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Zn+2HCl->ZnCl2+H2
ZnO+2HCl->ZnCl2+H2O
nH2=0.2(mol)->nZn=0.2(mol).mZn=13(g)
mZnO=21.1-13=8.1(g)
nZnO=0.1(mol)
Tổng nHCl cần dùng:0.2*2+0.1*2=0.6(mol)
mHCl=21.9(g)
C%ddHCl=21.9:200*100=10.95%
n muối=0.2+.1=0.3(mol)
m muối=40.8(g)
Đặt: \(n_{Zn}=a\left(mol\right);n_{ZnO}=b\left(mol\right)\left(a,b>0\right)\)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(a.Zn+2HCl\rightarrow ZnCl_2+H_2\\ ZnO+2HCl\rightarrow ZnCl_2+H_2O\\ \Rightarrow\left\{{}\begin{matrix}65a+81b=14,6\\a=0,1\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\\ b.m_{Zn}=0,1.65=6,5\left(g\right)\\ m_{ZnO}=0,1.81=8,1\left(g\right)\\ d.m_{ddHCl}=\dfrac{\left(0,1+0,1\right).2.36,5.100}{7,3}=200\left(g\right)\)
a) PTHH : \(Zn+H_2SO_4-->ZnSO_4+H_2\uparrow\) (1)
\(ZnO+H_2SO_4-->ZnSO_4+H_2O\) (2)
b) Theo pthh (1) : \(n_{Zn}=n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
=> \(m_{Zn}=0,1.65=6,5\left(g\right)\)
=> \(m_{ZnO}=22,7-6,5=16,2\left(g\right)\)
c) \(ZnO=\dfrac{16,2}{81}=0,2\left(mol\right)\)
Theo pthh (1) và (2) : \(\Sigma n_{H2SO4}=n_{Zn}+n_{ZnO}=0,1+0,2=0,3\left(mol\right)\)
=> \(C_{M\left(ddH2SO4\right)}=\dfrac{0,3}{0,1}=1,5M\)
a) PTHH : Zn+H2SO4−−>ZnSO4+H2↑Zn+H2SO4−−>ZnSO4+H2↑ (1)
ZnO+H2SO4−−>ZnSO4+H2OZnO+H2SO4−−>ZnSO4+H2O (2)
b) Theo pthh (1) : nZn=nH2=2,2422,4=0,1(mol)nZn=nH2=2,2422,4=0,1(mol)
=> mZn=0,1.65=6,5(g)mZn=0,1.65=6,5(g)
=> mZnO=22,7−6,5=16,2(g)mZnO=22,7−6,5=16,2(g)
c) ZnO=16,281=0,2(mol)ZnO=16,281=0,2(mol)
Theo pthh (1) và (2) : ΣnH2SO4=nZn+nZnO=0,1+0,2=0,3(mol)ΣnH2SO4=nZn+nZnO=0,1+0,2=0,3(mol)
=> CM(ddH2SO4)=0,30,1=1,5M
tích đúng đê
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
b, Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,1.65}{10}.100\%=65\%\\\%m_{ZnO}=35\%\end{matrix}\right.\)
c, \(n_{HCl}=0,1.0,5=0,05\left(mol\right)\)
\(n_{NaOH}=0,03.1=0,03\left(mol\right)\)
PT: \(HCl+NaOH\rightarrow NaCl+H_2O\)
Xét tỉ lệ: \(\dfrac{0,05}{1}>\dfrac{0,03}{1}\), ta được HCl dư.
→ Quỳ tím chuyển đỏ do acid dư.
