Cho sơ đồ phản ứng sau: Al → X → Y → AlCl3. X, Y có thể lần lượt là cặp chất nào sau đây?
A. Al(OH)3, Al(NO3)3.
B. Al(OH)3, Al2O3.
C. Al2(SO4)3, Al2O3.
D. Al2(SO4)3, Al(OH)3.
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4Al+3O2----to--->2Al2O3
Al2O3 +3H2SO4----->Al2(SO4)3+3H2O
Al2(SO4)3+3BaCl2------>2AlCl3+3BaSO4
2AlCl3+3Ca(OH)2---->2Al(OH)3+3CaCl2
Al(OH)3+3HNO3---->Al(NO3)3+3H2O
2Al(NO3)3+3Mg----->3Mg(NO3)2+2Al
2Al+3H2SO4------->Al2(SO4)3+3H2
Al2(SO4)3+3Ca(OH)2------>2Al(OH)3+3CaSO4
2Al(OH)3-----to----->Al2O3+3H2O
2Al2O3----\(\dfrac{t^o}{criolit}\)---->4Al+3O2
2Al+2H2O+2NaOH------>2NaAlO2+3H2
4Al+3O2\(\underrightarrow{t^o}\) 2Al2O3
Al2O3+H2SO4 —> Al2(SO4)3+3H2O
Al2(SO4)3+3BaCl2–>3BaSO4\(\downarrow\)+2AlCl3
AlCl3+3NaOH—>Al(OH)3\(\downarrow\)+3NaCl
Al(OH)3+HNO3 —>Al(NO3)3+NO2\(\uparrow\)+H2O
2Al(NO3)3+3Mg—>3Mg(NO3)2+2Al\(\downarrow\)
2Al+3H2SO4–>Al2(SO4)3+3H2\(\uparrow\)
Al2(SO4)3+6NaOH—>2Al(OH)3+3Na2SO4
2Al(OH)3\(\underrightarrow{t^o}\)Al2O3+3H2O
2Al2O3\(\xrightarrow[criolit]{đien.phan.nong.chay}\)
4Al+3O2
2Al+2NaOH+2H2O—>2NaAlO2+3H2
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(AlCl_3+3NaOH\rightarrow3NaCl+Al\left(OH\right)_3\)
\(2Al\left(OH\right)_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+6H_2O\)
\(Al_2\left(SO_4\right)_3+3BaCl_2\rightarrow2AlCl_3+3BaSO_4\)
\(AlCl_3+3AgNO_3\rightarrow3AgCl+Al\left(NO_3\right)_3\)
\(Al\left(NO_3\right)_3+3KOH\rightarrow3KNO_3+Al\left(OH\right)_3\)
\(2Al\left(OH\right)_3\underrightarrow{t^o}Al_2O_3+3H_2O\)
\(Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)
\(Al+\dfrac{3}{2}Cl_2\rightarrow AlCl_3\\ AlCl_3+3NaOH\rightarrow Al\left(OH\right)_3+3NaCl\\ 2Al\left(OH\right)_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+6H_2O\\ Al_2\left(SO_4\right)_3+3BaCl_2\rightarrow2AlCl_3+3BaSO_4\\ AlCl_3+3AgNO_3\rightarrow Al\left(NO_3\right)_3+3AgCl\\ Al\left(NO_3\right)_3+3NaOH\rightarrow Al\left(OH\right)_3+3NaNO_3\\ 2Al\left(OH\right)_3\underrightarrow{t^o}Al_2O_3+3H_2O\\ Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)
(1) \(2Al\left(OH\right)_3\underrightarrow{t^o}Al_2O_3+3H_2O\)
(2) \(Al_2O_3+3H_2SO_4->Al_2\left(SO_4\right)_3+3H_2O\)
(3) \(Al_2\left(SO_4\right)_3+3BaCl_2->3BaSO_4\downarrow+2AlCl_3\)
a)
\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)
\(MgO+H_2SO_4\rightarrow MgSO_4+H_2O\)
\(MgSO_4+BaCl_2\rightarrow BaSO_4\downarrow+MgCl_2\)
\(MgCl_2+2NaOH\rightarrow Mg\left(OH\right)_2\downarrow+2NaCl\)
b)
\(2Al_2O_3\xrightarrow[criolit]{npnc}4Al+3O_2\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(AlCl_3+3AgNO_3\rightarrow Al\left(NO_3\right)_3+3AgCl\downarrow\)
\(4Al\left(NO_3\right)_3\underrightarrow{t^o}2Al_2O_3+12NO_2+3O_2\)
\(Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)
\(3Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(Al_2\left(SO_4\right)_3+3Cu\rightarrow3CuSO_4+2Al\)
\(4Al+3O_2\rightarrow2Al_2O_3\)
\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)
\(AlCl_3+3H_2O\rightarrow Al\left(OH\right)_3+3HCl\)
\(2Al\left(OH\right)_3\rightarrow Al_2O_3+3H_2O\)
\(2Al_2O_3\rightarrow4Al+3O_2\)
\(2Al+3Cl_2\rightarrow2AlCl_3\)
Đáp án D