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a)
$n_{Cl_2} : n_{O_2} = 1 : 2$
Suy ra :
$\%V_{Cl_2} = \dfrac{1}{1 + 2}.100\% = 33,33\%$
$\%V_{O_2} = \dfrac{2}{1 + 2}.100\% = 66,67\%$
b)
Coi $n_{Cl_2} = 1 (mol) \Rightarrow n_{O_2} = 2(mol)$
$\%m_{Cl_2} = \dfrac{1.71}{1.71 + 2.32}.100\% = 52,59\%$
$\%m_{O_2} = 100\% -52,59\% = 47,41\%$
c)
$M_A = \dfrac{71.1 + 32.2}{1 + 2} = 45(g/mol)$
$d_{A/B} = \dfrac{45}{28} = 1,607$
Bài 2:
a) Vì khối lượng mol của N2 và CO đều bằng 28 và lớn hơn khối lượng mol của khí metan CH4 (28>16)
=> \(d_{\dfrac{hhX}{CH_4}}=\dfrac{28}{16}=1,75\)
Hỗn hợp X nhẹ hơn không khí (28<29)
b)
\(M_{C_2H_4}=M_{N_2}=M_{CO}=28\left(\dfrac{g}{mol}\right)\\ \rightarrow M_{hhY}=28\left(\dfrac{g}{mol}\right)\\ d_{\dfrac{Y}{H_2}}=\dfrac{28}{2}=14\)
c) \(\%V_{NO}=100\%-\left(30\%+30\%\right)=40\%\\ \rightarrow\%n_{CH_4}=40\%\\ Vì:\%m_{CH_4}=22,377\%\\ Nên:\dfrac{30\%.16}{40\%.30+30\%.16+30\%.\left(x.14+16\right)}=22,377\%\\ \Leftrightarrow x=-0,03\)
Sao lại âm ta, để xíu anh xem lại như nào nhé.
Bài 1:
\(a.\\ d_{\dfrac{SO_2}{O_2}}=\dfrac{64}{32}=2\\ d_{\dfrac{SO_2}{N_2}}=\dfrac{64}{28}=\dfrac{16}{7}\\ d_{\dfrac{SO_2}{SO_3}}=\dfrac{64}{80}=0,8\\ d_{\dfrac{SO_2}{CO}}=\dfrac{64}{28}=\dfrac{16}{7}\\ d_{\dfrac{SO_2}{N_2O}}=\dfrac{64}{44}=\dfrac{16}{11}\\ d_{\dfrac{SO_2}{NO_2}}=\dfrac{64}{46}=\dfrac{32}{23}\\ b.M_{hhA}=\dfrac{1.64+1.32}{1+1}=48\left(\dfrac{g}{mol}\right)\\ d_{\dfrac{hhA}{O_2}}=\dfrac{48}{32}=1,5\)
Giả sử có 1 mol khí Cl2, 2 mol khí O2
a) \(\left\{{}\begin{matrix}\%V_{Cl_2}=\dfrac{1}{1+2}.100\%=33,33\%\\\%V_{O_2}=\dfrac{2}{1+2}.100\%=66,67\%\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%m_{Cl_2}=\dfrac{1.71}{1.71+2.32}.100\%=52,59\%\\\%m_{O_2}=\dfrac{2.32}{1.71+2.32}.100\%=47,41\%\end{matrix}\right.\)
b) \(\overline{M}=\dfrac{1.71+2.32}{1+2}=45\left(g/mol\right)\)
=> \(d_{A/H_2}=\dfrac{45}{2}=22,5\)
c) \(n_A=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
=> mA = 0,3.45 = 13,5 (g)
Giả sử các khí được đo ở điều kiện sao cho 1 mol khí chiếm thể tích 1 lít
Gọi số mol CH4, C2H6 là a, b (mol)
=> \(a+b=\dfrac{25}{1}=25\left(mol\right)\) (1)
\(n_{O_2}=\dfrac{95}{1}=95\left(mol\right)\)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
a---->2a---------->a
2C2H6 + 7O2 --to--> 4CO2 + 6H2O
b------>3,5b-------->2b
=> \(\left\{{}\begin{matrix}n_{O_2\left(dư\right)}=95-2a-3,5b\left(mol\right)\\n_{CO_2}=a+2b\left(mol\right)\end{matrix}\right.\)
=> \(95-a-1,5b=\dfrac{60}{1}=60\)
=> a + 1,5b = 35 (2)
(1)(2) => a = 5; b = 20
=> \(\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{5}{25}.100\%=20\%\\\%V_{C_2H_6}=\dfrac{20}{25}.100\%=80\%\end{matrix}\right.\)
\(\overline{M}_A=\dfrac{5.16+20.30}{5+20}=27,2\left(g/mol\right)\)
\(\overline{M}_B=20,5.2=41\left(g/mol\right)\)
=> \(d_{A/B}=\dfrac{27,2}{41}\approx0,663\)
\(a.\)
\(GS:\)
\(n_{hh}=1\left(mol\right)\)
