Câu 1: Cho 200ml dung dịch Cu(NO3)2 1,5M tác dụng hoàn toàn với dd NaOH 2M
a) Tính khối lượng kết tủa thu đc
b) Tính thể tích dd NaOH 2M
c) Tính nồng độ mol dd thu đc sau p/ứ
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nFeCl3=0,1mol
nKOH=0,4mol
FeCl3+3KOH→Fe(OH)3↓+3KCl
-Tỉ lệ: 0,11<0,43→KOH dư
nFe(OH)3=nFeCl3=0,1mol
mFe(OH)3=0,1.107=10,7gam
2Fe(OH)3t0→Fe2O3+3H2O
nFe2O3=12nFe(OH)3=12.0,1=0,05mol
mFe2O3=0,05.160=8gam
nKCl=nKOH(pu)=3nFeCl3=0,3mol
nKOH(dư)=0,4−0,3=0,1mol
Vdd=0,1+0,4=0,5l
CMKOH=nv=0,10,5=0,2M
CMKCl=nv=0,30,5=0,6M
a, PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_{2\downarrow}\)
\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)
b, Ta có: \(n_{Mg}=\dfrac{9,6}{24}=0,4\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Mg}=0,8\left(mol\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{0,8}{0,2}=4\left(M\right)\)
c, Theo PT: \(n_{MgO}=n_{Mg}=0,4\left(mol\right)\)
\(\Rightarrow m_{MgO}=0,4.40=16\left(g\right)\)
\(n_{MgCl_2}=0,15.0,2=0,03(mol)\\ PTHH:MgCl_2+2NaOH\to Mg(OH)_2\downarrow +2NaCl\\ a,n_{Mg(OH)_2}=n_{MgCl_2}=0,03(mol)\\ \Rightarrow m_{\downarrow}=m_{Mg(OH)_2}=0,03.58=1,74(g)\\ b,n_{NaOH}=2n_{MgCl_2}=0,06(mol)\\ \Rightarrow C_{M_{NaOH}}=\dfrac{0,06}{0,3}=0,2M\\ c,PTHH:Mg(OH)_2\xrightarrow{t^o}MgO+H_2O\\ \Rightarrow n_{MgO}=n_{Mg(OH)_2}=0,03(mol)\\ \Rightarrow m_{A}=m_{MgO}=0,03.40=1,2(g)\)
\(n_{H_2SO_4}=1.0,2=0,2(mol)\\ H_2SO_4+BaCl_2\to BaSO_4\downarrow+2HCl\\ \Rightarrow n_{BaSO_4}=n_{BaCl_2}=0,2(mol)\\ a,m_{BaSO_4}=0,2.233=46,6(g)\\ b,V_{dd_{BaCl_2}}=\dfrac{0,2}{1,5}\approx 0,13(l)\\ c,n_{HCl}=0,4(mol)\\ \Rightarrow C_{M_{HCl}}=\dfrac{0,4}{0,2+0,13}\approx 1,21M\)
\(d,\) Dd sau p/ứ là HCl nên làm quỳ tím hóa đỏ
\(n_{H_2SO_4}=0,2.1=0,2\left(mol\right)\\ H_2SO_4+BaCl_2\rightarrow BaSO_4+2HCl\\ n_{BaCl_2}=n_{BaSO_4}=n_{H_2SO_4}=0,2\left(mol\right)\\ n_{HCl}=2.0,2=0,4\left(mol\right)\\ a,m_{\downarrow}=m_{BaSO_4}=0,2.233=46,6\left(g\right)\\ b,V_{\text{dd}BaCl_2}=\dfrac{0,2}{1,5}=\dfrac{2}{15}\left(l\right)\\ c,C_{M\text{dd}HCl}=\dfrac{0,4}{\dfrac{2}{15}+0,2}=1,2\left(M\right)\\ d,V\text{ì}.c\text{ó}.\text{dd}.HCl\Rightarrow Qu\text{ỳ}.ho\text{á}.\text{đ}\text{ỏ}\)
\(a,PTHH:3NaOH+FeCl_3\rightarrow3NaCl+Fe\left(OH\right)_3\downarrow\\ 2Fe\left(OH\right)_3\rightarrow^{t^o}Fe_2O_3+3H_2O\uparrow\\ b,n_{FeCl_3}=1,5\cdot0,2=0,3\left(mol\right)\\ \Rightarrow n_{NaOH}=3n_{FeCl_3}=0,9\left(mol\right)\\ \Rightarrow V_{dd_{NaOH}}=\dfrac{0,9}{2}=0,45\left(l\right)\)
Theo đề: \(\left\{{}\begin{matrix}X:Fe\left(OH\right)_3\\A:NaCl\\Y:Fe_2O_3\end{matrix}\right.\)
Theo PT: \(n_{NaCl}=3n_{FeCl_3}=0,9\left(mol\right)\)
\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,9}{0,45+0,2}\approx1,4M\)
\(c,\) Theo PT: \(n_{Fe\left(OH\right)_3}=n_{FeCl_3}=0,3\left(mol\right);n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_X=m_{Fe\left(OH\right)_3}=0,3\cdot107=32,1\left(g\right)\\m_Y=m_{Fe_2O_3}=0,15\cdot160=24\left(g\right)\end{matrix}\right.\)
Ta có: \(n_{Cu\left(NO_3\right)_2}=0,2.1,5=0,3\left(mol\right)\)
PT: \(Cu\left(NO_3\right)_2+2NaOH\rightarrow Cu\left(OH\right)_{2\downarrow}+2NaNO_3\)
_______0,3_______0,6_______0,3_________0,6 (mol)
a, mCu(OH)2 = 0,3.98 = 29,4 (g)
b, \(V_{ddNaOH}=\dfrac{0,6}{2}=0,3\left(l\right)\)
c, \(C_{M_{NaNO_3}}=\dfrac{0,6}{0,2+0,3}=1,2M\)
Bạn tham khảo nhé!
a) \(n_{Cu\left(NO_3\right)_2}=1,5.0,2=0,3\left(mol\right)\)
\(Cu\left(NO_3\right)_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\)
\(n_{Cu\left(OH\right)_2}=n_{Cu\left(NO_3\right)_2}=0,3\left(mol\right)\)
=> \(m_{Cu\left(OH\right)_2}=29,4\left(g\right)\)
b) \(n_{NaOH}=2n_{Cu\left(OH\right)_2}=0,6\left(mol\right)\)
=> \(V_{NaOH}=\dfrac{0,6}{2}=0,3\left(l\right)\)
c) \(CM_{NaCl}=\dfrac{0,3.2}{0,2+0,3}=1,2M\)