Câu 1. Viết PTHH cho dãy chuyển đổi sau: a. Fe ( FeCl3 ( Fe(OH)3 ( Fe2O3 ( Fe ( FeSO4 ( FeS ( FeCl2 ( Fe(NO3)2 b. Al2O3 ( Al ( Al2(SO4)3 ( Al(OH)3 ( Al(NO3)3 ( Al → NaAlO2
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![](https://rs.olm.vn/images/avt/0.png?1311)
![](https://rs.olm.vn/images/avt/0.png?1311)
a) 2Fe+3Cl2--->2FeCl3
FeCl3+3NaOH--->3NaCl+Fe(OH)3
3Fe(OH)3-->Fe2O3+3H2O
Fe2O3+H2---->2Fe+3H2O
Fe+H2SO4---->FeSO4+H2
FeSO4+BaCl2---->FeCl2+BaSO4
b) Fe+2HCl--->FeCl2+H2
FeCl2+AgNO3--->2AgCl+Fe(NO3)2
Fe(NO3)2+2NaOH--->2NaNO3+Fe(OH)2
Fe(OH)2+Na2SO4--->2NaOH+FeSO4
FeSO4+Zn----->ZnSO4+Fe
Fe+.....Ko biết
c)4 Al+3O2--->2Al2O3
Al2O3+3H2SO4--->Al2(SO4)3+3H2O
Al2(SO4)3+3BaCl2---->2AlCl3+3BaCl2
Alcl3+3NaOH--->Al(OH)3+3NaCl
2Al(OH)3--->Al2O3+3H2O
2Al2O3--->4Al+3O2
a) 2Fe+3Cl2--->2FeCl3
FeCl3+3NaOH--->3NaCl+Fe(OH)3
3Fe(OH)3-->Fe2O3+3H2O
Fe2O3+H2---->2Fe+3H2O
Fe+H2SO4---->FeSO4+H2
FeSO4+BaCl2---->FeCl2+BaSO4
b) Fe+2HCl--->FeCl2+H2
FeCl2+AgNO3--->2AgCl+Fe(NO3)2
Fe(NO3)2+2NaOH--->2NaNO3+Fe(OH)2
Fe(OH)2+Na2SO4--->2NaOH+FeSO4
FeSO4+Zn----->ZnSO4+Fe
ko có PTHH
c)4 Al+3O2--->2Al2O3
Al2O3+3H2SO4--->Al2(SO4)3+3H2O
Al2(SO4)3+3BaCl2---->2AlCl3+3BaCl2
Alcl3+3NaOH--->Al(OH)3+3NaCl
2Al(OH)3--->Al2O3+3H2O
2Al2O3--->4Al+3O2
![](https://rs.olm.vn/images/avt/0.png?1311)
a, \(2Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)
\(AlCl_3+3NaOH\rightarrow3NaCl+Al\left(OH\right)_3\)
\(2Al\left(OH\right)_3\underrightarrow{t^o}Al_2O_3+3H_2O\)
\(Al_2O_3\underrightarrow{đpnc}2Al+\dfrac{3}{2}O_2\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(Al_2\left(SO_4\right)_3+3Mg\rightarrow3MgSO_4+2Al\)
b, \(2Fe+3Cl_2\underrightarrow{t^o}2FeCl_3\)
\(FeCl_3+3NaOH\rightarrow3NaCl+Fe\left(OH\right)_3\)
\(2Fe\left(OH\right)_3\underrightarrow{t^o}Fe_2O_3+3H_2O\)
\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(Mg+FeCl_2\rightarrow MgCl_2+Fe\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
![](https://rs.olm.vn/images/avt/0.png?1311)
a.
