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PTHH: \(Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\uparrow\)
\(Na_2O+H_2O\rightarrow2NaOH\)
Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\) \(\Rightarrow n_{Na}=0,6\left(mol\right)\)
\(\Rightarrow\%m_{Na}=\dfrac{0,6\cdot23}{26,2}\cdot100\%\approx52,67\left(g\right)\) \(\Rightarrow\%m_{Na_2O}=47,33\%\)
Mặt khác: \(n_{Na_2O}=\dfrac{26,2-0,6\cdot23}{62}=0,2\left(mol\right)\)
Theo PTHH: \(n_{NaOH}=n_{Na}+2n_{Na_2O}=1\left(mol\right)\) \(\Rightarrow m_{NaOH}=1\cdot40=40\left(g\right)\)
2Na + 2H2O ---> 2NaOH + H2 (1)
Na2O + H2O ---> 2NaOH (2)
a) nH2 = 0,3 (mol)
Theo pthh (1) : nNa = 2nH2 = 0,6 (mol)
=> mNa = 0,6.23 = 13,8 (g)
=> mNa2O = 26,2 - 13,8 = 12,4 (g)
=> nNa2O = 0,2 (mol)
BTNa : nNaOH = nNa + 2nNa2O = 0,6 + 2.0,2 = 1 (mol)
=> mNaOH = 1.40 = 40(g)
b) %mNa = 13,8.100%/26,2 = 52,67%
%mNa2O = 100% - 52,67% = 47,33%
\(2Na+2H_2O\rightarrow2NaOH+H_2\\ Na_2O+H_2O\rightarrow2NaOH\\ n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{Na}=2.0,3=0,6\left(mol\right)\\ a,m_{Na}=0,6.23=13,8\left(g\right)\\ m_{Na_2O}=26,2-13,8=12,4\left(g\right)\\b, n_{Na_2O}=\dfrac{12,4}{62}=0,2\left(mol\right)\\ n_{NaOH\left(tổng\right)}=n_{Na}+2.n_{Na_2O}=0,6+\dfrac{12,4}{62}=0,8\left(mol\right)\\ m_{c.tan}=m_{NaOH}=0,8.40=32\left(g\right)\\ c,m_{ddNaOH}=m_{hh}+m_{H_2O}-m_{H_2}=26,2+200-0,3.2=225,6\left(g\right)\\ C\%_{ddNaOH}=\dfrac{32}{225,6}.100\approx14,185\%\)
\(a,n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH: Ba + 2H2O ---> Ba(OH)2 + H2
0,3<-------------0,3<---------0,3
=> mBa = 0,3.137 = 41,1 (g)
=> mK2O = 59,9 - 41,1 = 18,8 (g)
\(\rightarrow\left\{{}\begin{matrix}\%m_{Ba}=\dfrac{41,1}{59,9}.100\%=68,61\%\\\%m_{K_2O}=100\%-68,61\%=31,39\%\end{matrix}\right.\)
\(b,n_{K_2O}=\dfrac{18,8}{94}=0,2\left(mol\right)\)
PTHH: K2O + H2O ---> 2KOH
0,2----------------->0,4
Các chất tan trong dd sau phản ứng: KOH, Ba(OH)2
\(\rightarrow\left\{{}\begin{matrix}m_{KOH}=0,4.56=22,4\left(g\right)\\m_{Ba\left(OH\right)_2}=0,3.171=51,3\left(g\right)\end{matrix}\right.\)
Bài 2 :
\(n_{Fe_3O_4} = \dfrac{52,2}{232} = 0,225(mol)\\ Fe_3O_4 + 8HCl \to 2FeCl_3 + FeCl_2 + 4H_2O\\ n_{FeCl_2} = n_{Fe_3O_4} = 0,225(mol) \Rightarrow m_{FeCl_2} = 0,225.127 = 28,575(gam)\\ n_{FeCl_3} = 2n_{Fe_3O_4} = 0,45(mol) \Rightarrow m_{FeCl_3} = 0,45.162,5 = 73,125(gam)\)
Bài 3 :