\(Đặt:n_{N_2}=a\left(mol\right),n_{CO_2}=b\left(mol\right)\)
\(\Rightarrow a+b=1\left(1\right)\)
\(m_A=28a+44b=18\cdot2=36\left(2\right)\)
\(\left(1\right),\left(2\right):\)
\(a=b=0.5\)
\(\%m_{N_2}=\dfrac{0.5\cdot28}{0.5\cdot28+0.5\cdot44}\cdot100\%=38.89\%\)
\(\%m_{CO_2}=61.11\%\)
\(b.\)
\(\dfrac{n_{N_2}}{n_{CO_2}}=\dfrac{0.5}{0.5}=\dfrac{1}{1}\)
\(n_{N_2}=n_{CO_2}=\dfrac{1}{2}\cdot n_A=\dfrac{0.2}{2}=0.1\left(mol\right)\)
\(Đặt:n_{CO_2}=x\left(mol\right)\)
\(\overline{M}=\dfrac{0.1\cdot28+0.1\cdot44+44x}{0.2+x}=20\cdot2=40\left(\dfrac{g}{mol}\right)\)
\(\Rightarrow x=0.2\)
\(m_{CO_2\left(cầnthêm\right)}=0.2\cdot44=8.8\left(g\right)\)
a) Gọi số mol H2, CH4 là a, b
=> \(a+b=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
\(M_X=\dfrac{2a+16b}{a+b}=0,325.32=10,4\)
=> a = 0,2 ; b = 0,3
=> \(\left\{{}\begin{matrix}\%V_{H_2}=\dfrac{0,2}{0,5}.100\%=40\%\\\%V_{CH_4}=\dfrac{0,3}{0,5}.100\%=60\%\end{matrix}\right.\)
b) \(n_{O_2}=\dfrac{32}{32}=1\left(mol\right)\)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
0,3--->0,6------->0,3
2H2 + O2 --to--> 2H2O
0,2-->0,1
=> \(\left\{{}\begin{matrix}V_{CO_2}=0,3.22,4=6,72\left(l\right)\\V_{O_2\left(dư\right)}=\left(1-0,6-0,1\right).22,4=6,72\left(l\right)\end{matrix}\right.\)
a)
Gọi $n_{CO} = a ; n_{NO} = b$
Ta có :
$28a + 30b = (a + b). $\dfrac{103}{14}.4$
$\Rightarrow \dfrac{10}{7}a = \dfrac{4}{7}b$
$\Rightarrow \dfrac{a}{b} = \dfrac{2}{5}(1)$
b)
$28a + 30b = 20,6(2)$
Từ (1)(2) suy ra a = 0,2 ;b = 0,5
$n_{O_2} = 0,5(mol)$
2CO + O2 \(\xrightarrow{t^o}\) 2CO2
0,2..........0,1............0,2........(mol)
2NO + O2 \(\xrightarrow{t^o}\) 2NO2
0,5.........0,25...........0,5............(mol)
Sau phản ứng, B gồm :
CO2 : 0,2 mol
NO2 : 0,5 mol
O2 dư : 0,5 - 0,25 - 0,1 = 0,15(mol)
$n_{hh} = 0,2 + 0,5 + 0,15 = 0,85\ mol$
$\%n_{CO_2} = \dfrac{0,2}{0,85}.100\% = 23,53\%$
$\%n_{NO_2} = \dfrac{0,5}{0,85} .100\% = 58,82\%$
$\%n_{O_2\ dư} = 17,65\%$
Bảo toàn khối lượng : $m_B = m_A + m_{O_2} = 20,6 + 0,5.32 = 36,6(gam)$
$M_B = \dfrac{36,6}{0,85} = 43,06(g/mol)$
$d_{B/He} = \dfrac{43,06}{4} = 10,765$
a) \(M_A=\dfrac{103}{14}.4=\dfrac{206}{7}\)
Lập sơ đồ đường chéo :
=> \(\dfrac{n_{CO}}{n_{NO}}=\dfrac{30-\dfrac{206}{7}}{\dfrac{206}{7}-28}=\dfrac{2}{5}\)
b)Gọi x, y lần lượt là số mol CO, NO
=> \(\left\{{}\begin{matrix}28x+30y=20,6\\\dfrac{x}{y}=\dfrac{2}{5}\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}x=0,2\\y=0,5\end{matrix}\right.\)
\(n_{O_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
2CO + O2 → 2CO2
0,2---->0,1---->0,2
2NO + O2 → 2NO2
0,5---->0,25--->0,5
=> Hỗn hợp khí B gồm : \(\left\{{}\begin{matrix}O_{2\left(dư\right)}=0,5-\left(0,1+0,25\right)=0,15\left(mol\right)\\n_{CO_2}=0,2\left(mol\right)\\n_{NO_2}=0,5\left(mol\right)\end{matrix}\right.\)
=> \(M_B=\dfrac{0,15.32+0,2.44+0,5.46}{0,15+0,2+0,5}=\dfrac{732}{17}\)
dB/He= \(\dfrac{732}{17}:4=\dfrac{183}{17}\approx10,77\)