2Al2O3 \(\underrightarrow{t^o}\)4Al + 3O2\(\uparrow\)
Al + 6HNO3 \(\rightarrow\) Al(NO3)3\(\downarrow\) + 3NO2 + 3H2O
Al(NO3)3 + NaOH \(\rightarrow\) Al(OH)3\(\downarrow\) + NaNO3
2Al(OH)3 \(\xrightarrow[criolit]{đpnc}\) Al2O3 + 3H2O
Al2O3 + 3H2SO4 \(\rightarrow\) Al2(SO4)3 + 3H2O
Al2(SO4)3 + 3BaCl2 \(\rightarrow\) 3BaSO4\(\downarrow\) + 2AlCl3
2AlCl3 \(\xrightarrow[criolit]{đpnc}\) 2Al + 3Cl2\(\uparrow\)
2Al + 3CuSO4 \(\rightarrow\) 3Cu + Al2(SO4)3
![](https://rs.olm.vn/images/avt/0.png?1311)
\(a,4Al+3O_2\xrightarrow[t^0]{}2Al_2O_3\\ Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\\ AlCl_3+3AgNO_3\rightarrow Al\left(NO_3\right)_3+3AgCl\\ AlCl_3+3NaOH\rightarrow Al\left(OH\right)_3+3NaCl\\ 2Al\left(OH\right)_3\xrightarrow[t^0]{}Al_2O_3+3H_2O\\ 2Al_2O_3\xrightarrow[đpnc]{criolit}4Al+3O_2\\ b,3Fe+2O_2\xrightarrow[t^0]{}Fe_3O_4\\ Fe_3O_4+8HCl\rightarrow2FeCl_3+FeCl_2+4H_2O\\ FeCl_3+3NaOH\rightarrow Fe\left(OH\right)_3+3NaCl\\ 2Fe\left(OH\right)_3\xrightarrow[t^0]{}Fe_2O_3+3H_2O\\ Fe_2O_3+3CO\xrightarrow[t^0]{}2Fe+3CO_2\)
\(c,2Fe\left(OH\right)_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+6H_2O\\ Fe_2\left(SO_4\right)_3+3BaCl_2\rightarrow2FeCl_3+3BaSO_4\\ FeCl_3+AgNO_3\rightarrow Fe\left(NO_3\right)_3+3AgCl\)
![](https://rs.olm.vn/images/avt/0.png?1311)
a) Các PTHH:
(1) 2 Fe +3 Cl2 -to-> 2 FeCl3
(2) FeCl3 + 3 NaOH -> Fe(OH)3 +3 NaCl
(3) 2 Fe(OH)3 -to-> Fe2O3 + 3 H2O
(4) Fe2O3 + 3 CO -to-> 2 Fe + 3 CO2
(5) Fe + 2 HCl -> FeCl2 + H2
(6) FeCl2 + 2 AgNO3 -> Fe(NO3)2 + 2 AgCl
b) Các PTHH:
(1) MnO2 + 4 HCl(đặc) -to-> MnCl2 + Cl2 + 2 H2O
(2) 3 Cl2 + 2 Fe -to-> 2 FeCl3
(3) FeCl3 + 3 NaOH -> Fe(OH)3 + 3 NaCl
(4) NaCl + H2O -ddpdddcmnx-> NaOH + 1/2 H2 + 1/2 Cl2
(5) Cl2 + Cu -to-> CuCl2
(6) CuCl2 + 2 AgNO3 -> Cu(NO3)2 + 2 AgCl
c) Các PTHH:
(1) 4 Al + 3 O2 -to-> 2 Al2O3
(2) Al2O3 + 6 HCl -> 2 AlCl3 + 3 H2O
(3) AlCl3 + 3 KOH -> 3 KCl + Al(OH)3
(4) 2 Al(OH)3 -to-> Al2O3 +3 H2O
(5) 2 Al2O3 -đpnc-> 4 Al + 3 O2
\(a,2Fe+3Cl_2\xrightarrow{t^o}2FeCl_3\\ FeCl_3+3NaOH\to Fe(OH)_3\downarrow+3NaCl\\ 2Fe(OH)_3\xrightarrow{t^o}Fe_2O_3+3H_2O\\ Fe_2O_3+3CO\xrightarrow{t^o}2Fe+3CO_2\\ Fe+H_2SO_4\to FeSO_4+H_2\\ FeSO_4+BaS\to BaSO_4\downarrow+FeS\\ FeS+2HCl\to FeCl_2+H_2\\ FeCl_2+2AgNO_3\to Fe(NO_3)_2+2AgCl\downarrow\)
\(b,2Al_2O_3\xrightarrow[criolit]{đpnc}4Al+3O_2\\ 2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\\ Al_2(SO_4)_3+6NaOH\to 2Al(OH)_3\downarrow+3Na_2SO_4\\ Al(OH)_3+3HNO_3\to Al(NO_3)_3+3H_2O\\ 2Al(NO_3)_3+3Mg\to 3Mg(NO_3)_2+2Al\\ Al+NaOH+H_2O\to NaAlO_2+\dfrac{3}{2}H_2\)