C32:
a, \(n_C=\dfrac{2,4}{12}=0,2\left(mol\right)\)
PT: \(C+O_2\underrightarrow{t^o}CO_2\)
Theo PT: \(n_{CO_2}=n_C=0,2\left(mol\right)\Rightarrow V_{CO_2}=0,2.22,4=4,48\left(l\right)\)
b, \(n_{NaOH}=0,3.1=0,3\left(mol\right)\)
\(\Rightarrow\dfrac{n_{NaOH}}{n_{CO_2}}=1,5\) → Pư tạo NaHCO3 và Na2CO3
PT: \(CO_2+NaOH\rightarrow NaHCO_3\)
\(CO_2+2NaOH\rightarrow Na_2CO_3+H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{CO_2}=n_{NaHCO_3}+n_{Na_2CO_3}=0,2\\n_{NaOH}=n_{NaHCO_3}+2n_{Na_2CO_3}=0,3\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}n_{NaHCO_3}=0,1\left(mol\right)\\n_{Na_2CO_3}=0,1\left(mol\right)\end{matrix}\right.\)
⇒ mNaHCO3 = 0,1.84 = 8,4 (g)
mNa2CO3 = 0,1.106 = 10,6 (g)
c, \(C_{M_{NaHCO_3}}=C_{M_{Na_2CO_3}}=\dfrac{0,1}{0,3}=\dfrac{1}{3}\left(M\right)\)
Lần sau bạn đăng tách câu hỏi ra nhé.
C31:
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
b, \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,1.65}{14,6}.100\%\approx44,52\%\\\%m_{ZnO}\approx55,48\%\end{matrix}\right.\)
c, \(n_{ZnO}=\dfrac{14,6-0,1.65}{81}=0,1\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Zn}+2n_{ZnO}=0,4\left(mol\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{0,4.36,5}{10\%}=146\left(g\right)\)
CuO +2HCl= CuCl2 +H2O
ZnO+2HCl= ZnCl2 +H2O
gọi x,y là mol của CuO, ZnO
80x + 81y = 12.1
2x+2y = 0.3
=> x=0.05 , y=0.1 => mCuO= 4 %CuO=4/12.1 m ZnO=8.1 =>%ZnO=8.1/12.1
nH2SO4=1/2nHCl=0.3/2 =0.15
mH2SO4=0.15x98=14.7g => mddH2SO4=14.7/20%=73.5g
Câu 5 :
\(n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
a) Pt : \(Mg+2HCl\rightarrow MgCl_2+H_2|\)
1 2 1 1
0,1 0,2 0,1 0,1
\(MgO+2HCl\rightarrow MgCl_2+H_2O|\)
1 2 1 1
0,15 0,3 0,15
a) \(n_{Mg}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(m_{Mg}=0,1.24=2,4\left(g\right)\)
\(m_{MgO}=8,4-2,4=6\left(g\right)\)
0/0Mg = \(\dfrac{2,4.100}{8,4}=28,57\)0/0
0/0MgO = \(\dfrac{6.100}{8,4}=71,43\)0/0
b) Có : \(m_{MgO}=6\left(g\right)\)
\(n_{MgO}=\dfrac{6}{40}=0,15\left(mol\right)\)
\(n_{HCl\left(tổng\right)}=0,2+0,3=0,5\left(mol\right)\)
\(m_{HCl}=0,5.36,5=18,25\left(g\right)\)
\(m_{ddHCl}=\dfrac{18,25.100}{3,65}=500\left(g\right)\)
\(n_{MgCl2\left(tổng\right)}=0,1+0,15=0,25\left(mol\right)\)
⇒ \(m_{MgCl2}=0,15.95=14,25\left(g\right)\)
\(m_{ddspu}=8,4+500-\left(0,1.2\right)=508,2\left(g\right)\)
\(C_{MgCl2}=\dfrac{14,25.100}{508,2}=2,8\)0/0
Chúc bạn học tốt
`a)`
`Zn+2HCl->ZnCl_2+H_2`
`ZnO+2HCl->ZnCl_2+H_2O`
`b)`
Theo PT: `n_{Zn}=n_{H_2}={2,24}/{22,4}=0,1(mol)`
`->m_{Zn}=0,1.65=6,5(g)`
`->m_{ZnO}=14,6-6,5=8,1(g)`
giúp tui vss