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\(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\\ n_{O_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ PTHH:4P+5O_2\underrightarrow{t^o}2P_2O_5\\ LTL:\dfrac{0,2}{4}< \dfrac{0,4}{5}\Rightarrow O_2dư\)
\(n_{O_2\left(pư\right)}=\dfrac{5}{4}n_P=\dfrac{5}{4}.0,2=0,25\left(mol\right)\\ n_{O_2\left(dư\right)}=0,4-0,25=0,15\left(mol\right)\)
\(n_{P_2O_5\left(lt\right)}=\dfrac{1}{2}n_P=\dfrac{1}{2}.0,2=0,1\left(mol\right)\\ m_{P_2O_5\left(lt\right)}=0,1.142=14,2\left(g\right)\\ m_{P_2O_5\left(tt\right)}=0,1.142.80\%=11,36\left(g\right)\)
\(n_{Fe}=\dfrac{3,36}{56}=0,06mol\)
\(n_{O_2}=\dfrac{11,2}{22,4}=0,5mol\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
0,06 < 0,5 ( mol )
0,06 0,04 0,02 ( mol )
Chất dư là O2
\(m_{O_2\left(dư\right)}=\left(0,5-0,04\right).32=14,72g\)
\(m_{Fe_3O_4}=0,02.232=4,64g\)
\(a)3Fe+2O_2\rightarrow Fe_3O_4\)
\(3mol\) \(2mol\) \(1mol\)
\(0,3mol\) \(0,2mol\) \(0,1mol\)
\(b)n_{Fe}=\dfrac{m}{M}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
\(n_{O_2}=\dfrac{V}{22,4}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
\(\text{Ta thấy }O_2\text{ dư,}Fe\text{ phản ứng hết}\)
\(c)m_{Fe_3O_4}=n.M=0,1.232=23,2\left(g\right)\)
a, \(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
b, \(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\)
\(n_{O_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,2}{4}< \dfrac{0,4}{5}\), ta được O2 dư.
Theo PT: \(n_{O_2\left(pư\right)}=\dfrac{5}{4}n_P=0,25\left(mol\right)\Rightarrow n_{O_2\left(dư\right)}=0,4-0,25=0,15\left(mol\right)\)
\(\Rightarrow m_{O_2\left(dư\right)}=0,15.32=4,8\left(g\right)\)
c, Theo PT: \(n_{P_2O_5}=\dfrac{1}{2}n_P=0,1\left(mol\right)\Rightarrow m_{P_2O_5}=0,1.142=14,2\left(g\right)\)
d, \(m_{P_2O_5}=14,2.80\%=11,36\left(g\right)\)
\(a,PTHH:4Al+3O_2\underrightarrow{t^o}2Al_2O_3\\ n_{Al}=\dfrac{m}{M}=\dfrac{10,8}{27}=0,4\left(mol\right)\\ Theo.PTHH:n_{Al_2O_3}=\dfrac{1}{2}.n_{Al}=\dfrac{1}{2}.0,4=0,2\left(mol\right)\\ m_{Al_2O_3}=n.M=0,2.102=20,4\left(g\right)\)
\(b,n_{O_2}=\dfrac{V_{\left(đktc\right)}}{22,4}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\\ Lập.tỉ.lệ:\dfrac{n_{Al}}{4}>\dfrac{n_{O_2}}{3}\Rightarrow Al.dư\\ Theo.PTHH:n_{Al\left(pư\right)}=\dfrac{4}{3}.n_{O_2}=\dfrac{4}{3}.0,2\left(mol\right)\\ n_{Al\left(dư\right)}=n_{Al\left(bđ\right)}-n_{Al\left(pư\right)}=0,4-0,2=0,2\left(mol\right)\\ Theo.PTHH:n_{Al_2O_3}=\dfrac{1}{2}.n_{Al}=\dfrac{1}{2}.0,2=0,1\left(mol\right)\\ m_{Al_2O_3}=n.M=0,1=102=10,2\left(g\right)\)
PTHH: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
Ta có: \(\left\{{}\begin{matrix}n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\n_{O_2}=\dfrac{12,8}{32}=0,4\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{3}< \dfrac{0,4}{2}\) \(\Rightarrow\) Oxi còn dư, Fe p/ứ hết
\(\Rightarrow n_{O_2\left(dư\right)}=0,4-\dfrac{2}{15}=\dfrac{4}{15}\left(mol\right)\)
+) Theo PTHH: \(\left\{{}\begin{matrix}n_{O_2}=\dfrac{2}{15}\left(mol\right)\\n_{Fe_3O_4}=\dfrac{1}{15}\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}V_{kk}=\dfrac{2}{15}\cdot22,4\cdot5\approx14,93\left(l\right)\\m_{Fe_3O_4}=\dfrac{1}{15}\cdot232\approx15,47\left(g\right)\end{matrix}\right.\)
a)
\(3Fe + 2O_2 \xrightarrow{t^o} Fe_3O_4\)
b)
Ta có :
\(n_{Fe} = \dfrac{8,4}{56} = 0,15(mol)\\ n_{O_2} = \dfrac{96}{32} = 3(mol)\)
Ta thấy : \(\dfrac{n_{Fe}}{3} = 0,05 < \dfrac{n_{O_2}}{2} = 1,5\) do đó O2 dư.
