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\(1,2H_2+O_2\underrightarrow{t}2H_2O\)
\(2Mg+O_2\underrightarrow{t}2MgO\)
\(2Cu+O_2\underrightarrow{t}2CuO\)
\(S+O_2\underrightarrow{t}SO_2\)
\(4Al+3O_2\underrightarrow{t}2Al_2O_3\)
\(C+O_2\underrightarrow{t}CO_2\)
\(4P+5O_2\underrightarrow{t}2P_2O_5\)
\(2,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(a,n_{O_2}=0,2\left(mol\right)\Rightarrow n_{CO_2}=0,2\left(mol\right)\Rightarrow m_{CO_2}=8,8\left(g\right)\)
\(b,n_C=0,3\left(mol\right)\Rightarrow n_{CO_2}=0,3\left(mol\right)\Rightarrow m_{CO_2}=13,2\left(g\right)\)
c, Vì\(\frac{0,3}{1}>\frac{0,2}{1}\)nên C phản ửng dư, O2 phản ứng hết, Bài toán tính theo O2
\(n_{O_2}=0,2\left(mol\right)\Rightarrow n_{CO_2}=0,2\left(mol\right)\Rightarrow m_{CO_2}=8,8\left(g\right)\)
\(3,PTHH:CH_4+2O_2\underrightarrow{t}CO_2+2H_2O\)
\(C_2H_2+\frac{5}{2}O_2\underrightarrow{t}2CO_2+H_2O\)
\(C_2H_6O+3O_2\underrightarrow{t}2CO_2+3H_2O\)
\(4,a,PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
\(n_P=1,5\left(mol\right)\Rightarrow n_{O_2}=1,2\left(mol\right)\Rightarrow m_{O_2}=38,4\left(g\right)\)
\(b,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(n_C=2,5\left(mol\right)\Rightarrow n_{O_2}=2,5\left(mol\right)\Rightarrow m_{O_2}=80\left(g\right)\)
\(c,PTHH:4Al+3O_2\underrightarrow{t}2Al_2O_3\)
\(n_{Al}=2,5\left(mol\right)\Rightarrow n_{O_2}=1,875\left(mol\right)\Rightarrow m_{O_2}=60\left(g\right)\)
\(d,PTHH:2H_2+O_2\underrightarrow{t}2H_2O\)
\(TH_1:\left(đktc\right)n_{H_2}=1,5\left(mol\right)\Rightarrow n_{O_2}=0,75\left(mol\right)\Rightarrow m_{O_2}=24\left(g\right)\)
\(TH_2:\left(đkt\right)n_{H_2}=1,4\left(mol\right)\Rightarrow n_{O_2}=0,7\left(mol\right)\Rightarrow m_{O_2}=22,4\left(g\right)\)
\(5,PTHH:S+O_2\underrightarrow{t}SO_2\)
\(n_{O_2}=0,46875\left(mol\right)\)
\(n_{SO_2}=0,3\left(mol\right)\)
Vì\(0,46875>0,3\left(n_{O_2}>n_{SO_2}\right)\)nên S phản ứng hết, bài toán tính theo S.
\(a,\Rightarrow n_S=n_{SO_2}=0,3\left(mol\right)\Rightarrow m_S=9,6\left(g\right)\)
\(n_{O_2}\left(dư\right)=0,16875\left(mol\right)\Rightarrow m_{O_2}\left(dư\right)=5,4\left(g\right)\)
\(6,a,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_C=1,5\left(mol\right)\Rightarrow m_C=18\left(g\right)\)
\(b,PTHH:2H_2+O_2\underrightarrow{t}2H_2O\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_{H_2}=0,75\left(mol\right)\Rightarrow m_{H_2}=1,5\left(g\right)\)
\(c,PTHH:S+O_2\underrightarrow{t}SO_2\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_S=1,5\left(mol\right)\Rightarrow m_S=48\left(g\right)\)
\(d,PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_P=1,2\left(mol\right)\Rightarrow m_P=37,2\left(g\right)\)
\(7,n_{O_2}=5\left(mol\right)\Rightarrow V_{O_2}=112\left(l\right)\left(đktc\right)\);\(V_{O_2}=120\left(l\right)\left(đkt\right)\)
\(8,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(m_C=0,96\left(kg\right)\Rightarrow n_C=0,08\left(kmol\right)=80\left(mol\right)\Rightarrow n_{O_2}=80\left(mol\right)\Rightarrow V_{O_2}=1792\left(l\right)\)
\(9,n_p=0,2\left(mol\right);n_{O_2}=0,3\left(mol\right)\)
\(PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
Vì\(\frac{0,2}{4}< \frac{0,3}{5}\)nên P hết O2 dư, bài toán tính theo P.
