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\(a,n_{Na_2SO_4}=0,2\cdot0,2=0,04\left(mol\right);n_{Ba\left(OH\right)_2}=0,2\cdot0,1=0,02\left(mol\right)\\ PTHH:Na_2SO_4+Ba\left(OH\right)_2\rightarrow2NaOH+BaSO_4\downarrow\\ TL:....1.....1......2......1\left(mol\right)\\ BR:.......0,02.....0,02......0,04......0,02\left(mol\right)\)
Vì \(\dfrac{n_{Na_2SO_4}}{1}>\dfrac{n_{Ba\left(OH\right)_2}}{1}\) nên \(Na_2SO_4\) dư, \(Ba\left(OH\right)_2\) hết
\(b,C_{M_{NaOH}}=\dfrac{0,04}{0,2+0,2}=0,1M\)
a, \(CuCl_2+2NaOH\rightarrow2NaCl+Cu\left(OH\right)_2\)
b, \(n_{NaOH}=\dfrac{10}{40}=0,25\left(mol\right)\)
Theo PT: \(n_{CuCl_2}=n_{Cu\left(OH\right)_2}=\dfrac{1}{2}n_{NaOH}=0,125\left(mol\right)\)
\(\Rightarrow m_{Cu\left(OH\right)_2}=0,125.98=12,25\left(g\right)\)
c, \(C_{M_{CuCl_2}}=\dfrac{0,125}{0,1}=1,25\left(M\right)\)
\(n_{NaOH}=\dfrac{10}{40}=0,25\left(mol\right)\)
PTHH:
\(CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\)
0,125 0,25 0,125 0,25
\(m_{Cu\left(OH\right)_2}=0,125.98=12,25\left(g\right)\)
\(C_{M\left(CuCl_2\right)}=\dfrac{0,125}{0,1}=1,25\left(M\right)\)
\(a,2NaOH+MgSO_4\rightarrow Mg\left(OH\right)_2+Na_2SO_4\\ n_{NaOH}=0,5.1=0,5\left(mol\right)\\ b,n_{Mg\left(OH\right)_2}=\dfrac{0,5}{2}=0,25\left(mol\right)=n_{Na_2SO_4}\\ m_{kt}=m_{Mg\left(OH\right)_2}=58.0,25=14,5\left(g\right)\\ c,V_{ddX}=V_{ddNaOH}+V_{ddMgSO_4}=0,5+0,5=1\left(l\right)\\ C_{MddNa_2SO_4}=\dfrac{0,25}{1}=0,25\left(M\right)\)
a/ \(n_{KOH}=0,2.1=0,2\left(mol\right);n_{H_2SO_4}=0,3.1=0,3\left(mol\right)\)
PTHH: 2KOH + H2SO4 → K2SO4 + 2H2O
Mol: 0,2 0,1 0,1
Ta có: \(\dfrac{0,2}{2}< \dfrac{0,3}{1}\) ⇒ KOH hết, H2SO4 dư
b/ \(m_{H_2SO_4dư}=\left(0,3-0,1\right).98=19,6\left(g\right)\)
c/ Vdd sau pứ = 0,2 + 0,3 = 0,5 (l)
d/ \(C_{M_{ddK_2SO_4}}=\dfrac{0,1}{0,5}=0,2M\)
\(C_{M_{ddH_2SO_4dư}}=\dfrac{0,3-0,1}{0,5}=0,4M\)
300ml = 0,3l
\(n_{HNO3}=1.0,3=0,3\left(mol\right)\)
Pt : \(NaOH+HNO_3\rightarrow NaNO_3+H_2O|\)
1 1 1 1
0,3 0,3 0,3
\(n_{NaOH}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)
200ml = 0,2l
\(C_{M_{NaOH}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\)
\(n_{NaNO3}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)
⇒ \(m_{NaNO3}=0,3.85=25,5\left(g\right)\)
Sau phản ứng :
\(V_{dd}=0,2+0,3=0,5\left(l\right)\)
\(C_{M_{NaNO3}}=\dfrac{0,3}{0,5}=0,6\left(M\right)\)
Chúc bạn học tốt
\(n_{HNO_3}=0,3\left(mol\right)\)
\(NaOH+HNO_3\rightarrow NaNO_3+H_2O\)
Theo PT: \(n_{NaOH}=n_{NaNO_3}=n_{HNO_3}=0,3\left(mol\right)\)
\(\Rightarrow CM_{NaOH}=\dfrac{0,3}{0,2}=1,5M\)
\(m_{NaNO_3}=0,3.85=25,5\left(g\right)\)
\(n_{Fe_2O_3}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: Fe2O3 + 3H2SO4 --> Fe2(SO4)3 + 3H2O
______0,05------>0,15--------->0,05
=> mH2SO4 = 0,15.98 = 14,7(g)
=> \(C\%\left(H_2SO_4\right)=\dfrac{14,7}{100}.100\%=14,7\%\)
\(C\%\left(Fe_2\left(SO_4\right)_3\right)=\dfrac{0,05.400}{8+100}.100\%=18,52\%\)
PTHH: Fe2(SO4)3 + 6NaOH --> 2Fe(OH)3\(\downarrow\) + 3Na2SO4
________0,05----------------------->0,1
=> mFe(OH)3 = 0,1.107=10,7(g)
Theo đề bài ta có : \(\left\{{}\begin{matrix}nNa2SO4=0,25.0,2=0,05\left(mol\right)\\nBa\left(OH\right)2=0,25.0,1=0,025\left(mol\right)\end{matrix}\right.\)
PTHH :
\(Na2SO4+Ba\left(OH\right)2->2NaOH+B\text{aS}O4\downarrow\)
0,025mol...........0,025mol........0,05mol........0,025mol
Theo PTHH ta có :
nNa2SO4 = \(\dfrac{0,05}{1}mol>nBa\left(OH\right)2=\dfrac{0,025}{1}mol=>nNa2SO4\left(d\text{ư}\right)\) ( tính theo nBa(OH)2 )
Khối lượng kết tủa sau phản ứng là :
mBaSO4 = 0,025.233 = 5,8825(g)
Nồng độ mol của các chất trong dung dịch thu được sau phản ứng \(\left\{{}\begin{matrix}CM_{NaOH}=\dfrac{0,05}{0,25}=0,2\left(M\right)\\CM_{Na2SO4\left(d\text{ư}\right)}=\dfrac{0,05-0,025}{0,25}=0,1\left(M\right)\end{matrix}\right.\)
\(n_{Na_2SO_4}=0,25.0,2=0,05mol\)
\(n_{Ba\left(OH\right)_2}=0,25.0,1=0,025mol\)
Na2SO4+Ba(OH)2\(\rightarrow\)BaSO4+2NaOH
-Tỉ lệ: \(\dfrac{0,05}{1}>\dfrac{0,025}{1}\)Suy ra Na2SO4 dư
Na2SO4+Ba(OH)2\(\rightarrow\)BaSO4+2NaOH
0,025..\(\leftarrow\)0,025\(\rightarrow\)......0,025.....0,05
\(m_{BaSO_4}=0,025.233=5,825gam\)
\(n_{NaOH}=0,05mol\)
\(n_{Na_2SO_4\left(dư\right)}=0,05-0,025=0,025mol\)
\(V_{dd}=0,25+0,25=0,5l\)
\(C_{M_{NaOH}}=\dfrac{n}{v}=\dfrac{0,05}{0,5}=0,1M\)
\(C_{M_{Na_2SO_4}}=\dfrac{n}{v}=\dfrac{0,025}{0,5}=0,05M\)