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a)
\(3Fe + 2O_2 \xrightarrow{t^o} Fe_3O_4\)
b)
Ta có :
\(n_{Fe} = \dfrac{8,4}{56} = 0,15(mol)\\ n_{O_2} = \dfrac{96}{32} = 3(mol)\)
Ta thấy : \(\dfrac{n_{Fe}}{3} = 0,05 < \dfrac{n_{O_2}}{2} = 1,5\) do đó O2 dư.
Theo PTHH :
\(n_{O_2\ pư} = \dfrac{2}{3}n_{Fe} = 0,1(mol)\\ \Rightarrow n_{O_2\ dư} = 3 - 0,1 = 2,9(mol)\\ \Rightarrow m_{O_2\ dư} = 92,8(gam)\)
c)
\(n_{Fe_3O_4} = \dfrac{1}{3}n_{Fe} = 0,05(mol)\\ \Rightarrow m_{Fe_3O_4} = 0,05.232 = 11,6(gam)\)
\(a)PTHH:FeCl_3+2O_2\xrightarrow[]{t^o}Fe_3O_4\)
mol 1 2 1
mol
\(b)\)Số mol \(FeCl_3\) là: \(n_{FeCl_3}=\dfrac{m_{FeCl_3}}{M_{FeCl_3}}=\dfrac{8,4}{162,5}=0,052\left(mol\right)\)
Số mol \(O_2\) là: \(n_{O_2}=\dfrac{m_{O_2}}{M_{O_2}}=\dfrac{96}{32}=3\left(mol\right)\)
Lập tỉ lệ: \(\dfrac{1}{0,052}>\dfrac{2}{3}\Rightarrow FeCl_3dư\)
Số mol \(FeCl_3\) phản ứng là:
Từ PTHH\(\Rightarrow\) \(n_{FeCl_3}=\dfrac{0,052\times3}{3}=0,035\left(mol\right)\)
Số mol \(FeCl_3\) dư là: \(n_{FeCl_3dư}=n_{FeCl_3đầu}-n_{FeCl_3p/ứng}=0,052-0,035=0,018\left(mol\right)\)
Khối lượng \(FeCl_3\) dư là: \(m_{FeCl_3dư}=n_{FeCl_3dư}\times M_{FeCl_3}=0,018\times162,5=2,925\left(g\right)\)
\(n_{Fe}=\dfrac{16,8}{56}=0,3mol\)
\(n_{O_2}=\dfrac{5,6}{22,4}=0,25mol\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
\(\dfrac{0,3}{3}\) < \(\dfrac{0,25}{2}\) ( mol )
0,3 0,2 0,1 ( mol )
Chất dư là O2
\(m_{O_2\left(dư\right)}=\left(0,25-0,2\right).32=1,6g\)
\(m_{Fe_3O_4}=0,1.232=23,2g\)
nFe = 16.8/56 = 0.3 (mol)
nO2 = 6.72/22.4 = 0.3 (mol)
2Fe + 3O2 -to-> Fe3O4
0.2___0.3________0.1
mFe dư = ( 0.3 - 0.2 ) * 56 = 5.6 (g)
mFe3O4 = 0.1*232 = 23.2 (g)
a)
3Fe+2O2→Fe3O4
b)
nFe=16,8/56=0,3mol
nO2=6,72/22,4=0,3mol
Ta có: 0,3/3<0,3/2=> O2 dư tính theo Fe
nFe3O4=0,3/3=0,1
mFe3O4=0,1.232=23,2g
PTHH: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
Ta có: \(\left\{{}\begin{matrix}n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\n_{O_2}=\dfrac{12,8}{32}=0,4\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{3}< \dfrac{0,4}{2}\) \(\Rightarrow\) Oxi còn dư, Fe p/ứ hết
\(\Rightarrow n_{O_2\left(dư\right)}=0,4-\dfrac{2}{15}=\dfrac{4}{15}\left(mol\right)\)
+) Theo PTHH: \(\left\{{}\begin{matrix}n_{O_2}=\dfrac{2}{15}\left(mol\right)\\n_{Fe_3O_4}=\dfrac{1}{15}\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}V_{kk}=\dfrac{2}{15}\cdot22,4\cdot5\approx14,93\left(l\right)\\m_{Fe_3O_4}=\dfrac{1}{15}\cdot232\approx15,47\left(g\right)\end{matrix}\right.\)
nFe = 16,8 : 56 = 0,3 (mol)