\(a,n_{O_2}\left(dư\right)=0,05\left(mol\right)\Rightarrow m_{O_2}\left(dư\right)=1,6\left(g\right)\)
\(b,n_{P_2O_5}=0,1\left(mol\right)\Rightarrow m_{P_2O_5}=14,2\left(g\right)\)
\(n_P=\dfrac{3,1}{31}=0,1\left(mol\right)\)
\(n_{O_2}=\dfrac{4,48}{22,4}=0,2mol\)
4P + 5O2 \(\underrightarrow{t^o}\) 2P2O5
\(\dfrac{0,1}{4}< \dfrac{0,2}{5}\) => O2 dư, Photpho đủ
\(n_{O_2}=0,2-0,04=0,16\left(mol\right)\)
\(m_{P_2O_5}=\) 0,05 . 142 = 7,1 ( g )
a. \(n_P=\frac{6,2}{31}=0,2mol\)
\(V_{O_2}=V_{kk}.\frac{1}{5}=\frac{18,48}{5}=3,696l\)
\(n_{O_2}=\frac{3,696}{22,4}=0,165mol\)
PTHH: \(4P+5O_2\xrightarrow{t^o}2P_2O_5\)
Tỷ lệ \(\frac{0,2}{4}>\frac{0,165}{5}\)
Vậy P dư
\(n_{P\left(\text{phản ứng }\right)}=\frac{4}{5}n_{O_2}=0,132mol\)
\(n_{P\left(dư\right)}=0,2-0,132=0,068mol\)
\(\rightarrow m_{P\left(dư\right)}=0,068.31=2,108g\)
b. \(n_{P_2O_5}=\frac{2}{5}n_{O_2}=0,066mol\)
\(\rightarrow m_{P_2O_5}=0,066.142=9,372g\)
c. PTHH: \(2KClO_3\xrightarrow{t^o}2KCl+3O_2\)
\(n_{KClO_3}=\frac{2}{3}n_{O_2}=0,11mol\)
\(\rightarrow m_{KClO_3}=0,11.122,5=13,475g\)
\(n_{hhkhí}=\dfrac{16,8}{22,4}=0,75\left(mol\right)\)
Gọi \(n_{SO_2}=a\left(mol\right)\left(0< a< 0,75\right)\)
\(\rightarrow n_{O_2\left(dư\right)}=0,75-b\left(mol\right)\)
Ta có: \(\dfrac{64a+32\left(0,75-a\right)}{0,75}=\dfrac{33,6}{1}=33,6\left(\dfrac{g}{mol}\right)\)
\(\rightarrow a=0,0375\left(mol\right)\)
\(\rightarrow\left\{{}\begin{matrix}\%V_{SO_2}=\dfrac{0,0375}{0,75}=5\%\\\%V_{O_2\left(dư\right)}=100\%-5\%=95\%\end{matrix}\right.\)
Câu 1:
PTHH: Fe + 2HCl ===> FeCl2 + H2
a/ nFe = 11,2 / 56 = 0,2 mol
=> nH2 = 0,2 mol
=> VH2(đktc) = 0,2 x 22,4 = 4,48 lít
b/ => nHCl = 0,2 x 2 = 0,4 mol
=> mHCl = 0,4 x 36,5 = 14,6 gam
c/ => nFeCl2 = 0,2 mol
=> mFeCl2 = 0,2 x 127 = 25,4 gam
Câu 3/
a/ Chất tham gia: S, O2
Chất tạo thành: SO2
Đơn chất: S, O2 vì những chất này chỉ do 1 nguyên tố tạo nên
Hợp chất: SO2 vì chất này do 2 nguyên tố S và O tạo tên
b/ PTHH: S + O2 =(nhiệt)==> SO2
=> nO2 = 1,5 mol
=> VO2(đktc) = 1,5 x 22,4 = 33,6 lít
c/ Khí sunfuro nặng hơn không khí
a)
\(n_{O_2} = \dfrac{11,2}{22,4} = 0,5(mol)\\ 4P + 5O_2 \xrightarrow{t^o} 2P_2O_5\\ n_P = \dfrac{4}{5}n_{O_2} = 0,4(mol)\\ \Rightarrow m_P = 0,4.31 = 12,4(gam)\)
b)
\(n_{P_2O_5} = \dfrac{2}{5}n_{O_2} = 0,2(mol)\\ \Rightarrow m_{P_2O_5} = 0,2.142 = 28,4(gam)\)
c)
\(2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2\\ n_{KMnO_4} = 2n_{O_2} = 0,5.2 = 1(mol)\\ \Rightarrow m_{KMnO_4} = 1.158 = 158(gam)\)
Bài 14
\(n_{O_2}=\dfrac{1.4}{22,4}=0,0625\left(mol\right)\)
\(n_P=\dfrac{2.5}{31}=0,0806451\left(mol\right)\)
4P + 5O2 ----to--->2P2O5
Xét tỉ lệ : \(\dfrac{0.0625}{5}< \dfrac{0.0806451}{4}\)
=> P ko cháy hết
bài 15
\(n_{O_2}=\dfrac{3.36}{22,4}=0,15\left(mol\right)\)
Gọi nFe = a ( mol ) và nS = b (mol )
PTHH :
S + O2 ---to---> SO2
3Fe + 2O2 ----to----> Fe3O4
Ta có 32b + 56a= 100
Theo PT : nS = nO2 = b (mol)
Theo PT : nO2 = 2/3 nFe = 2/3a ( mol)
=> 2/3a + b = 1,5
Từ những điều trên \(\left[{}\begin{matrix}56a+32b=100\\\dfrac{2}{3}a+b=1,5\end{matrix}\right.\Leftrightarrow\left[{}\begin{matrix}a=1,5\left(mol\right)\\b=0,5\left(mol\right)\end{matrix}\right.\)
\(m_{Fe}=1,5.56=84\left(g\right)\)
\(m_S=0,5.32=16\left(g\right)\)