Hòa tan 16g Fe2O3 trong 150g dd axit clohidric 19.47%. Tính nồng độ % các chất trong dd sau phản ứng.
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a)
nFe2O3=16/160=0,1(mol)
nHCl=0,5.1=0,5(mol)
PTHH: Fe2O3 + 6 HCl -> 2 FeCl3 + 3 H2O
Ta có: 0,1/1 > 0,5/6
=> HCl hết, Fe2O3 dư, tính theo nHCl.
nFeCl3= 2/6. nHCl= 2/6 . 0,5= 1/6(mol)
=>mFeCl3= 162,5. 1/6= 27,083(g)
b) Vddsau=VddHCl=0,5(l)
- dd sau p.ứ chỉ có FeCl3.
=> CMddFeCl3= 1/6: 0,5= 1/3(M)
a, \(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
b, \(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
\(n_{Fe_2\left(SO_4\right)_3}=n_{Fe_2O_3}=0,1\left(mol\right)\Rightarrow m_{Fe_2\left(SO_4\right)_3}=0,1.400=40\left(g\right)\)
c, \(n_{H_2SO_4}=3n_{Fe_2O_3}=0,3\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}=0,3.98=29,4\left(g\right)\Rightarrow m_{ddH_2SO_4}=\dfrac{29,4}{9,8\%}=300\left(g\right)\)
\(\Rightarrow C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{40}{16+300}.100\%\approx12,66\%\)
\(n_{Fe_2O_3}=\dfrac{32}{160}=0,2\left(mol\right)\)
\(m_{H_2SO_4}=196.40\%=78,4\left(g\right)\Rightarrow n_{H_2SO_4}=\dfrac{78,4}{98}=0,8\left(mol\right)\)
PTHH: Fe2O3 + 3H2SO4 → Fe2(SO4)3 + 3H2O
Mol: 0,2 0,6 0,2
Ta có: \(\dfrac{0,2}{1}< \dfrac{0,8}{3}\) ⇒ Fe2O3 hết, H2SO4 dư
mdd sau pứ = 32 + 196 = 228 (g)
\(C\%_{ddFe_2\left(SO_4\right)_3}=\dfrac{0,2.400.100\%}{228}=35,09\%\)
\(C\%_{ddH_2SO_4dư}=\dfrac{\left(0,8-0,6\right).98.100\%}{228}=8,596\%\)
\(n_{H_3PO_4}=n_P=0,1\left(mol\right)\)
\(C\%\left(H_3PO_4\right)=\dfrac{98.n_{H_3PO_4}}{150}.100\%=24,5\%\Rightarrow n_{H_3PO_4}=0,375\left(mol\right)\)
\(\Rightarrow\Sigma n_{H_3PO_4}=0,1+0,375=0,475\left(mol\right)\)
\(\Rightarrow C\%\left(H_3PO_4\right)=\dfrac{0,475.98}{0,1.98+150}.100\%=29,13\%\)
a)
$n_{Zn} = \dfrac{13}{65} = 0,2(mol) ; n_{H_2 SO_4} = 0,5.2 = 1(mol)$
$Zn + H_2SO_4 \to ZnSO_4 + H_2$
Ta thấy :
$n_{Zn} < n_{H_2SO_4}$ nên $H_2SO_4$ dư
$n_{ZnSO_4} = n_{H_2SO_4\ pư} = n_{Zn} = 0,2(mol)$
$m_{ZnSO_4} = 0,2.161=32,2(gam)$
$m_{H_2SO_4\ pư} = 0,2.98 = 19,6(gam)$
b)
$n_{H_2SO_4\ dư} = 1 - 0,2 = 0,8(mol)$
$C_{M_{H_2SO_4\ dư}} = \dfrac{0,8}{0,5} = 1,6M$
$C_{M_{FeSO_4}} = \dfrac{0,2}{0,5} = 0,4M$
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ n_{H_2SO_4}=0,5.2=1\left(mol\right)\\ Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ a.Vì:\dfrac{0,2}{1}< \dfrac{1}{1}\Rightarrow H_2SO_4dư\\ n_{H_2SO_4\left(p.ứ\right)}=n_{ZnSO_4}=n_{Zn}=0,2\left(mol\right)\\ m_{H_2SO_4\left(p.ứ\right)}=0,2.98=19,6\left(g\right)\\ m_{ZnSO_4}=161.0,2=32,2\left(g\right)\\ b.V_{ddsau}=V_{ddH_2SO_4}=0,5\left(l\right)\\ C_{MddZnSO_4}=\dfrac{0,2}{0,5}=0,4\left(M\right)\\ C_{MddH_2SO_4\left(dư\right)}=\dfrac{1-0,2}{0,5}=1,6\left(M\right)\)
Ta có: \(n_{MgO}=\dfrac{4}{40}=0,1\left(mol\right)\)
PTHH: MgO + 2HCl ---> MgCl2 + H2.
Theo PT: \(n_{MgCl_2}=n_{MgO}=0,1\left(mol\right)\)
=> \(m_{MgCl_2}=0,1.95=9,5\left(g\right)\)
Ta có: \(m_{dd_{MgCl_2}}=4+100=104\left(g\right)\)
=> \(C_{\%_{MgCl_2}}=\dfrac{9,5}{104}.100\%=9,13\%\)
PTHH: \(MgO+H_2SO_4\rightarrow MgSO_4+H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{MgO}=\dfrac{40}{40}=1\left(mol\right)\\n_{H_2SO_4}=\dfrac{300\cdot98\%}{98}=3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Axit còn dư
\(\Rightarrow\left\{{}\begin{matrix}n_{MgSO_4}=1\left(mol\right)\\n_{H_2SO_4\left(dư\right)}=2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C\%_{MgSO_4}=\dfrac{120}{300+40}\cdot100\%\approx35,3\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{2\cdot98}{300+40}\cdot100\%\approx57,65\%\end{matrix}\right.\)
a: \(n_{H_2SO_4}=0.25\cdot2=0.5\left(mol\right)\)
\(n_{Al_2O_3}=\dfrac{10.2}{27\cdot2+16\cdot3}=0.1\left(mol\right)\)
\(Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)
0,1 0,5
Vì 0,1/1<0,5/3
nên Al2O3 hết, H2SO4 dư
=>Tính theo Al2O3
b:
\(Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)
0,1 0,3 0,1
\(m_{H_2SO_4\left(pư\right)}=0.3\cdot98=29.4\left(g\right)\)
\(m_{muối}=0.1\left(54+3\cdot96\right)=34.2\left(g\right)\)