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a) CaCO3 + 2HCl --> CaCl2 + CO2 + H2O
b) \(n_{CaCO_3}=\dfrac{10}{100}=0,1\left(mol\right)\)
CaCO3 + 2HCl --> CaCl2 + CO2 + H2O
_0,1---->0,2------->0,1----->0,1
=> mCaCl2 = 0,1.111 = 11,1 (g)
=> VCO2 = 0,1.22,4 = 2,24 (l)
c) \(a=C_{M\left(HCl\right)}=\dfrac{0,2}{0,4}=0,5M\)
d) \(C_{M\left(CaCl_2\right)}=\dfrac{0,1}{0,4}=0,25M\)
a) 2Al + 6HCl -> 2AlCl3 + 3H2
Al2O3 + 6HCl -> 2AlCl3 + 3H2O
nH2 = 0,15mol => nAl=0,1mol => mAl=2,7g; mAl2O3 = 10,2g => nAl2O3 = 0,1mol
=>%mAl=20,93% =>%mAl2O3 = 79,07%
b) nHCl = 0,1.3+0,1.6=0,9 mol=>mHCl(dd)=100g
mddY=12,9+100-0,15.2=112,6g
mAlCl3=22,5g=>C%=19,98%
\(m_O=\dfrac{15.12,8}{100}=1,92\left(g\right)\)
=> \(n_O=\dfrac{1,92}{16}=0,12\left(mol\right)\)
=> \(n_{H_2O}=0,12\left(mol\right)\)
\(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
Bảo toàn H: nHCl = 0,12.2 + 0,15.2 = 0,54 (mol)
=> nCl = 0,54 (mol)
mmuối = mhh rắn - mO + mCl
= 15 - 1,92 + 0,54.35,5 = 32,25 (g)
1)
a)
$CaO + 2HCl \to CaCl_2 + H_2O$
$CaCO_3 + 2HCl \to CaCl_2 + CO_2 + H_2O$
$n_{CaCO_3} = n_{CO_2} = 0,2(mol)$
$n_{CaCl_2} = 0,3(mol)$
Suy ra:
$n_{CaO} = 0,3 - 0,2 = 0,1(mol)$
$\%m_{CaO} = \dfrac{0,1.56}{0,1.56 + 0,2.100}.100\% = 21,875\%$
$\%m_{CaCO_3} = 78,125\%$
b)
$m_{dd} = 0,1.56 + 0,2.100 + 50 - 0,2.44 = 66,8(gam)$
$C\%_{CaCl_2} = \dfrac{33,3}{66,8}.100\% = 49,85\%$
Câu 4 :
a)
Gọi $n_{Fe} = a(mol) ; n_{MgO} = b(mol)$
Suy ra: $56a + 40b = 19,2(1)$
$Fe + 2HCl \to FeCl_2 + H_2$
$MgO + 2HCl \to MgCl_2 + H_2O$
Theo PTHH : $n_{HCl} = 2a + 2b = 0,4.2 = 0,8(2)$
Từ (1)(2) suy ra a = b = 0,2
$\%m_{Fe} = \dfrac{0,2.56}{19,2}.100\% = 58,33\%$
$\%m_{MgO} = 100\% -58,33\% = 41,67\%$
b)
$n_{FeCl_2} = a = 0,2(mol)$
$n_{MgCl_2} = b = 0,2(mol)$
$m_{muối} = 0,2.127 + 0,2.95 = 44,4(gam)$
Ta có: \(\left\{{}\begin{matrix}n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\n_{CaCl_2}=\dfrac{33,3}{111}=0,3\left(mol\right)\end{matrix}\right.\)
PTHH: \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2\uparrow+H_2O\)
0,2_____0,4_____0,2____0,2_____0,2 (mol)
\(CaO+2HCl\rightarrow CaCl_2+H_2O\)
0,1_____0,2_____0,1____0,1 (mol)
Ta có: \(\left\{{}\begin{matrix}m_{CaO}=0,1\cdot56=5,6\left(g\right)\\m_{CaCO_3}=0,2\cdot100=20\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{CaO}=\dfrac{5,6}{5,6+20}\cdot100\%=21,875\%\\\%m_{CaCO_3}=78,125\%\end{matrix}\right.\)
Mặt khác: \(m_{CO_2}=0,2\cdot44=8,8\left(g\right)\)
