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\(n_{O_2}=\dfrac{8}{32}=0.25\left(mol\right)\)
\(CH_4+2O_2\underrightarrow{t^0}CO_2+2H_2O\)
\(0.125....0.25....0.125\)
\(m_{CH_4}=0.125\cdot16=2\left(g\right)\)
\(V_{CO_2}=0.125\cdot22.4=2.8\left(l\right)\)
\(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\)
\(............0.125.....0.125\)
\(m_{CaCO_3}=0.125\cdot100=12.5\left(g\right)\)
a, \(n_{CO_2}=\dfrac{17,6}{44}=0,4\left(mol\right)\)
CH4 + 2O2 -----to---> CO2 + 2H2O
x x
C2H4 + 3O2 -----to---> 2CO2 + 2H2O
y 2y
Ta có hệ pt: \(\left\{{}\begin{matrix}16x+28y=6\\x+2y=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)
\(\%m_{CH_4}=\dfrac{0,2.16.100\%}{6}=53,33\%;\%m_{C_2H_4}=100\%-53,33\%=46,67\%\)
b, \(\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,2.22,4.100\%}{\left(0,2+0,1\right).22,4}=66,67\%\\\%V_{C_2H_4}=100\%-66,67\%=33,33\%\end{matrix}\right.\)
\(n_{C_2H_2}=a\left(mol\right),n_{CH_4}=b\left(mol\right)\)
\(\Rightarrow a+b=0.2\left(1\right)\)
\(n_{CO_2}=\dfrac{13.2}{44}=0.3\left(mol\right)\)
\(\Rightarrow2a+b=0.3\left(2\right)\)
\(\left(1\right),\left(2\right):a=b=0.1\)
\(m_{C_2H_2}=0.1\cdot26=2.6\left(g\right)\)
\(n_{C_2H_2} = a(mol) ; n_{CH_4} = b(mol)\\ \Rightarrow a + b = 0,2(1)\\ C_2H_2 + \dfrac{5}{2}O_2 \xrightarrow{t^o} 2CO_2 + H_2O\\ CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ n_{CO_2} = 2a + b = \dfrac{13,2}{44} = 0,3(2)\\ (1)(2)\Rightarrow a = 0,1 ; b = 0,2\\ m_{C_2H_2} = 0,1.26 = 2,6(gam)\)
\(a,Gọi\left\{{}\begin{matrix}n_{CH_4}=a\left(mol\right)\\n_{C_2H_4}=b\left(mol\right)\\n_{C_2H_2}=c\left(mol\right)\end{matrix}\right.\\ n_{hhkhí}=0,4\left(mol\right)\\ n_{CO_2}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\\ n_{Br_2}=\dfrac{64}{160}=0,4\left(mol\right)\\ PTHH:C_2H_4+Br_2\rightarrow C_2H_4Br_2\\ Mol:a\rightarrow a\\ C_2H_2+2Br_2\rightarrow C_2H_2Br_4\\ Mol:b\rightarrow2b\\ CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\\ Mol:a\rightarrow2a\rightarrow a\)
\(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\\ Mol:b\rightarrow3b\rightarrow2b\\ 2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\\ Mol:c\rightarrow2,5c\rightarrow2c\\ Hệ.pt\left\{{}\begin{matrix}a+b+c=0,4\\b+2c=0,4\\a+2b+2c=0,7\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\left(mol\right)\\b=0,2\left(mol\right)\\c=0,1\left(mol\right)\end{matrix}\right.\)
\(\%V_{CH_4}=\%V_{C_2H_2}=\dfrac{0,1}{0,4}=25\%\\ \%V_{C_2H_4}=\dfrac{0,2}{0,4}=50\%\)
\(m_{CH_4}=0,1.16=1,6\left(g\right)\\ m_{C_2H_4}=28.0,2=5,6\left(g\right)\\ m_{C_2H_2}=0,1.26=2,6\left(g\right)\\ \%m_{CH_4}=\dfrac{1,6}{1,6+5,6+2,6}=16,32\%\\ \%m_{C_2H_4}=\dfrac{5,6}{1,6+5,6+2,6}=57,14\%\\ \%m_{C_2H_2}=100\%-16,32\%-57,14\%=26,54\%\)
\(b,PTHH:C_2H_5OH\rightarrow C_2H_4+H_2O\\ Mol:0,2\leftarrow0,2\\ m_{C_2H_5OH}=0,2.46=9,2\left(g\right)\)
Dài quá!!!
\(Đặt:n_{C_2H_2}=a\left(mol\right),n_{CH_4}=b\left(mol\right)\)
\(n_{hh}=a+b=0.15\left(mol\right)\left(1\right)\)
\(C_2H_2\rightarrow2CO_2\)
\(CH_4\rightarrow CO_2\)
\(n_{CO_2}=2a+b=0.2\left(mol\right)\left(2\right)\)
\(\left(1\right),\left(2\right):a=0.05,b=0.1\)
\(\%C_2H_2=\dfrac{0.05}{0.15}\cdot100\%=33.33\%\)
\(\%CH_4=66.67\%\)
\(2NaOH+CO_2\rightarrow Na_{_{ }2}CO_3+H_2O\)
\(0.4...............0.2............0.2\)
\(C_{M_{Na_2CO_3}}=\dfrac{0.2}{0.5}=0.4\left(M\right)\)
\(C_{M_{NaOH\left(dư\right)}}=\dfrac{0.5-0.4}{0.5}=0.2\left(M\right)\)
a)
\(CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_4 + 3O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O\\ CO_2 + Ca(OH)_2 \to CaCO_3 + H_2O\\ C_2H_4 + Br_2 \to C_2H_4Br_2\\ b) n_{C_2H_4} = n_{Br_2} = \dfrac{8}{160}=0,05(mol)\\ n_{CaCO_3} = n_{CO_2} = n_{CH_4} + 2n_{C_2H_4} = \dfrac{50}{100} = 0,5(mol)\\ \Rightarrow n_{CH_4} = 0,5 - 0,05.2 = 0,4(mol)\\ \%m_{CH_4}= \dfrac{0,4.16}{0,4.16 + 0,05.28}.100\% = 82,05\%\\ \%m_{C_2H_4} =100\% - 82,05\% = 17,95\%\)
\(28ml=0,028l\)
\(67,2ml=0,0672l\)
Giả sử ta đo ở đktc
Gọi \(\left\{{}\begin{matrix}n_{CH_4}=x\\n_{C_2H_2}=y\end{matrix}\right.\)
\(n_{hh}=\dfrac{0,028}{22,4}=0,00125mol\)
\(n_{O_2}=\dfrac{0,0672}{22,4}=0,003mol\)
\(CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\)
x 2x ( mol )
\(2C_2H_2+5O_2\rightarrow\left(t^o\right)4CO_2+2H_2O\)
y 5/2 y ( mol )
Ta có:
\(\left\{{}\begin{matrix}x+y=0,00125\\2x+\dfrac{5}{2}y=0,003\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,00025\\y=0,001\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,00025}{0,00125}.100=20\%\\\%V_{C_2H_2}=100\%-20\%=80\%\end{matrix}\right.\)
=> Chọn A
CH4+2O2-to->CO2+2H2o
0,0625------------0,0625
C2H4+3O2-to->2CO2+2H2O
0,036---------------0,071
C2H2+5\2O2-to->2CO2+H2O
0,038------------------0,076 mol
C6H6+15\2O2-to->6CO2+3H2O
0,013-----------------------0,08 mol
=>a<b<c<d
cảm ơn bạn