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a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
Gọi: \(\left\{{}\begin{matrix}n_{Zn}=x\left(mol\right)\\n_{Al}=y\left(mol\right)\end{matrix}\right.\) ⇒ 65x + 27y = 17,05 (1)
Ta có: \(n_{H_2}=\dfrac{9,52}{22,4}=0,425\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Zn}+\dfrac{3}{2}n_{Al}=x+\dfrac{3}{2}y=0,425\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Zn}=0,2\left(mol\right)\\n_{Al}=0,15\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Zn}=0,2.65=13\left(g\right)\\m_{Al}=0,15.27=4,05\left(g\right)\end{matrix}\right.\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\\n_{AlCl_3}=n_{Al}=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{ZnCl_2}}=\dfrac{0,2}{0,5}=0,4\left(M\right)\\C_{M_{AlCl_3}}=\dfrac{0,15}{0,5}=0,3\left(M\right)\end{matrix}\right.\)
c, Ta có: m dd HCl = 1,05.500 = 525 (g)
m dd sau pư = mhh + m dd HCl - mH2 = 541,2 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,2.136}{541,2}.100\%\approx5,03\%\\C\%_{AlCl_3}=\dfrac{0,15.133,5}{541,2}.100\%\approx3,7\%\end{matrix}\right.\)
\(n_{HCl}=1\cdot0,2=0,2\left(mol\right)\\ PTHH:MgO+2HCl\rightarrow MgCl_2+H_2O\\ a,n_{MgO}=\dfrac{1}{2}n_{HCl}=0,1\left(mol\right)\\ \Rightarrow m=m_{MgO}=0,1\cdot40=4\left(g\right)\\ b,n_{MgCl_2}=n_{MgO}=0,1\left(mol\right)\\ \Rightarrow m_{MgCl_2}=0,1\cdot95=9,5\left(g\right)\\ c,m_{CT_{HCl}}=0,2\cdot36,5=7,3\left(g\right)\\ \Rightarrow C\%_{HCl}=\dfrac{7,3}{250}\cdot100\%=2,92\%\)
\(n_{H_2O}=n_{MgO}=0,1\left(mol\right)\\ \Rightarrow m_{H_2O}=0,1\cdot18=1,8\left(g\right)\\ \Rightarrow m_{dd_{MgCl_2}}=4+250-1,8=252,2\left(g\right)\\ \Rightarrow C\%_{MgCl_2}=\dfrac{9,5}{252,2}\cdot100\%\approx3,77\%\)
a) Lập công thức hóa học của muối kẽm clorua: Z n C l 2
b) Khối lượng muối Z n C l 2 = 6,5 + 7,3 – 0,2 = 13,6 (gam)
a, \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
PTHH: Mg + 2HCl ---> MgCl2 + H2
0,2-->0,4-------->0,2---->0,2
\(\Rightarrow\left\{{}\begin{matrix}b,V_{H_2}=0,2.22,4=4,48\left(l\right)\\c,V_{ddHCl}=\dfrac{0,4}{2}=0,2\left(l\right)\\d,m_{MgCl_2}=0,2.95=19\left(g\right)\end{matrix}\right.\)
\(n_{Mg}=\dfrac{4,8}{24}=0,2mol\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
0,2 0,4 0,2 0,2 ( mol )
\(V_{H_2}=0,2.22,4=4,48l\)
\(V_{HCl}=\dfrac{0,4}{2}=0,2l\)
\(m_{ZnCl_2}=0,2.95=19g\)
\(n_{HCl}=0,2.2=0,4\left(mol\right)\\ PTHH:Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{Fe}=n_{H_2}=n_{FeCl_2}=\dfrac{0,4}{2}=0,2\left(mol\right)\\ a,m_{Fe}=0,2.56=11,2\left(g\right)\\ b,V_{H_2\left(đktc\right)}=0,2.22,4=4,48\left(l\right)\\ c,V_{ddFeCl_2}=V_{ddHCl}=0,2\left(l\right)\\ C_{MddFeCl_2}=\dfrac{0,2}{0,2}=1\left(M\right)\)
a, \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Theo PT: \(n_{H_2}=n_{Zn}=0,1\left(mol\right)\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, \(n_{ZnCl_2}=n_{Zn}=0,1\left(mol\right)\Rightarrow m_{ZnCl_2}=0,1.136=13,6\left(g\right)\)
c, m dd muối = 13,6 + 172,8 = 186,4 (g)
\(\Rightarrow C\%_{ZnCl_2}=\dfrac{13,6}{186,4}.100\%\approx7,3\%\)
\(pthh:Zn+2HCl--->ZnCl_2+H_2\uparrow\)
a. Ta có: \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
Theo pt: \(n_{H_2}=n_{Zn}=0,1\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,1.22,4=2,24\left(lít\right)\)
b. Theo pt: \(n_{ZnCl_2}=n_{Zn}=0,1\left(mol\right)\)
\(\Rightarrow m_{ZnCl_2}=0,1.136=13,6\left(g\right)\)
c. \(C_{\%_{ZnCl_2}}=\dfrac{m_{ZnCl_2}}{m_{dd_{ZnCl_2}}}.100\%=\dfrac{13,6}{13,6+172,8}.100\%=7,3\%\)
\(a,PTHH:2X+6HCl\to 2XCl_3+3H_2\\ b,n_{H_2}=\dfrac{6,72}{22,4}=0,3(mol)\\ \Rightarrow n_{X}=\dfrac{2}{3}n_{H_2}=0,2(mol)\\ \Rightarrow M_{X}=\dfrac{5,4}{0,2}=27(g/mol)\)
Vậy X là nhôm (Al)
\(c,n_{AlCl_3}=n_{Al}=0,2(mol)\\ \Rightarrow m_{AlCl_3}=0,2.133,5=26,7(g)\)
a)
PTHH: Mg + 2HCl --> MgCl2 + H2
0,075<--0,15--->0,075-->0,075
=> m = 0,075.24 = 1,8 (g)
b) VH2 = 0,075.22,4 = 1,68 (l)
c) mMgCl2 = 0,075.95 = 7,125 (g)
d)
PTHH: 2H2 + O2 --to--> 2H2O
0,075->0,0375
=> VO2 = 0,0375.22,4 = 0,84 (l)
a.b.c.
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
0,075 0,15 0,075 0,075 ( mol )
\(m_{Mg}=0,075.24=1,8g\)
\(V_{H_2}=0,075.22,4=1,68l\)
\(m_{MgCl_2}=0,075.95=7,125g\)
d.\(2H_2+O_2\rightarrow\left(t^o\right)2H_2O\)
0,075 0,0375 ( mol )
\(V_{O_2}=0,0375.22,4=0,84l\)
\(2Al + 6HCl \to 2AlCl_3 + 3H_2\\ n_{AlCl_3} = n_{Al} = \dfrac{4,05}{27}=0,15(mol)\\ m_{AlCl_3} = 0,15.133,5 = 20,025(gam)\)
nAl = 4,05/27=0,15mol
pthh 2Al + 6HCl --> 2AlCl3 + 3H2
0,15 0,15 mol
mAlCl3=0,15*(27+35,5*3)=20.025 g