pthh :3 Fe + 2O2 -t--> Fe3O4
0,3--------------> 0,1 (mol)
=> mFe3O4 =0,1 . 232 = 23,2(G)
nH2 = 44,8 : 22,4 = 2 (g)
pthh : Fe3O4 + H2 -t--> Fe + H2O
LTL : 0,1 / 1 < 2 /1
=> H2 du
nH2 (pu) = nFe3O4 = 0,1 (mol)
=> nH2 (d) = 2-0,1 = 1,9 (mol)
mH2 (d) = 1,9 . 2 = 3,8 (g)
\(a)3Fe+2O_2\rightarrow Fe_3O_4\)
\(3mol\) \(2mol\) \(1mol\)
\(0,3mol\) \(0,2mol\) \(0,1mol\)
\(b)n_{Fe}=\dfrac{m}{M}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
\(n_{O_2}=\dfrac{V}{22,4}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
\(\text{Ta thấy }O_2\text{ dư,}Fe\text{ phản ứng hết}\)
\(c)m_{Fe_3O_4}=n.M=0,1.232=23,2\left(g\right)\)
nFe = 33,6 : 56 = 0,6 (mol)
pthh : 3Fe + 2O2 -t--> Fe3O4
0,6--> 0,4------->0,2 (mol)
=> vO2 = 0,4.22,4 = 8,96 (mol)
=> mFe3O4 = 0,2.232 = 46,4 (g)
pthh : 2KClO3 -t--> 2KClO3 + 3O2
0,267<-----------------------0,4(mol)
mKClO3= 0,267 .122,5 = 32,67 (g)
a, \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, Ta có: \(n_{Fe}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=0,6\left(mol\right)\Rightarrow V_{O_2}=0,6.22,4=13,44\left(l\right)\)
c, \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,3\left(mol\right)\Rightarrow m_{Fe_3O_4}=0,3.232=69,6\left(g\right)\)
d, \(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
Theo PT: \(n_{KClO_3}=\dfrac{2}{3}n_{O_2}=0,4\left(mol\right)\Rightarrow m_{KClO_3}=0,4.122,5=49\left(g\right)\)
\(n_{Fe}=\dfrac{m}{M}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
\(a.PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
3 2 1
0,9 0,6 0,3
\(b.V_{O_2}=n.24,79=0,6.24,79=14,874\left(l\right)\)
\(c.m_{Fe_3O_4}=n.M=0,3.\left(56.3+16.4\right)=69,6\left(g\right)\)
\(d.V_{O_2}=14,874\left(l\right)\\ \Rightarrow n_{O_2}=\dfrac{V}{24,79}=\dfrac{14,874}{24,79}=0,6\left(mol\right)\\ PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
2 2 3
0,6 0,6 0,9
\(m_{KClO_3}=n.M=0,6.\left(39+35,5+16.3\right)=55,5\left(g\right).\)
a. \(n_{Fe}=\dfrac{8.4}{56}=0,15\left(mol\right)\)
\(n_{O_2}=\dfrac{1.12}{22,4}=0,05\left(mol\right)\)
PTHH : 3Fe + 2O2 -to> Fe3O4
0,075 0,05 0,025
Xét tỉ lệ \(\dfrac{0.15}{3}>\dfrac{0.05}{2}\) => Fe dư , O2 đủ
\(m_{Fe_3O_4}=0,025.232=5,8\left(g\right)\)
b. \(m_{Fe\left(dư\right)}=\left(0,15-0,075\right).56=4,2\left(g\right)\)
\(n_{Fe}=\dfrac{3,36}{56}=0,06mol\)
\(n_{O_2}=\dfrac{11,2}{22,4}=0,5mol\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
0,06 < 0,5 ( mol )
0,06 0,04 0,02 ( mol )
Chất dư là O2
\(m_{O_2\left(dư\right)}=\left(0,5-0,04\right).32=14,72g\)
\(m_{Fe_3O_4}=0,02.232=4,64g\)