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PTHH: \(Na_2SO_4+CaCl_2\rightarrow2NaCl+CaSO_4\downarrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Na_2SO_4}=0,1\cdot0,5=0,05\left(mol\right)\\n_{CaCl_2}=0,1\cdot0,4=0,04\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Na2SO4 dư
\(\Rightarrow\left\{{}\begin{matrix}n_{CaSO_4}=0,04\left(mol\right)\\n_{NaCl}=0,08\left(mol\right)\\n_{Na_2SO_4\left(dư\right)}=0,01\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{CaSO_4}=0,04\cdot136=5,44\left(g\right)\\C_{M_{NaCl}}=\dfrac{0,08}{0,1+0,1}=0,4\left(M\right)\\C_{M_{Na_2SO_4\left(dư\right)}}=\dfrac{0,01}{0,2}=0,05\left(M\right)\end{matrix}\right.\)
\(n_{CuSO_4}=0.2\cdot0.5=0.1\left(mol\right)\)
\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
\(0.1.............0.2.................0.1..........0.1\)
\(C_{M_{Na_2SO_4}}=\dfrac{0.1}{0.3+0.2}=0.2\left(M\right)\)
\(Cu\left(OH\right)_2\underrightarrow{^{^{t^0}}}CuO+H_2O\)
\(0.1.............0.1\)
\(m_{CuO}=0.1\cdot80=8\left(g\right)\)
a/
\(n_{Na_2O}=\dfrac{9,3}{62}=0,15\left(mol\right)\)
\(Na_2O+H_2O\rightarrow2NaOH\)
0,15 0,3 (mol)
\(m_{NaOH}=0,3.40=12\left(g\right)\)
\(m_A=90,7+9,3=100\left(g\right)\)
\(C\%_{NaOH}=\dfrac{12}{100}.100\%=12\%\)
b/
m\(_{FeSO_4}=\dfrac{16.200}{100}=32\left(g\right)\)
\(\rightarrow m_{FeSO_4}=\dfrac{32}{152}=\dfrac{4}{19}\left(mol\right)\)
\(2NaOH+FeSO_4\rightarrow Na_2SO_4+Fe\left(OH\right)_2\downarrow\)
bđ: 0,3 \(\dfrac{4}{19}\) 0 0 (mol)
pư: 0,3 0,15 0,15 0,15 (mol)
dư: 0 \(\dfrac{23}{380}\) (mol)
\(m_{Fe\left(OH\right)_2}=0,15.90=13,5\left(g\right)\)
\(m_C=100+200-13,5=286,5\left(g\right)\)
\(m_{Na_2SO_4}=0,15.142=21,3\left(g\right)\)
\(\rightarrow C\%_{Na_2SO_4}=\dfrac{21,3}{286,5}.100\%\approx7,4\%\)
\(m_{FeSO_4\left(dư\right)}=\dfrac{23}{380}.152=9,2\left(g\right)\)
\(\rightarrow C\%_{FeSO_4\left(dư\right)}=\dfrac{9,2}{286,5}.100\%\approx3,2\%\)
Dung dịch A chứa CO32- (x mol) và HCO3- (y mol)
CO32- + H+ —> HCO3-
x…………x………….x
HCO3- + H+ —> CO2 + H2O
x+y…….0,15-x
Dung dịch B tạo kết tủa với Ba(OH)2 nên HCO3- dư, vậy nCO2 = 0,15 – x = 0,045 —> x = 0,105
HCO3- + OH- + Ba2+ —> BaCO3 + H2O
—> nBaCO3 = (x + y) – (0,15 – x) = 0,15 —> y = 0,09
—> a = 20,13 gam
a)Đổi \(V_{H_2SO_4}=100ml=0,1l\)
Số mol của 2,7 gam Al:
\(n_{Al}=\dfrac{m}{M}=\dfrac{2,7}{27}=0,1\left(mol\right)\)
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)3+3H_2\)
Tỉ lệ 2 : 3 : 1 : 3
0,1 -> 0,15 : 0,05 : 0,15(mol)
Nồng độ mol của dung dịch H2SO4:
\(C_{M_{H_2SO_4}}=\dfrac{n_{H_2SO_4}}{V_{H_2SO_4}}=\dfrac{0,15}{0,1}=1,5\left(M\right)\)
b) thể tích của 0,15 mol H2:
\(V_{H_2}=n.22,4=0,15.22,4=3,36\left(l\right)\)
c) nồng độ mol của dd \(Al_2\left(SO_4\right)_3\) :
\(C_{M_{Al_2\left(SO_4\right)_3}}=\dfrac{n}{V}=\dfrac{0,05}{0,1}=0,5\left(M\right)\)
a)\(Na2SO4+BaCl2--.>BaSO4+2NaCl\)
\(m_{Na2SO4}=\frac{17,75.8}{100}=1,42\left(g\right)\)
\(n_{Na2SO4}=\frac{1,42}{142}=0,01\left(mol\right)\)
\(n_{BaCl2}=\frac{31,2.10}{100}=3,12\left(g\right)\)
\(n_{BaCl2}=\frac{3,12}{208}=0,015\left(mol\right)\)
=> BaCl2 dư
dd sau pư là BaCl2 dư và NaCl
\(n_{BaCl2}dư=0,05\left(mol\right)\)
\(m_{BaCl2}=0,005.208=1,04\left(g\right)\)
\(m_{ddBaCl2}dư=\frac{1,04.100}{10}=10,4\left(g\right)\)
\(d_{BaCl2}=\frac{10,4}{40}=0,26\left(\frac{g}{ml}\right)\)
b) \(C_{M\left(BaCk2\right)}=\frac{0,005}{0,04}=0,125\left(M\right)\)
\(n_{NaCl}=2n_{Na2SO4}=0,02\left(mol\right)\)
\(C_{M\left(NaCl\right)}=\frac{0,02}{0,04}=0,5\left(M\right)\)
\(n_{NaOH}=0.2\cdot0.5=0.1\left(mol\right)\)
\(n_{CuSO_4}=0.1\cdot2=0.2\left(mol\right)\)
\(2NaOH+CuSO_4\rightarrow Na_2SO_4+Cu\left(OH\right)_2\)
\(0.1.............0.05...............0.05...........0.05\)
\(m_{Cu\left(OH\right)_2}=0.05\cdot98=4.9\left(g\right)\)
\(C_{M_{Na_2SO_4}}=\dfrac{0.05}{0.2+0.1}=0.167\left(M\right)\)
\(C_{M_{CuSO_4\left(dư\right)}}=\dfrac{0.2-0.05}{0.1}=1.5\left(M\right)\)
\(n_{CaCl_2}=0,1.1,5=0,15\left(mol\right)\)
\(PTHH:Na_2CO_3+CaCl_2\rightarrow2NaCl+CaCO_3\)
(mol)_____0,15_________0,15_____0,3_______0,15
\(m_{\downarrow\left(CaCO_3\right)}=100.0,15=15\left(g\right)\)
\(C_{M_{Na_2CO_3}}=\frac{0,15}{0,05}=3\left(M\right)\)
\(C_{M_B}=\frac{0,3}{0,15}=2\left(M\right)\)
Xuan Xuannajimex cả bài đó e, tại a k ghi a,b,c thôi