Theo PTHH :
\(n_{O_2\ pư} = \dfrac{2}{3}n_{Fe} = 0,1(mol)\\ \Rightarrow n_{O_2\ dư} = 3 - 0,1 = 2,9(mol)\\ \Rightarrow m_{O_2\ dư} = 92,8(gam)\)
c)
\(n_{Fe_3O_4} = \dfrac{1}{3}n_{Fe} = 0,05(mol)\\ \Rightarrow m_{Fe_3O_4} = 0,05.232 = 11,6(gam)\)
\(a)PTHH:FeCl_3+2O_2\xrightarrow[]{t^o}Fe_3O_4\)
mol 1 2 1
mol
\(b)\)Số mol \(FeCl_3\) là: \(n_{FeCl_3}=\dfrac{m_{FeCl_3}}{M_{FeCl_3}}=\dfrac{8,4}{162,5}=0,052\left(mol\right)\)
Số mol \(O_2\) là: \(n_{O_2}=\dfrac{m_{O_2}}{M_{O_2}}=\dfrac{96}{32}=3\left(mol\right)\)
Lập tỉ lệ: \(\dfrac{1}{0,052}>\dfrac{2}{3}\Rightarrow FeCl_3dư\)
Số mol \(FeCl_3\) phản ứng là:
Từ PTHH\(\Rightarrow\) \(n_{FeCl_3}=\dfrac{0,052\times3}{3}=0,035\left(mol\right)\)
Số mol \(FeCl_3\) dư là: \(n_{FeCl_3dư}=n_{FeCl_3đầu}-n_{FeCl_3p/ứng}=0,052-0,035=0,018\left(mol\right)\)
Khối lượng \(FeCl_3\) dư là: \(m_{FeCl_3dư}=n_{FeCl_3dư}\times M_{FeCl_3}=0,018\times162,5=2,925\left(g\right)\)
a, PT: \(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
b, Ta có: \(n_{P_2O_5}=\dfrac{7,1}{142}=0,05\left(mol\right)\)
Theo PT: \(n_P=2n_{P_2O_5}=0,1\left(mol\right)\)
\(\Rightarrow m_P=0,1.31=3,1\left(g\right)\)
\(n_{O_2}=\dfrac{5}{2}n_{P_2O_5}=0,125\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,125.22,4=2,8\left(l\right)\)
c, Có: \(V_{O_2\left(dư\right)}=2,8.15\%=0,42\left(l\right)\)
\(\Rightarrow V_{O_2}=2,8+0,42=3,22\left(l\right)\)
nFe = 16.8/56 = 0.3 (mol)
nO2 = 6.72/22.4 = 0.3 (mol)
2Fe + 3O2 -to-> Fe3O4
0.2___0.3________0.1
mFe dư = ( 0.3 - 0.2 ) * 56 = 5.6 (g)
mFe3O4 = 0.1*232 = 23.2 (g)
a)
3Fe+2O2→Fe3O4
b)
nFe=16,8/56=0,3mol
nO2=6,72/22,4=0,3mol
Ta có: 0,3/3<0,3/2=> O2 dư tính theo Fe
nFe3O4=0,3/3=0,1
mFe3O4=0,1.232=23,2g
\(a,n_{Fe}=\dfrac{14}{56}=0,25(mol)\\ n_{O_2}=\dfrac{8,96}{22,4}=0,4(mol)\\ PTHH:3Fe+2O_2\xrightarrow{t^o}Fe_3O_4\\ \text {Vì }\dfrac{n_{Fe}}{3}<\dfrac{n_{O_2}}{2}\text {nên sau phản ứng } O_2\text { dư}\)
\(\text {Theo PT: }n_{O_2}=\dfrac{2}{3}n_{Fe}=0,17(mol)\\ \Rightarrow n_{O_2(dư)}=0,4-0,17\approx0,23(mol)\\ b,n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}\approx0,08(mol)\\ \Rightarrow m_{Fe_3O_4}=0,08.232=18,56(g) \)
nFe=14/56=0,25
nO2=8,96/22,4=0,4
3Fe+2O2----->Fe3O4
0,25/3<0,4/2 =>Fe hết và O2 dư và dư 0,2 mol
mFe3O4=1/12*232=19,3g