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Ta có: \(n_{NaOH}=\dfrac{12}{40}=0,3\left(mol\right)\)
PT: \(2NaOH+CuCl_2\rightarrow2NaCl+Cu\left(OH\right)_{2\downarrow}\)
_____0,3_______________________0,15 (mol)
\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
0,15_______0,15 (mol)
⇒ m = mCuO = 0,15.80 = 12 (g)
Bạn tham khảo nhé!
MgCl2 + 2NaOH -> 2NaCl + Mg(OH)2 (1)
Mg(OH)2 -> MgO + H2O (2)
nMgCl2=0,2.0,15=0,03(mol)
nNaOH=0,2.0,2=0,04(mol)
Vì \(\dfrac{0,04}{2}< 0,03\) nên MgCl2 dư 0,1 mol
Theo PTHH 1 ta có:
nMg(OH)2=\(\dfrac{1}{2}\)nNaOH=0,02(mol)
nNaCl=nNaOH=0,04(mol)
Theo PTHH 2 ta có:
nMgO=nMg(OH)2=0,02(mol)
mMgO=40.0,02=0,8(g)
CM dd MgCl2=\(\dfrac{0,01}{0,4}=0,025M\)
CM dd NaCl=\(\dfrac{0,04}{0,4}=0,01M\)
a, \(MgCl_2+2NaOH\rightarrow Mg\left(OH\right)_2+2NaCl\)
\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)
b, \(n_{MgCl_2}=0,2.0,25=0,05\left(mol\right)\)
Theo PT: \(n_{MgO}=n_{Mg\left(OH\right)_2}=n_{MgCl_2}=0,05\left(mol\right)\)
\(\Rightarrow m_{MgO}=0,05.40=2\left(g\right)\)
c, \(n_{NaOH}=2n_{MgCl_2}=0,1\left(mol\right)\)
\(\Rightarrow m_{ddNaOH}=\dfrac{0,1.40}{15\%}=\dfrac{80}{3}\left(g\right)\)
\(a,PTHH:3NaOH+FeCl_3\rightarrow3NaCl+Fe\left(OH\right)_3\downarrow\\ 2Fe\left(OH\right)_3\rightarrow^{t^o}Fe_2O_3+3H_2O\uparrow\\ b,n_{FeCl_3}=1,5\cdot0,2=0,3\left(mol\right)\\ \Rightarrow n_{NaOH}=3n_{FeCl_3}=0,9\left(mol\right)\\ \Rightarrow V_{dd_{NaOH}}=\dfrac{0,9}{2}=0,45\left(l\right)\)
Theo đề: \(\left\{{}\begin{matrix}X:Fe\left(OH\right)_3\\A:NaCl\\Y:Fe_2O_3\end{matrix}\right.\)
Theo PT: \(n_{NaCl}=3n_{FeCl_3}=0,9\left(mol\right)\)
\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,9}{0,45+0,2}\approx1,4M\)
\(c,\) Theo PT: \(n_{Fe\left(OH\right)_3}=n_{FeCl_3}=0,3\left(mol\right);n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_X=m_{Fe\left(OH\right)_3}=0,3\cdot107=32,1\left(g\right)\\m_Y=m_{Fe_2O_3}=0,15\cdot160=24\left(g\right)\end{matrix}\right.\)
a, \(CuCl_2+2NaOH\rightarrow2NaCl+Cu\left(OH\right)_2\)
\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
b, \(n_{CuCl_2}=\dfrac{27}{135}=0,2\left(mol\right)\)
Theo PT: \(n_{CuO}=n_{Cu\left(OH\right)_2}=n_{CuCl_2}=0,2\left(mol\right)\)
\(\Rightarrow m_{CuO}=0,2.80=16\left(g\right)\)
c, \(n_{NaOH}=2n_{CuCl_2}=0,4\left(mol\right)\)
\(\Rightarrow C\%_{NaOH}=\dfrac{0,4.40}{200}.100\%=8\%\)
\(n_{AlCl_3}=0.2\cdot1=0.2\left(mol\right)\)
\(n_{NaOH}=0.5V\left(mol\right)\)
\(n_{Al_2O_3}=\dfrac{5.1}{102}=0.05\left(mol\right)\)
\(2Al\left(OH\right)_3\underrightarrow{^{^{t^0}}}Al_2O_3+3H_2O\)
\(0.1...............0.05\)
TH1 : Al(OH)3 không bị hòa tan.
\(AlCl_3+3NaOH\rightarrow Al\left(OH\right)_3+3NaCl\)
\(0.1...........0.3................0.1\)
\(\Leftrightarrow V=\dfrac{0.3}{0.5}=0.6\left(l\right)\)
TH2 : Al(OH)3 bị hòa tan một phần
\(AlCl_3+3NaOH\rightarrow Al\left(OH\right)_3+3NaCl\)
\(0.2...........0.6................0.2\)
\(NaOH+Al\left(OH\right)_3\rightarrow NaAlO_2+2H_2O\)
\(0.5V-0.6...0.5V-0.6\)
\(n_{Al\left(OH\right)_3}=0.2+0.5V-0.6=0.1\left(mol\right)\)
\(\Rightarrow V=1\left(l\right)\)