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a) \(n_{HCl}=0,1.2=0,2\left(mol\right)\)
PTHH: CuO + 2HCl --> CuCl2 + H2O
______0,1<---0,2------->0,1
=> a = 0,1.80 = 8(g)
b) \(C_{M\left(CuCl_2\right)}=\dfrac{0,1}{0,1}=1M\)
c)
PTHH: CuCl2 + 2NaOH --> Cu(OH)2 + 2NaCl
______0,1------------------------>0,1
=> mCu(OH)2 = 0,1.98 = 9,8(g)
\(a)n_{NaOH}=0,5.0,2=0,1mol\\ n_{H_2SO_4}=0,3.1=0,3mol\\2 NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\\ \Rightarrow\dfrac{0,1}{2}< \dfrac{0,3}{1}\Rightarrow H_2SO_4.dư\\ 2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
0,1 0,05 0,05 0,1
\(C_M\) \(_{Na_2SO_4}=\dfrac{0,05}{0,2+0,3}=0,1M\)
\(C_M\) \(_{H_2SO_4}=\dfrac{0,3-0,05}{0,2+0,3}=0,5M\)
b) Vì H2SO4 dư nên quỳ tím hoá đỏ.
\(n_{H_2SO_4}=1.0,2=0,2(mol)\\ H_2SO_4+BaCl_2\to BaSO_4\downarrow+2HCl\\ \Rightarrow n_{BaSO_4}=n_{BaCl_2}=0,2(mol)\\ a,m_{BaSO_4}=0,2.233=46,6(g)\\ b,V_{dd_{BaCl_2}}=\dfrac{0,2}{1,5}\approx 0,13(l)\\ c,n_{HCl}=0,4(mol)\\ \Rightarrow C_{M_{HCl}}=\dfrac{0,4}{0,2+0,13}\approx 1,21M\)
\(d,\) Dd sau p/ứ là HCl nên làm quỳ tím hóa đỏ
\(n_{H_2SO_4}=0,2.1=0,2\left(mol\right)\\ H_2SO_4+BaCl_2\rightarrow BaSO_4+2HCl\\ n_{BaCl_2}=n_{BaSO_4}=n_{H_2SO_4}=0,2\left(mol\right)\\ n_{HCl}=2.0,2=0,4\left(mol\right)\\ a,m_{\downarrow}=m_{BaSO_4}=0,2.233=46,6\left(g\right)\\ b,V_{\text{dd}BaCl_2}=\dfrac{0,2}{1,5}=\dfrac{2}{15}\left(l\right)\\ c,C_{M\text{dd}HCl}=\dfrac{0,4}{\dfrac{2}{15}+0,2}=1,2\left(M\right)\\ d,V\text{ì}.c\text{ó}.\text{dd}.HCl\Rightarrow Qu\text{ỳ}.ho\text{á}.\text{đ}\text{ỏ}\)
PTHH: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
Ta có: \(n_{KOH}=0,2\cdot0,5=0,1\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4}=n_{K_2SO_4}=0,05\left(mol\right)\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{H_2SO_4}}=\dfrac{0,05}{0,1}=0,5\left(M\right)\\C_{M_{K_2SO_4}}=\dfrac{0,05}{0,2+0,1}\approx0,17\left(M\right)\end{matrix}\right.\)
Bài 1 :
200ml = 0,2l
100ml = 0,1l
\(n_{KOH}=0,5.0,2=0,1\left(mol\right)\)
a) Pt : \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O|\)
2 1 1 2
0,1 0,05 0,05
b) \(n_{H2SO4}=\dfrac{0,1.1}{2}=0,05\left(mol\right)\)
\(C_{M_{ddH2SO4}}=\dfrac{0,05}{0,1}=0,5\left(M\right)\)
c) \(n_{K2SO4}=\dfrac{0,05.1}{1}=0,05\left(mol\right)\)
\(V_{ddspu}=0,2+0,1=0,3\left(l\right)\)
\(C_{M_{K2SO4}}=\dfrac{0,05}{0,3}=\dfrac{1}{6}\left(M\right)\)
Chúc bạn học tốt
\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+H_2O\)
\(a\) \(2a\)
\(H_2SO_4+2KOH\rightarrow K_2SO_4+H_2O\)
\(b\) \(2b\)
Sau pư (1) đổi màu quỳ tìm \(\Rightarrow H_2SO_4\) dư \(n_{KON}=0,02.0,5=0,01\left(mol\right)\)
\(\rightarrow n_{H_2SO_4dư}=\frac{1}{2}n_{KOU}=5.10^{-3}\left(MOL\right)\)
\(\rightarrow n_{H_2O_4\text{ban đầu }}=0,05.1=0,05\left(mol\right)\)
\(\rightarrow n_{H_2SO_4\left(\text{pư 1 }\right)}=0,05-5.10^{-3}=0,045\left(mol\right)\)
\(\rightarrow n_{NaOH}=0,045.2=0,09\left(mol\right)\)
\(\rightarrow CM_{NaOH}=\frac{0,09}{0,05}=1,8\left(M\right)\)
a, \(H_2SO_4+2KOH\rightarrow K_2SO_4+2H_2O\)
b, \(n_{KOH}=0,12.0,4=0,048\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=\dfrac{1}{2}n_{KOH}=0,024\left(mol\right)\)
\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,024}{0,08}=0,3\left(M\right)\)
c, \(n_{K_2SO_4}=\dfrac{1}{2}n_{KOH}=0,024\left(mol\right)\)
\(\Rightarrow C_{M_{K_2SO_4}}=\dfrac{0,024}{0,08+0,12}=0,12\left(M\right)\)
PTHH: \(Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{Ba\left(OH\right)_2}=0,05\cdot0,5=0,025\left(mol\right)\\n_{HCl}=0,15\cdot0,1=0,015\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,025}{1}>\dfrac{0,015}{2}\) \(\Rightarrow\) Ba(OH)2 còn dư, dd sau p/ứ có tính kiềm
\(\Rightarrow\left\{{}\begin{matrix}n_{BaCl_2}=0,0075\left(mol\right)\\n_{Ba\left(OH\right)_2\left(dư\right)}=0,0175\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{BaCl_2}}=\dfrac{0,0075}{0,05+0,15}=0,0375\left(M\right)\\C_{M_{Ba\left(OH\right)_2}}=\dfrac{0,0175}{0,2}=0,0875\left(M\right)\end{matrix}\right.\)