\(n_{Fe} = \dfrac{16,8}{56} = 0,3(mol)\\ 3Fe + 2O_2 \xrightarrow{t^o} Fe_3O_4\\ n_{Fe_3O_4} = \dfrac{1}{3}n_{Fe} = 0,1(mol)\\ Fe_3O_4 + 4H_2SO_4 \to Fe_2(SO_4)_3 + FeSO_4 + 4H_2O\\ n_{FeSO_4} = n_{Fe_2(SO_4)_3} = n_{Fe_3O_4} = 0,1(mol)\\ \Rightarrow m_{FeSO_4} = 0,1.152 = 15,2(gam)\\ m_{Fe_2(SO_4)_3} = 0,1.400 = 40(gam)\)
a) nH2=0,05(mol)
Na + H2O -> NaOH + 1/2 H2
0,1_______________0,05(mol)
Na2O + H2O -> 2 NaOH
b) => mNa=0,1.23=2,3(g)
=>nNa2O= 14,7 - 2,3= 12,4(g)
a)\(n_{H_2}=\dfrac{2,24}{22,4}=0,1mol\)
\(2Na+2H_2O\rightarrow2NaOH+H_2\)
0,2 0,1
\(NaO+H_2O\rightarrow2NaOH\)
b)\(m_{Na}=0,2\cdot23=4,6g\)
\(m_{NaO}=m_{hh}-m_{Na}=40,5-4,6=35,9g\)
c)\(n_{NaO}=\dfrac{35,9}{39}=0,92mol\Rightarrow n_{NaOH}=2n_{NaO}=1,84mol\)
\(\Rightarrow m_{NaOH}=1,84\cdot40=73,6g\)
a) PTHH : \(FeO+H_2-t^o->Fe+H_2O\)
\(CuO+H_2-t^o->Cu+H_2O\)
Đặt \(\hept{\begin{cases}n_{FeO}=x\left(mol\right)\\n_{CuO}=y\left(mol\right)\end{cases}}\) => \(72x+80y=11,2\left(I\right)\)
Có : \(m_{O\left(lấy.đi\right)}=m_{giảm}=1,92\left(g\right)\)
=> \(n_{O\left(lấy.đi\right)}=\frac{1,92}{16}=0,12\left(mol\right)\) Vì H% = 80% => Thực tế : \(n_{O\left(hh\right)}=\frac{0,12}{80}\cdot100=0,15\left(mol\right)\)
BT Oxi : \(x+y=0,15\left(II\right)\)
Từ (I) và (II) suy ra : \(\hept{\begin{cases}x=0,1\\y=0,05\end{cases}}\)
=> \(\hept{\begin{cases}m_{FeO}=7,2\left(g\right)\\m_{CuO}=4\left(g\right)\end{cases}}\)
b) PTHH : \(Fe+H_2SO_4-->FeSO_4+H_2\)
BT Fe : \(n_{Fe}=n_{FeO}=0,1\left(mol\right)\)
Theo pthh : \(n_{H_2}=n_{Fe}=0,1\left(mol\right)\)
=> \(V_{H_2}=2,24\left(l\right)\)
BT Cu : \(n_{Cu}=n_{CuO}=0,05\left(mol\right)\)
=> \(m_{CR\left(ko.tan\right)}=0,05\cdot64=3,2\left(g\right)\)
goi: x la khoi luong cua Na
y la khoi luong cua Na2O
\(\Rightarrow n_{Na}=\dfrac{x}{23}\left(mol\right)\) va \(n_{Na_2O}=\dfrac{y}{62}\left(mol\right)\)
\(2Na+2H_2O\rightarrow2NaOH+H_2\left(1\right)\)
DE: \(\dfrac{x}{23}\rightarrow\) \(\dfrac{x}{23}\rightarrow\) \(\dfrac{x}{46}\) (mol)
\(Na_2O+H_2O\rightarrow2NaOH\left(2\right)\)
DE: \(\dfrac{y}{62}\rightarrow\) \(\dfrac{2y}{62}\) (mol)
ta co: \(V_{H_2}=22,4.n=\dfrac{x}{46}.22,4=6,72\)
\(\Rightarrow x=\dfrac{6,72.46}{22,4}=13,8\left(g\right)\)
\(\Rightarrow y=26,2-13,8=12,4\left(g\right)\)
A, \(m_{NaOH}=m_{NaOH\left(1\right)}+m_{NaOH\left(2\right)}\)
\(=40.\left(\dfrac{13,8}{23}+\dfrac{12,4.2}{62}\right)=40\left(g\right)\)
B, \(\%m_{Na}=\dfrac{13,8}{26,2}.100\approx52,67\%\)
\(\%m_{Na_2O}=100-52,67=47,33\text{%}\)