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ZnO + H2SO4 = ZnSO4 + H2O
0.1mol:2.32mol
=> H2SO4 dư theo ZnO
=> khối lượng axits tham gia: 0,1.(2+32+16.4)=9.8g
=> khối lượng muối : mZnSO4=0.1(65+32+16.4)=16.1g
nồng độ mol sau pu: CM=\(\frac{0.1}{0.58}\)=\(\frac{5}{29}\)
Gọi nNa2CO3 = x (mol)
Na2CO3 + 2HCl \(\rightarrow\) 2NaCl + H2O + CO2
x \(\rightarrow\) 2x \(\rightarrow\) 2 x (mol)
C%(NaCl) = \(\frac{2.58,5x}{200+120}\) . 100% = 20%
=> x =0,547 (mol)
mNa2CO3 = 0,547 . 106 = 57,982 (g)
mHCl = 2 . 0,547 . 36,5 =39,931 (g)
C%(Na2CO3) =\(\frac{57,892}{200}\) . 100% = 28,946%
C%(HCl) = \(\frac{39,931}{120}\) . 100% = 33,28%
2KOH+ H2SO4 ------> K2SO4+ 2H2O
0.2...........0.1...................0.1.........0.2
nH2SO4=(200.4.9%)/98=0.1 mol
a) VddKOH=\(\dfrac{0.2\cdot56}{1.12}\)=10 ml ( V=m/D)
b)mK2SO4=174*0.1=17.4 g
mddKOH=1.12*10=11.2 g (m=D*V)
c) mdd=200+11.2=211.2 g
=>C%K2SO4=(17.4*100)/211.2=8.24%
PTHH: \(H_2SO_4+2KOH\rightarrow K_2SO+2H_2O\)
Ta có: \(n_{H_2SO_4}=0,2\cdot1=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{KOH}=0,4\left(mol\right)\\n_{K_2SO_4}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{ddKOH}=\dfrac{\dfrac{0,4\cdot56}{6\%}}{1,048}\approx356,2\left(ml\right)\\C_{M_{K_2SO_4}}=\dfrac{0,2}{0,2+0,3562}\approx0,36\left(M\right)\end{matrix}\right.\)
\(n_{H_2SO_4}=1.0,2=0,2\left(mol\right)\\ H_2SO_4+2KOH\rightarrow K_2SO_4+2H_2O\\ 0,2.........0,4........0,2.......0,2\left(mol\right)\\ a.m_{ddKOH}=\dfrac{0,4.56.100}{6}=\dfrac{1120}{3}\left(g\right)\\ V_{ddKOH}=\dfrac{\dfrac{1120}{3}}{1,048}=\dfrac{140000}{393}\left(ml\right)\approx0,356\left(l\right)\)
\(b.C_{MddK_2SO_4}=\dfrac{0,2}{\dfrac{140000}{393}+0,2}\approx0,00056\left(M\right)\)
1)
a dd KOH
MgCl2 + 2KOH --------> Mg(OH)2 + 2KCl
Cu(NO3)2 + 2KOH ------> Cu(OH)2 + 2KNO3
b) AgNO3
2AgNO3 + MgCl2 -------> 2AgCl + Mg(NO3)2
nNa2O=15,5/62=0,25mol
pt : Na2O + H2O ---------> 2NaOH
npứ: 0,25---------------------->0,5
CM(NaOH)=0,5/0,5=1M
pt : 2NaOH + H2SO4 ------> Na2SO4 + 2H2O
npứ:0,5---------->0,25
mH2SO4 = 0,25.98=24,5g
mddH2SO4 =\(\dfrac{24,5.100}{20}=122,5\)
Vdd H2SO4=122,5/1,14\(\approx107,46ml\)
Bài 1:
PTHH: \(BaO+H_2SO_4\rightarrow BaSO_4+H_2O\)
