Cho 20,8g BaCl2 tác dụng với dd H2SO4 9,8%
a) Tính khối lượng dd axit đã dùng
b) Tính khối lượng kết tủa thu được sau phản ứng
c) Tính nồng độ% của dd thu được sau phản ứng
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\(n_{FeCl_3}=\dfrac{48,75}{162,5}=0,3(mol)\\ 3NaOH+FeCl_3\to Fe(OH)_3\downarrow+3NaCl\\ \Rightarrow n_{Fe(OH)_3}=0,3(mol);n_{NaOH}=n_{NaCl}=0,9(mol)\\ a,m_{Fe(OH)_3}=0,3.107=32,1(g)\\ b,m_{dd_{NaOH}}=\dfrac{0,9.40}{10\%}=360(g)\\ c,C\%_{NaCl}=\dfrac{0,9.58,5}{360+48,75-32,1}.100\%=13,98\%\\ \)
\(d,2Fe(OH)_3+3H_2SO_4\to Fe_2(SO_4)_3+6H_2O\\ \Rightarrow n_{H_2SO_4}=0,45(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,45.98}{20\%}=220,5(g)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{220,5}{1,14}=193,42(ml)\)
PTHH: \(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
Ta có: \(n_{Fe_2O_3}=\dfrac{4,8}{160}=0,03\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{H_2SO_4}=0,09\left(mol\right)\\n_{Fe_2\left(SO_4\right)_3}=0,03\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{ddH_2SO_4}=\dfrac{0,09\cdot98}{9,8\%}=90\left(g\right)\\m_{Fe_2\left(SO_4\right)_3}=0,03\cdot400=12\left(g\right)\end{matrix}\right.\)
a, PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_{2\downarrow}\)
\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)
b, Ta có: \(n_{Mg}=\dfrac{9,6}{24}=0,4\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Mg}=0,8\left(mol\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{0,8}{0,2}=4\left(M\right)\)
c, Theo PT: \(n_{MgO}=n_{Mg}=0,4\left(mol\right)\)
\(\Rightarrow m_{MgO}=0,4.40=16\left(g\right)\)
\(n_{BaCl_2}=\dfrac{150.16,64\%}{137+35.2}=0,12\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{100.14,7\%}{98}=0,15\left(mol\right)\)
Phương trình hóa học :
BaCl2 + H2SO4 -----> BaSO4 + 2HCl
Dễ thấy \(\dfrac{n_{BaCl_2}}{1}< \dfrac{n_{H_2SO_4}}{1}\Rightarrow H_2SO_4\text{ dư }0,15-0,12=0,03\left(mol\right)\)
c) Khối lượng kết tủa :
\(m_{BaSO_4}=0,12.233=27,96\) (g)
Khối lượng chất tan : \(m_{HCl}=0,24.36,5=8,76\left(g\right)\) ;
\(m_{H_2SO_4\left(\text{dư}\right)}=0,03.98=2,94\left(g\right)\)
c) \(C\%_{H_2SO_4}\)= \(\dfrac{2,94}{150+100}.100\%=1,176\%\)
\(C\%_{HCl}=\dfrac{8,76}{150+100}.100\%=3.504\%\)
d) NaOH + HCl ---> NaCl + H2O
0,24 <-- 0,24
mol mol
2NaOH + H2SO4 ---> Na2SO4 + 2H2O
0,06 mol <-- 0,03 mol
\(\Rightarrow n_{NaOH}=0,24+0,06=0,3\left(mol\right)\)
\(V_{NaOH}=0,3.2=0,6\left(l\right)\)
a. PTHH: \(CuSO_4+2NaOH--->Na_2SO_4+Cu\left(OH\right)_2\downarrow\)
b. Đổi 100ml = 0,1 lít
Ta có: \(n_{Cu\left(OH\right)_2}=\dfrac{9,8}{98}=0,1\left(mol\right)\)
Theo PT: \(n_{CuSO_4}=n_{Cu\left(OH\right)_2}=0,1\left(mol\right)\)
=> \(m_{CuSO_4}=0,1.160=16\left(g\right)\)
c. Theo PT: \(n_{NaOH}=2.n_{CuSO_4}=2.0,1=0,2\left(mol\right)\)
=> \(C_{M_{NaOH}}=\dfrac{0,2}{0,1}=2M\)
PTHH: \(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\\n_{H_2SO_4}=\dfrac{200\cdot9,8\%}{98}=0,2\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,2}{3}\) \(\Rightarrow\) Fe2O3 còn dư, tính theo axit
\(\Rightarrow\left\{{}\begin{matrix}n_{Fe_2\left(SO_4\right)_3}=0,1\left(mol\right)\\n_{Fe_2O_3\left(dư\right)}=\dfrac{1}{30}\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Fe_2\left(SO_4\right)_3}=0,1\cdot400=40\left(g\right)\\m_{Fe_2O_3\left(dư\right)}=\dfrac{1}{30}\cdot160\approx5,3\left(g\right)\end{matrix}\right.\)
\(\Rightarrow C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{40}{16+200-5,3}\cdot100\%\approx18,98\%\)
PTHH: \(BaCl_2+H_2SO_4\rightarrow BaSO_4+2HCl\)
a) Ta có: \(n_{BaCl_2}=\frac{20,8}{208}=0,1\left(mol\right)\) \(\Rightarrow n_{H_2SO_4}=0,1mol\)
\(\Rightarrow m_{H_2SO_4}=98\cdot0,1=9,8\left(g\right)\) \(\Rightarrow m_{ddH_2SO_4}=\frac{9,8}{9,8\%}=100\left(g\right)\)
b) Theo PTHH: \(n_{BaCl_2}=n_{BaSO_4}=0,1mol\)
\(\Rightarrow m_{BaSO_4}=0,1\cdot233=23,3\left(g\right)\)
c) Theo PTHH: \(n_{BaCl_2}:n_{HCl}=1:2\) \(\Rightarrow n_{HCl}=0,2mol\)
\(\Rightarrow m_{HCl}=0,2\cdot36,5=7,3\left(g\right)\)
Ta có: \(m_{dd}=m_{BaCl_2}+m_{ddH_2SO_4}-m_{BaSO_4}=20,8+100-23,3=97,5\left(g\right)\) \(\Rightarrow C\%_{HCl}=\frac{7,3}{97,5}\cdot100\approx7,49\%\)