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nH2= 0,12 mol
Fe + 2HCl = FeCl2 + H2
=> nFe = nH2 = 0,12 mol
=> mFe = 0,12*56 = 6,72 gam
=%Fe = (6,72*100%):10 = 67,2%
=> % Cu = 100% -67,2% = 32,8%
a. B gồm AlCl3
\(b.n_{H_2}=\dfrac{13,44}{22,4}=0,6mol\\ 2Al+6HCl\rightarrow2AlCl_3+3H_2\)
0,4 1,2 0,4 0,6
\(\%m_{Al}=\dfrac{0,4.27}{23,6}\cdot100\%=45,76\%\\ \%m_{Cu}=100\%-45,76=54,24\%\\ c.m_B=m_{AlCl_3}=1,2.133,5=106,2g\)
\(n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
a) \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)
b) \(n_{Fe}=n_{H2}=n_{H2SO4}=0,1\left(mol\right)\Rightarrow m_{Fe}=0,1.56=5,6\left(g\right)\)
\(\Rightarrow m_{Al2O3}=15,8-5,6=10,2\left(g\right)\)
c) Ta có : \(n_{Al2O3}=\dfrac{10,2}{102}=0,1\left(mol\right)\Rightarrow n_{H2SO4}=3n_{Al2O3}=0,3\left(mol\right)\)
\(C_{MddH2SO4}=\dfrac{0,1+0,3}{0,2}=2M\)
PT: \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
a, Giả sử: \(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\n_{Al}=y\left(mol\right)\end{matrix}\right.\)
⇒ 24x + 27y = 12,6 (1)
Ta có: \(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Mg}+\dfrac{3}{2}n_{Al}=x+\dfrac{3}{2}y\left(mol\right)\)
\(\Rightarrow x+\dfrac{3}{2}y=0,6\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,3\left(mol\right)\\y=0,2\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{MG}=\dfrac{0,3.24}{12,6}.100\%\approx57,1\%\\\%m_{Al}\approx42,9\%\end{matrix}\right.\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{H_2SO_4}=n_{H_2}=0,6\left(mol\right)\\n_{MgSO_4}=n_{Mg}=0,3\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow m_{H_2SO_4}=0,6.98=58,8\left(g\right)\Rightarrow m_{ddH_2SO_4}=\dfrac{58,8}{14,7\%}=400\left(g\right)\)
Ta có: m dd sau pư = 12,6 + 400 - 0,6.2 = 411,4 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{MgSO_4}=\dfrac{0,3.120}{411,4}.100\%\approx8,75\%\\C\%_{Al_2\left(SO_4\right)_3}=\dfrac{0,1.342}{411,4}.100\%\approx8,31\%\end{matrix}\right.\)
Bạn tham khảo nhé!
Sửa đề: 3,785 (l) → 3,7185 (l)
a, \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)
b, Ta có: \(n_{H_2}=\dfrac{3,7185}{24,79}=0,15\left(mol\right)\)
Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,1.27}{40}.100\%=6,75\%\\\%m_{Al_2O_3}=93,25\%\end{matrix}\right.\)
c, \(n_{Al_2O_3}=\dfrac{40.93,25\%}{102}=\dfrac{373}{1020}\left(mol\right)\)
Theo PT: \(n_{HCl}=3n_{Al}+6n_{Al_2O_3}=\dfrac{212}{85}\left(mol\right)\)
\(\Rightarrow V_{HCl}=\dfrac{\dfrac{212}{85}}{2}=\dfrac{106}{85}\left(l\right)\approx1247,06\left(ml\right)\)
d, \(n_{AlCl_3}=n_{Al}+2n_{Al_2O_3}=\dfrac{212}{255}\left(mol\right)\)
\(\Rightarrow m_{AlCl_3}=\dfrac{212}{255}.133,5=\dfrac{9434}{85}\left(g\right)\)
e, \(C_{M_{AlCl_3}}=\dfrac{\dfrac{212}{255}}{\dfrac{106}{85}}=\dfrac{2}{3}\left(M\right)\)
a)
$2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$
$n_{H_2} = \dfrac{13,44}{22,4} = 0,6(mol)$
Theo PTHH :
$n_{Al} = \dfrac{2}{3}n_{H_2} = 0,4(mol)$
$m_{Al} = 0,4.27 = 10,8(gam)$
$m_{Cu} = 20,4 - 10,8 = 9,6(gam)$
b) $n_{H_2SO_4} = n_{H_2} = 0,6(mol)$
$m = \dfrac{0,6.98}{14,7\%} = 400(gam)$