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Gọi x,y lần lượt là số mol của Al, Mg
nH2 = \(\dfrac{6,72}{22,4}\)=0,3mol
Pt: 2Al + 6HCl --> 2AlCl3 + 3H2
......x.........................................1,5x
.....Mg + 2HCl --> MgCl2 + H2
......y......................................y
Ta có hệ pt:
\(\left\{{}\begin{matrix}1,5x+y=0,3\\27x+24y=10,2\end{matrix}\right.\)=> số âm xem lại
\(n_{O_2}=\dfrac{5.6}{22.4}=0.25\left(mol\right)\)
\(n_{H_2}=\dfrac{10.08}{22.4}=0.45\left(mol\right)\)
\(n_{Fe}=a\left(mol\right),n_{Al}=b\left(mol\right)\)
\(3Fe+2O_2\underrightarrow{^{^{t^0}}}Fe_3O_4\)
\(a.......\dfrac{2a}{3}\)
\(4Al+3O_2\underrightarrow{^{^{t^0}}}2Al_2O_3\)
\(b.......\dfrac{3b}{4}\)
\(n_{O_2}=\dfrac{2a}{3}+\dfrac{3b}{4}=0.25\left(mol\right)\left(1\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(n_{H_2}=a+1.5b=0.45\left(mol\right)\left(2\right)\)
\(\left(1\right),\left(2\right):a=0.15,b=0.2\)
\(m_{Fe}=0.15\cdot56=8.4\left(g\right)\)
\(m_{Al}=0.2\cdot27=5.4\left(g\right)\)
\(\%m_{Fe}=\dfrac{8.4}{8.4+5.4}\cdot100\%=60.8\%\)
\(\%m_{Al}=100-60.8=39.2\%\)
\(n_{H_2}=n_{H_2SO_4}=\dfrac{11.2}{22.4}=0.5\left(mol\right)\)
\(BTKL:\)
\(m_{Muối}=17.5+0.5\cdot98-0.5\cdot2=65.5\left(g\right)\)
Fe+H2SO4→FeSO4+H2Fe+H2SO4→FeSO4+H2
2Al+3H2SO4→Al2(SO4)3+3H22Al+3H2SO4→Al2(SO4)3+3H2
Zn+H2SO4→ZnSO4+H2Zn+H2SO4→ZnSO4+H2
nH2=11,222,4=0,5(mol)nH2=11,222,4=0,5(mol)
Theo 3PTHH trên: nH2=nH2SO4=0,5(mol)nH2=nH2SO4=0,5(mol)
a) VddH2SO4=0,50,5=1M
Gọi \(\left\{{}\begin{matrix}n_{Al}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
Theo pt: \(\Rightarrow\left\{{}\begin{matrix}3x+y=0,2\\27x+56y=5,5\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=\dfrac{19}{470}\\y=\dfrac{37}{470}\end{matrix}\right.\)
\(\%m_{Al}=\dfrac{\dfrac{19}{470}\cdot27}{5,5}\cdot100\%=19,84\%\)
\(\%m_{Fe}=100\%-19,84\%=80,16\%\)
b.\(n_{HCl}=\dfrac{m_{HCl}}{M_{HCl}}=\dfrac{29,2}{36,5}=0,8mol\)
Gọi \(\left\{{}\begin{matrix}n_{Al}=x\\n_{Mg}=y\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Al}=27x\\m_{Mg}=24y\end{matrix}\right.\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
x 3x ( mol )
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
y 2y ( mol )
Ta có:
\(\left\{{}\begin{matrix}27x+24y=7,8\\3x+2y=0,8\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Al}=0,2.27=5,4g\\m_{Mg}=0,1.24=2,4g\end{matrix}\right.\)
a, PT: \(2Mg+O_2\underrightarrow{t^o}2MgO\)
\(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
b, Ta có: \(n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Theo ĐLBT KL, có: m oxit = mKL + mO2 = 15,6 + 0,2.32 = 22 (g)
c, Gọi: \(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\n_{Al}=y\left(mol\right)\end{matrix}\right.\) (trong 15,6 g)
⇒ 24x + 27y = 15,6 (1)
Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{Mg}+\dfrac{3}{4}n_{Al}=\dfrac{1}{2}x+\dfrac{3}{4}y=0,2\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=1,4\\y=-\dfrac{2}{3}\end{matrix}\right.\)
Đến đây thì ra số mol âm, bạn xem lại đề nhé.
m gam gì kia bn :) ?