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Có : \(d_{\dfrac{hh}{kk}}=0,3276\)
\(\Rightarrow M_{hh}=9,5004\)
\(\Rightarrow\dfrac{n_{O_2}}{n_{H_2}}=\dfrac{~1}{3}\)
=> %O2 = 25% . %H2 = 75 % .
Giả sử có 1 mol khí Cl2, 2 mol khí O2
a) \(\left\{{}\begin{matrix}\%V_{Cl_2}=\dfrac{1}{1+2}.100\%=33,33\%\\\%V_{O_2}=\dfrac{2}{1+2}.100\%=66,67\%\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%m_{Cl_2}=\dfrac{1.71}{1.71+2.32}.100\%=52,59\%\\\%m_{O_2}=\dfrac{2.32}{1.71+2.32}.100\%=47,41\%\end{matrix}\right.\)
b) \(\overline{M}=\dfrac{1.71+2.32}{1+2}=45\left(g/mol\right)\)
=> \(d_{A/H_2}=\dfrac{45}{2}=22,5\)
c) \(n_A=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
=> mA = 0,3.45 = 13,5 (g)
\(n_{O_2}=\dfrac{89.6}{22.4}=4\left(mol\right)\)
\(n_{H_2O}=3a\left(mol\right)\)
\(n_{CO_2}=a\left(mol\right)\)
\(2H_2+O_2\underrightarrow{^{^{t^0}}}2H_2O\)
\(2CO+O_2\underrightarrow{^{^{t^0}}}2CO_2\)
\(n_{O_2}=1.5a+0.5a=4\left(mol\right)\)
\(\Leftrightarrow a=2\)
\(n_{H_2}=3\left(mol\right),n_{CO}=1\left(mol\right)\)
\(\%V_{H_2}=\dfrac{3}{4}\cdot100\%=75\%\)
\(\%V_{CO}=25\%\)
\(\%m_{H_2}=\dfrac{3\cdot2}{3\cdot2+1\cdot28}\cdot100\%=17.64\%\)
\(\%m_{CO}=100-17.64=82.36\%\)
a) Gọi số mol N2, H2 là a, b (mol)
Có: \(\overline{M}_A=\dfrac{28a+2b}{a+b}=7,5.2=15\left(g/mol\right)\)
=> 13a = 13b
=> a = b
=> \(\left\{{}\begin{matrix}\%m_{N_2}=\dfrac{28a}{28a+2b}.100\%=93,33\%\\\%m_{H_2}=\dfrac{2b}{28a+2b}.100\%=6,67\%\end{matrix}\right.\)
b) Giả sử A chứa 1 mol N2, 1 mol H2
PTHH: N2 + 3H2 --to,p,xt--> 2NH3
Xét tỉ lệ: \(\dfrac{1}{1}>\dfrac{1}{3}\) => Hiệu suất tính theo H2
Gọi số mol H2 phản ứng là 3a
PTHH: N2 + 3H2 --to,p,xt--> 2NH3
Trc pư: 1 1 0
Pư: a<--3a--------------->2a
Sau pư: (1-a) (1-3a) 2a
=> \(\overline{M}_B=\dfrac{\left(1-a\right).28+\left(1-3a\right).2+17.2a}{\left(1-a\right)+\left(1-3a\right)+2a}=9,375.2=18,75\left(g/mol\right)\)
=> a = 0,2
=> \(H\%=\dfrac{0,2.3}{1}.100\%=60\%\)
\(a.\)
\(GS:\)
\(n_{hh}=1\left(mol\right)\)
\(Đặt:n_{N_2}=a\left(mol\right),n_{CO_2}=b\left(mol\right)\)
\(\Rightarrow a+b=1\left(1\right)\)
\(m_A=28a+44b=18\cdot2=36\left(2\right)\)
\(\left(1\right),\left(2\right):\)
\(a=b=0.5\)
\(\%m_{N_2}=\dfrac{0.5\cdot28}{0.5\cdot28+0.5\cdot44}\cdot100\%=38.89\%\)
\(\%m_{CO_2}=61.11\%\)
\(b.\)
\(\dfrac{n_{N_2}}{n_{CO_2}}=\dfrac{0.5}{0.5}=\dfrac{1}{1}\)
\(n_{N_2}=n_{CO_2}=\dfrac{1}{2}\cdot n_A=\dfrac{0.2}{2}=0.1\left(mol\right)\)
\(Đặt:n_{CO_2}=x\left(mol\right)\)
\(\overline{M}=\dfrac{0.1\cdot28+0.1\cdot44+44x}{0.2+x}=20\cdot2=40\left(\dfrac{g}{mol}\right)\)
\(\Rightarrow x=0.2\)
\(m_{CO_2\left(cầnthêm\right)}=0.2\cdot44=8.8\left(g\right)\)
a)
$n_{Cl_2} : n_{O_2} = 1 : 2$
Suy ra :
$\%V_{Cl_2} = \dfrac{1}{1 + 2}.100\% = 33,33\%$
$\%V_{O_2} = \dfrac{2}{1 + 2}.100\% = 66,67\%$
b)
Coi $n_{Cl_2} = 1 (mol) \Rightarrow n_{O_2} = 2(mol)$
$\%m_{Cl_2} = \dfrac{1.71}{1.71 + 2.32}.100\% = 52,59\%$
$\%m_{O_2} = 100\% -52,59\% = 47,41\%$
c)
$M_A = \dfrac{71.1 + 32.2}{1 + 2} = 45(g/mol)$
$d_{A/B} = \dfrac{45}{28} = 1,607$
Chẳng ai giải đc
theo đề ra ta có
dx/kok = \(\dfrac{M_X}{29}\) = 0,3276 => Mx =9,5
gọi x và y lần lượt là số mol của H2 và O2
nx = x + y
mx = 2x + 32y
\(\overline{M}\) = \(\dfrac{2x+32y}{x+y}=9,2\)
x = 22,5 y =77,5