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PTHH: 2CH3COOH+Na2CO3→2CH3COONa+CO2+H2O
Ta có:
nCO2=3,36/22,4=0,15mol
=> nCH3COOH=2nCO2=0,3mol
=> VCH3COOH=0,3/0,5=0,6l
=> nCH3COONa=2nCO2=0,3mol
=> mCH3COONa=0,3.82=24,6g
nNa2CO3 = nCO2 = 0,15mol
=> C%Na2CO3 = (0,15.106)/300.100%=5,3%
a) 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
b) \(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
0,4--->0,6-------------------->0,6
=> VH2 = 0,6.22,4 = 13,44 (l)
c) \(V_{dd.H_2SO_4}=\dfrac{0,6}{1}=0,6\left(l\right)\)
d) \(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
PTHH: Fe2O3 + 3H2 --to--> 2Fe + 3H2O
Xét tỉ lệ: \(\dfrac{0,1}{1}< \dfrac{0,6}{3}\) => Fe2O3 hết, H2 dư
PTHH: Fe2O3 + 3H2 --to--> 2Fe + 3H2O
0,1----------------->0,2
=> mFe = 0,2.56 = 11,2 (g)
Rượu etylic \(C_2H_5OH\)
Axit axetic \(CH_3COOH\)
\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1mol\)
\(2CH_3COOH+Na_2CO_3\rightarrow2CH_3COONa+H_2O+CO_2\uparrow\)
0,2 0,1 0,2 0,1 0,1
\(\%m_{CH_3COOH}=\dfrac{0,2\cdot60}{39,6}\cdot100\%=30,3\%\)
\(\%m_{C_2H_5OH}=100\%-30,3\%=69,7\%\)
a)
\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH: 2CH3COOH + Na2CO3 --> 2CH3COONa + CO2 + H2O
0,2<----------0,1<-------------0,2<-------0,1
=> \(m_{CH_3COOH}=0,2.60=12\left(g\right)\)
\(\%m_{CH_3COOH}=\dfrac{12}{39,6}.100\%=30,3\%\)
\(\%m_{C_2H_5OH}=\dfrac{39,6-12}{39,6}.100\%=69,7\%\)
b) dd sau pư chứa \(\left\{{}\begin{matrix}CH_3COONa:0,2\left(mol\right)\\C_2H_5OH:\dfrac{39,6-12}{46}=0,6\left(mol\right)\end{matrix}\right.\)
\(V_{dd}=\dfrac{0,1}{2}=0,05\left(l\right)\)
=> \(\left\{{}\begin{matrix}C_{M\left(CH_3COONa\right)}=\dfrac{0,2}{0,05}=4M\\C_{M\left(C_2H_5OH\right)}=\dfrac{0,6}{0,05}=12M\end{matrix}\right.\)
\(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\\ n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\a, \Rightarrow n_{CaCl_2}=n_{CaCO_3}=n_{CO_2}=0,1\left(mol\right)\\ \Rightarrow a=m_{CaCO_3}=100.0,1=10\left(g\right)\\b,n_{HCl}=2.n_{CO_2}=2.0,1=0,2\left(mol\right)\\ \Rightarrow V_{ddHCl}=\dfrac{0,2}{2}=0,1\left(l\right)\\ c,m_{CaCl_2}=111.0,1=11,1\left(g\right)\)
\(n_{CO2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Pt : \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O|\)
1 2 1 1 1
0,1 0,2 0,1 0,1
a) \(n_{CaCO3}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
⇒ \(m_{CaCO3}=0,1.100=10\left(g\right)\)
b) \(n_{HCl}=\dfrac{0,1.2}{1}=0,2\left(mol\right)\)
\(V_{HCl}=\dfrac{0,2}{2}=0,1\left(l\right)\)
c) \(n_{CaCl2}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
⇒ \(m_{CaCl2}=0,1.111=11,1\left(g\right)\)
Chúc bạn học tốt
\(a,n_{\left(CH_3COO\right)_2Mg}=\dfrac{7,1}{142}=0,05\left(mol\right)\)
PTHH: \(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\uparrow\)
0,1<----------------0,05-------------->0,05
\(\rightarrow V_{H_2}=0,05.22,4=1,12\left(l\right)\\ b,C\%_{CH_3COOH}=\dfrac{0,1.60}{100}.100\%=6\%\)
\(c,n_{C_2H_5OH}=\dfrac{6,9}{46}=0,15\left(mol\right)\)
PTHH: \(CH_3COOH+C_2H_5OH\xrightarrow[H_2SO_{4\left(đặc\right)}]{t^o}CH_3COOC_2H_5+H_2O\)
bđ 0,1 0,15
pư 0,1 0,1
spư 0 0,05 0,1
\(\rightarrow m_{este}=0,1.80\%.88=7,04\left(g\right)\)
a, \(m_{CH_3COOH}=100.6\%=6\left(g\right)\Rightarrow n_{CH_3COOH}=\dfrac{6}{60}=0,1\left(mol\right)\)
PT: \(CH_3COOH+NaHCO_3\rightarrow CH_3COONa+CO_2+H_2O\)
Theo PT: \(n_{NaHCO_3}=n_{CH_3COONa}=n_{CO_2}=n_{CH_3COOH}=0,1\left(mol\right)\)
\(\Rightarrow m_{NaHCO_3}=0,1.84=8,4\left(g\right)\)
\(V_{CO_2}=0,1.22,4=2,24\left(l\right)\)
b, Ta có: m dd sau pư = 100 + 8,4 - 0,1.44 = 104 (g)
\(\Rightarrow C\%_{CH_3COONa}=\dfrac{0,1.82}{104}.100\%\approx7,88\%\)
nAl=\(\dfrac{5,8}{27}\)≈0,215 mol
a, PTPƯ: 2Al + 6HCl ---> 2AlCl3 + 3H2
Ta có: 2 mol Al ---> 3 mol H2
nên 0,215 mol Al ---> 0,323 mol H2
=> VH2=0,323.22,4≈7,24 l
b, Ta có: 2 mol Al ---> 6 mol HCl
nên 0,215 mol Al ---> 0,65 mol HCl
=> VHCl=0,65.22,4=14,56 l
c, Ta có: 2 mol Al ---> 2 mol AlCl3
nên 0,215 mol Al ---> 0,215 mol AlCl3
=> mAlCl3=0,215.133,5≈28,7 g
a) \(n_{CH_3COOH}=\dfrac{120.20\%}{60}=0,4\left(mol\right)\)
\(n_{Na_2CO_3}=\dfrac{53.30\%}{106}=0,15\left(mol\right)\)
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
Xét tỉ lệ: \(\dfrac{0,15}{1}< \dfrac{0,4}{2}\) => Na2CO3 hết, CH3COOH dư
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
0,15-------->0,3-------------->0,3------->0,15
=> \(m_{CH_3COONa}=0,3.82=24,6\left(g\right)\)
b) mdd sau pư = 120 + 53 - 0,15.44 = 166,4 (g)
=> \(C\%=\dfrac{24,6}{166,4}.100\%=14,78\text{%}\)
nCO2= 0.15 mol
CH3COOH + NaHCO3 --> CH3COONa + CO2 + H2O
0.15_________0.15_________0.15______0.15
VddCH3COOH= 0.15/0.5=0.3 l
mCH3COONa = 12.3g
C%NaHCO3= 12.6/300*100%=4.2%