Bđ____0,05___0,2
Pư____0,05___0,05_______0,05
Kt____0______0,15_______0,05
\(m_{kt}=m_{BaSO_4}=0,05.233=11,65\left(g\right)\)
\(m_{ddsaupư}=7,65+200-11,65=196\left(g\right)\)
\(C\%ddH_2SO_4=7,5\%\)
Bài 2: \(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)
bđ___0,1_______0,5
pư__1/12_______0,5_____1/6
kt ___1/60______0_______1/6
\(m_{FeCl_3}=\dfrac{1}{6}.162,5\approx27g\)
\(C_{MddFeCl_3}=\dfrac{1}{6}:0,5\approx0,3M\)
a.250ml=0,25l ; nHCl=0,25.1,5=0,375mol
KOH+HCl->KCl+H2O
1mol 1mol 1mol
0,375 0,375 0,375
VKOh=0,375/2=0,1875l
b.CM KCL=0,375/0,25=1,5M
c.NaOH+HCL=NaCl+H2O
1mol 1mol
0,375 0,375
mdd NaOH=0,375.40.100/10=150g
PTHH: \(Na_2O\) + \(H_2O\) ----->2NAOH
a. \(m_{_{ }ddNaOH}\) = \(m_{H_2O}\) = 187,6g
ACDT: \(m_{ct}\) = \(\frac{m_{dd}.C\%}{100}\) => \(m_{NaOH}\) = \(\frac{187,6.8}{100}\) = 15,008g
b. PTHH: \(NaOH\) + \(HNO_3\) ----> \(NaNO_3\) + \(H_2O\)
ADCT: \(m_{ct}=\frac{m_{dd}.C\%}{100}\) ---> \(m_{HNO_3}\) = \(\frac{187,6.15}{100}\) = 28,14(g)
=> \(n_{HNO_3}\) = \(\frac{28,14}{63}\) = 0,4(mol)
Theo PT: \(n_{NANO_3}\) = \(n_{HNO_3}\) =0,4 (mol)
=> \(m_{NaNO_3}=\) 0,4 x 85 = 34(g)
\(C\%_{NaNO_3}\) = \(\frac{34}{187,6}\)x100% = 18,2%
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\(n_{NaOH}=\frac{15,008}{40}=0,3752\left(mol\right)\)
Theo PT: \(n_{Na_2O}=2n_{NaOH}=2.0,3752=0,7504\left(mol\right)\)
ADCT: m = n.M => \(m_{Na_2O}\) = 0.7504.62 = 46.5248 (g)
Bài 1: \(n_{H_2SO_4}=\frac{9}{49}\left(mol\right)\)
H2SO4 + 2KOH -> K2SO4 + 2H2O
=> nKOH= 2nH2SO4 = \(\frac{18}{49}\left(mol\right)\)
=> Vdd KOH = \(\frac{18}{49}:\frac{2}{1000}=\frac{9000}{49}\left(ml\right)\)
b) nK2SO4 = nH2SO4 = \(\frac{9}{49}\left(mol\right)\)
=> mK2SO4= \(\frac{9}{49}\cdot174=\frac{1566}{49}\left(g\right)\)
mdd KOH = \(\frac{9000}{49}\cdot1,12=\frac{1440}{7}\left(g\right)\)
c) \(\%m_{K_2SO_4}=\frac{1566}{49}:\left(200+\frac{1440}{7}\right)\cdot100\%\approx7,87\%\)
bài 2: nNa2CO3 = 0,05 (mol)
PTHH:
Na2CO3 + 2HCl -> 2NaCl + H2O + CO2
=> nHCl = n NaCl = 2nNa2CO3 = 0,1 (mol)
=> mNaCl= 0,1 . 58,5 = 5,85 (g)
b) nCO2 = nNa2CO3 = 0,05 (mol)
=> mCO2 = 0,05 . 44 = 2,2 (g)
mdd HCl = 0,1 . 36,5 :20% = 18,25 (g)
=> %mNaCl = \(\frac{5,85}{53+18,25-2,2}\approx8,47\%\)