\(\Rightarrow m_{dd\left(sau.p/ứ\right)}=m_{CaO}+m_{CaCO_3}+m_{ddHCl}-m_{CO_2}=66,8\left(g\right)\)
\(\Rightarrow C\%_{CaCl_2}=\dfrac{33,3}{66,8}\cdot100\%\approx49,85\%\)
nCO2=\(\dfrac{4,48}{22,4}=0,2\) mol
nCaCl2=\(\dfrac{33,3}{111}=0,3\)
CaCO2 + 2HCl → CaCl2 + CO2 + H2O
0,2 ← 0,2 ← 0,2
CaO + 2HCl → CaCl2 + H2O
0,1 ← 0,1
a) % CaO=\(\dfrac{0,1.56}{0,1.56+0,2.100}.100\%=21,875\%\)
% CaCO3 =100% - 21,875%= 78,125%
b) a = mCaO+mCaCO3 =0,1.56+0,2.100=25,6g
mdd sau pư= a + mddHCl - mCO2
= 25,6 + 50 - 0,2.44=66,8g
C%CaCl2=\(\dfrac{33,3}{66,8}.100\%\simeq49,85\%\)
1) Ptpư:
2Al + 6HCl \(\rightarrow\) 2AlCl3 + 3H2
Fe + 2HCl \(\rightarrow\) FeCl2 + H2
Cu + HCl \(\rightarrow\) không phản ứng
=> 0,6 gam chất rắn còn lại chính là Cu:
Gọi x, y lần lượt là số mol Al, Fe
Ta có:
3x + 2y = 2.0,06 = 0,12
27x + 56 y = 2,25 – 0,6 = 1,65
=> x = 0,03 (mol) ; y = 0,015 (mol)
=> \(\%Cu=\frac{0,6}{2,25}.100\%=26,67\%\); \(\%Fe=\frac{56.0,015}{2,25}.100\%=37,33\%\); %Al = 36%
2) \(n_{SO_2}=\frac{1,344}{22,4}=0,06mol\); m (dd KOH) = 13,95.1,147 = 16 (gam)
=> mKOH = 0,28.16 = 4,48 (gam)=> nKOH = 0,08 (mol)=> \(1<\)\(\frac{n_{KOH}}{n_{SO_2}}<2\)
=> tạo ra hỗn hợp 2 muối: KHSO3: 0,04 (mol) và K2SO3: 0,02 (mol)
Khối lượng dung dịch sau pu = 16 + 0,06.64 = 19,84 gam
=> \(C\%\left(KHSO_3\right)=\frac{0,04.120}{19,84}.100\%\)\(=24,19\%\)
\(C\%\left(K_2SO_3\right)=\frac{0,02.158}{19,84}.100\%\)\(=15,93\%\)
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)
Ta có: \(\left\{{}\begin{matrix}\Sigma n_{HCl}=0,4\cdot2=0,8\left(mol\right)\\n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}n_{Mg}=0,1mol\\n_{Al_2O_3}=0,1mol\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Al_2O_3}=0,1\cdot102=10,2\left(g\right)\\m_{Mg}=0,1\cdot24=2,4\left(g\right)\end{matrix}\right.\)
\(\Rightarrow m_{hh}=10,2+2,4=12,6\left(g\right)\)
Theo PTHH: \(\left\{{}\begin{matrix}n_{MgCl_2}=n_{Mg}=0,1mol\\n_{AlCl_3}=2n_{Al_2O_3}=0,2mol\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{MgCl_2}=0,1\cdot95=9,5\left(g\right)\\m_{AlCl_3}=0,2\cdot133,5=26,7\left(g\right)\end{matrix}\right.\)
Mặt khác: \(\left\{{}\begin{matrix}m_{ddHCl}=400\cdot1,2=480\left(g\right)\\m_{H_2}=0,1\cdot2=0,2\left(g\right)\end{matrix}\right.\)
\(\Rightarrow m_{dd}=m_{hh}+m_{ddHCl}-m_{H_2}=492,4\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{MgCl_2}=\dfrac{9,5}{492,4}\cdot100\%\approx1,93\%\\C\%_{AlCl_3}=\dfrac{26,7}{492,4}\cdot100\%\approx5,42\%\end{matrix}\right.\)