Cho hỗn hợp 6,2g kali, natri vào nước thu được 2,24 lít hiđrô. Tính khối lượng natri và kali phản ứng
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`2Na+2H_2O->2NaOH+H_2`
x-----------------------------`1/2`x mol
`2K+2H_2O->2KOH+H_2`
y---------------------------`1/2` y mol
`n_(H_2)=(6,72)/(22,4)=0,3 mol`
Ta có phương trình :
\(\left\{{}\begin{matrix}23x+39y=9,3\\\dfrac{1}{2}x+\dfrac{1}{2}y=0,3\end{matrix}\right.\)
-> nghiệm vô lí
`#YBTran~`
\(n_{Na}=\dfrac{4.6}{23}=0.2\left(mol\right)\)
\(n_K=\dfrac{3.9}{39}=0.1\left(mol\right)\)
\(Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\)
\(K+H_2O\rightarrow KOH+\dfrac{1}{2}H_2\)
\(V_{H_2}=\left(\dfrac{0.2}{2}+\dfrac{0.1}{2}\right)\cdot22.4=3.36\left(l\right)\)
\(m_{bazo}=0.2\cdot40+0.1\cdot56=13.6\left(g\right)\)
\(n_{Na}=\dfrac{6,9}{23}=0,3\left(mol\right)\\ 2Na+2H_2O\rightarrow2NaOH+H_2\\ n_{H_2}=\dfrac{0,3}{2}=0,15\left(mol\right)\\ a,V_{H_2\left(đktc\right)}=0,15.22,4=3,36\left(l\right)\\ b,m_{ddsaup.ứ}=m_{Na}+m_{H_2O}-m_{H_2}=6,9+100-0,15.2=106,6\left(g\right)\)
\(n_{Na}=\dfrac{m}{M}=\dfrac{3,45}{23}=0,15\left(mol\right)\\ n_{Na_2O}=\dfrac{m}{M}=\dfrac{6,2}{62}=0,1\left(mol\right)\\ PTHH:2Na+2H_2O->2NaOH+H_2\left(1\right)\)
tỉ lệ 2 : 2 : 2 ; 1
n(mol) 0,15---->0,15------->0,15----->0,075
\(m_{NaOH\left(1\right)}=n\cdot M=0,15\cdot40=6\left(g\right)\)
\(PTHH:Na_2O+H_2O->2NaOH\left(2\right)\)
tỉ lệ 1 ; 1 ; 2
n(mol) 0,1----->0,1------->0,2
\(m_{NaOH\left(2\right)}=n\cdot M=0,2\cdot40=8\left(g\right)\\ =>m_{NaOH}=m_{NaOH\left(1\right)}+m_{NaOH\left(2\right)}=6+8=14\left(g\right)\)
a,\(n_{Na}=\dfrac{4,6}{23}=0,2\left(mol\right);n_K=\dfrac{3,9}{39}=0,1\left(mol\right)\)
PTHH: 2Na + 2H2O → 2NaOH + H2
Mol: 0,2 0,1
PTHH: 2K + 2H2O → 2KOH + H2
Mol: 0,1 0,05
b, \(n_{H_2}=0,1+0,05=0,15\left(mol\right)\)
\(V_{H_2}=0,15.22,4=3,36\left(l\right)\)
c,mdd sau pứ=4,6+3,9+91,5-0,15.2=99,7 (g)
\(\%m_{NaOH}=\dfrac{0,2.40.100\%}{99,7}=8,02\%\)
\(\%m_{KOH}=\dfrac{0,1.56.100\%}{99,7}=5,62\%\)
Bài 3 :
\(n_{Na}=\dfrac{4,6}{23}=0,2\left(mol\right)\)
\(n_K=\dfrac{3,9}{39}=0,1\left(mol\right)\)
a) Pt : \(2Na+2H_2O\rightarrow2NaOH+H_2|\)
2 2 2 1
0,2 0,2 0,1
\(2K+2H_2O\rightarrow2KOH+H_2|\)
2 2 2 1
0,1 0,1 0,05
b) \(n_{H2\left(tổng\right)}=0,1+0,05=0,15\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,15.22,4=3,36\left(l\right)\)
c) \(n_{NaOH}=\dfrac{0,1.2}{1}=0,2\left(mol\right)\)
⇒ \(m_{NaOH}=0,2.40=8\left(g\right)\)
\(n_{KOH}=\dfrac{0,05.2}{1}=0,1\left(mol\right)\)
⇒ \(m_{KOH}=0,1.56=5,6\left(g\right)\)
\(m_{ddspu}=8,5+91,5-\left(0,15.2\right)=99,7\left(g\right)\)
\(C_{NaOH}=\dfrac{8.100}{99,7}=8,02\)0/0
\(C_{KOH}=\dfrac{5,6.100}{99,7}=5,62\)0/0
Chúc bạn học tốt
a) nH2=0,05(mol)
Na + H2O -> NaOH + 1/2 H2
0,1_______________0,05(mol)
Na2O + H2O -> 2 NaOH
b) => mNa=0,1.23=2,3(g)
=>nNa2O= 14,7 - 2,3= 12,4(g)
a;
2K + 2H2O -> 2KOH + H2 (1)
2Na + 2H2O -> 2NaOH + H2 (2)
Đặt nK=a
nNa=b
Ta có:
\(\left\{{}\begin{matrix}39a+23b=3,4\\\dfrac{1}{2}b=a\end{matrix}\right.\)
=>a=0,04;b=0,08
Tự tính tiếp nhé
Gọi $n_{Na} = a(mol) ; n_{K} = b(mol)$
Ta có :$23a + 39b = 6,2(1)$
$2Na + 2H_2O \to 2NaOH + H_2$
$2K + 2H_2O \to 2KOH + H_2$
Theo PTHH :
$n_{H_2} = 0,5a + 0,5b = 0,1(2)$
Từ (1)(2) suy ra a = b = 0,1
Vậy :
$m_{K} = 0,1.39 = 3,9(gam)$
$m_{Na} = 0,1.23 = 2,3(gam)$
So mol cua khi hidro
nH2 = \(\dfrac{V_{H2}}{22,4}=\dfrac{2,24}{22,4}=0,1\) (mol)
Pt : 2K + 2H2O \(\rightarrow\) 2KOH + H2
2Na + 2H2O \(\rightarrow\) 2NaOH + H2
Khoi luong cua kali
mK = 39 . 0,1
= 3,9 (g)
Khoi luong cua natri
mNa = 6,2 - 3,9
= 2,3 (g)
Chuc ban hoc tot