%\end{matrix}\right.\)
Bạn tham khảo nhé!
1) nh2=0,2; n CACO3=0,7
pt1: CH4+2O2 ---> CO2+2H2O
x x
pt2: C2H4 +3O2 ----> 2CO2+2H2O
y 2y
pt3: CO2+CA(OH)2 ----> CACO3+H2O
0,7 0,7
ta có hệ pt: x+y=0,2
x+2y=0,7
tự tìm
b) nbr2=1
pt: C4H6+ 2Br2 -----> C4H6Br4
0,05 0,1 0,05
tỉ lệ: 0,3/1 > 0,1/2 => C4H6 dư
CM C4H6Br2=0,05/8,72
CM C4H6 dư= 0,25/8,72
Bài 1:
Ta có: \(n_{C_2H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PT: \(2C_2H_2+5O_2\underrightarrow{t^O}4CO_2+2H_2O\)
a, \(n_{O_2}=\dfrac{5}{2}n_{C_2H_2}=0,625\left(mol\right)\Rightarrow m_{O_2}=0,625.32=20\left(g\right)\)
b, \(n_{CO_2}=2n_{C_2H_2}=0,5\left(mol\right)\Rightarrow m_{CO_2}=0,5.44=22\left(g\right)\)
Bài 2:
Ta có: \(\%V_{C_2H_2}=\%V_{CH_4}=50\%\) (do tỉ lệ số mol 2 khí bằng nhau)
\(n_{hhkhí}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\\ m_{tăng}=m_{C_2H_4}=4,2\left(g\right)\\ n_{C_2H_4}=\dfrac{4,2}{28}=0,15\left(mol\right)\\ n_{CH_4}=0,35-0,15=0,2\left(mol\right)\\ \left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,15}{0,35}=42,85\%\\\%V_{CH_4}=100\%-42,85\%=57,15\%\end{matrix}\right.\)
PTHH:
C2H4 + 3O2 --to--> 2CO2 + 2H2O
0,15 ------------------> 0,3
CH4 + O2 --to--> CO2 + 2H2O
0,2 -----------------> 0,2
Ca(OH)2 + CO2 ---> CaCO3 + H2O
0,5 -------> 0,5
\(m_{CaCO_3}=0,5.100=50\left(g\right)\)
PT: \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
\(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)
Giả sử: \(\left\{{}\begin{matrix}n_{CH_4}=x\left(mol\right)\\n_{C_2H_4}=y\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow x+y=\dfrac{7,84}{22,4}=0,35\left(1\right)\)
Ta có: \(n_{O_2}=\dfrac{19,04}{22,4}=0,85\left(mol\right)\)
Theo PT: \(n_{O_2}=2n_{CH_4}+3n_{C_2H_4}=2x+3y\)
⇒ 2x + 3y = 0,85 (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,2\left(mol\right)\\y=0,15\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{0,2.16}{0,2.16+0,15.28}.100\%\approx43,2\%\\\%m_{C_2H_4}\approx56,8\%\end{matrix}\right.\)
Bạn tham khảo nhé!