Cho 8,1g nhôm vào dung dịch axit clohiđric 3,65%
a)Tính thể tích khí thoát ra (đktc)
b)Tính khối lượng dung dịch axit đã dùng
c)Tính nồng độ phần trăm dung dịch thu được sau phản ứng
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PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
Ta có: \(n_{H_2SO_4}=0,2\cdot1,5=0,3\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{Al}=0,2\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=0,1\left(mol\right)\\n_{H_2}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Al}=0,2\cdot27=5,4\left(g\right)\\V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\\C_{M_{Al_2\left(SO_4\right)_3}}=\dfrac{0,1}{0,2}=0,5\left(M\right)\end{matrix}\right.\)
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\ a.Mg+2HCl\rightarrow MgCl_2+H_2\\ n_{H_2}=n_{MgCl_2}=n_{Mg}=0,2\left(mol\right)\\ V_{H_2\left(đktc\right)}=0,2.22,4=4,48\left(l\right)\\ b.n_{HCl}=0,2.2=0,4\left(mol\right)\\ m_{ddHCl}=\dfrac{0,4.36,5.100}{7,3}=200\left(g\right)\\ c.m_{ddsau}=4,8+200-0,2.2=204,4\left(g\right)\\ C\%_{ddMgCl_2}=\dfrac{0,2.95}{204,4}.100\approx9,295\%\\ d.V_{ddHCl}=\dfrac{200}{1,05}=\dfrac{4000}{21}\left(ml\right)=\dfrac{4}{21}\left(l\right)\\ C_{MddHCl}=\dfrac{0,4}{\dfrac{4}{21}}=2,1\left(M\right)\)
\(n_{Fe}=\dfrac{36,4}{56}=0,65\left(mol\right)\)
PTHH: Fe + 2HCl ---> FeCl2 + H2
0,65->1,3----->0,65--->0,65
=> \(\left\{{}\begin{matrix}a,V_{ddHCl}=\dfrac{1,3}{0,5}=2,6\left(l\right)\\b,V_{H_2}=0,65.22,4=14,56\left(l\right)\end{matrix}\right.\)
c, \(C_{M\left(FeCl_2\right)}=\dfrac{0,65}{2,6}=0,25M\)
a)
$n_{Al} = 0,3(mol)$
$2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$
Theo PTHH :
$n_{H_2SO_4} = \dfrac{3}{2}n_{Al} = 0,45(mol)$
$m_{dd\ H_2SO_4} = \dfrac{0,45.98}{12,25\%} = 360(gam)$
b)
$n_{H_2} = n_{H_2SO_4} = 0,45(mol)$
$V_{H_2} = 0,45.22,4 = 10,08(lít)$
c)
$n_{Al_2(SO_4)_3} = 0,15(mol)$
$m_{dd\ sau\ pư} = 8,1 + 360 - 0,45.2 = 367,2(gam)$
$C\%_{Al_2(SO_4)_3} = \dfrac{0,15.342}{367,2}.100\% = 14\%$
\(a,n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\)
PTHH: Zn + 2HCl ---> ZnCl2 + H2
0,125->0,25----->0,125->0,125
\(\Rightarrow\left\{{}\begin{matrix}a,V_{ddHCl}=\dfrac{0,25}{0,5}=0,5\left(l\right)\\b,V_{H_2}=0,125.22,4=2,8\left(l\right)\\c,C_{M\left(ZnCl_2\right)}=\dfrac{0,125}{0,5}=0,25M\end{matrix}\right.\)
a) \(n_{Al}=\dfrac{0,54}{27}=0,02\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
_____0,02->0,06---->0,02--->0,03
=> VH2 = 0,03.22,4 = 0,672 (l)
b) mHCl = 0,06.36,5 = 2,19 (g)
=> \(C\%_{ddHCl}=\dfrac{2,19}{100}.100\%=2,19\%\)
`a)`
`2Al+6HCl->2AlCl_3+3H_2`
`n_{Al}={0,54}/{27}=0,02(mol)`
`n_{H_2}=3/{2}n_{Al}=0,03(mol)`
`V_{H_2}=0,03.22,4=0,672(l)`
`b)`
`n_{HCl}=2n_{H_2}=0,06(mol)`
`C%_{HCl}={0,06.36,5}/{100}.100%=2,19%`
`a)PTHH:`
`2Al + 6HCl -> 2AlCl_3 + 3H_2`
`0,2` `0,6` `0,3` `(mol)`
`n_[Al]=[5,4]/27=0,2(mol)`
`b)V_[H_2]=0,3.22,4=6,72(l)`
`c)m_[dd HCl]=[0,6.36,5]/10 . 100 =219(g)`
a)
$n_{Al} = \dfrac{8,1}{27} = 0,3(mol)$
$2Al + 6HCl \to 2AlCl_3 + 3H_2$
Theo PTHH :
$n_{H_2} = \dfrac{3}{2}n_{Al} = 0,45(mol)$
$V_{H_2} = 0,45.22,4 = 10,08(lít)$
b) $n_{HCl} = 3n_{Al} = 0,9(mol)$
$\Rightarrow m_{dd\ HCl} = \dfrac{0,9.36,5}{3,65\%} = 900(gam)$
c)
$m_{dd\ sau\ pư}= 8,1 + 900 - 0,45.2 = 907,2(gam)$
$n_{Al_2(SO_4)_3} = \dfrac{1}{2}n_{Al} = 0,15(mol)$
$C\%_{Al_2(SO_4)_3} = \dfrac{0,15.342}{907,2}.100\% = 5,65\%$