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a,\(n_{Na_2O}=\dfrac{15,5}{62}=0,25\left(mol\right)\)
PTHH: Na2O + H2O → 2NaOH
Mol: 0,25 0,5
\(C_{M_{ddNaOH}}=\dfrac{0,5}{0,5}=1M\)
b, PTHH: 2NaOH + H2SO4 → Na2SO4 + 2H2O
Mol: 0,5 0,25 0,25
\(m_{ddH_2SO_4}=\dfrac{0,2.98.100\%}{20\%}=98\left(g\right)\)
\(V_{ddH_2SO_4}=\dfrac{98}{1,14}=85,96\left(ml\right)\)
c,Vdd sau pứ = 0,5 + 0,08596 = 0,58596 (l)
\(C_M=\dfrac{0,25}{0,58596}=0,427M\)
\(a) n_{Fe_2O_3} = \dfrac{8}{160} = 0,05(mol)\\ Fe_2O_3 + 6HCl \to 2FeCl_3 + 3H_2O\\ n_{FeCl_3} = 2n_{Fe_2O_3} = 0,1(mol)\\ m_{FeCl_3} = 0,1.162,5 = 16,25(gam)\\ b) n_{HCl} = 6n_{Fe_2O_3} = 0,05.6 = 0,3(mol)\\ V_{dd\ HCl} = \dfrac{0,3}{0,5} = 0,6(lít)\\ c) C_{M_{FeCl_3}} = \dfrac{0,1}{0,5} = 0,2M\)
\(n_{H_2}=0,6\left(mol\right)\\ Đặt:a=n_{Mg}\left(mol\right);b=n_{Zn}\left(mol\right)\left(a,b>0\right)\\ PTHH:Mg+H_2SO_4\rightarrow MgSO_4+H_2\\ Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ \Rightarrow\left\{{}\begin{matrix}24a+65b=18,5\\a+b=0,6\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,5\\b=0,1\end{matrix}\right.\\ a,\Rightarrow m_{Mg}=0,5.24=12\left(g\right);m_{Zn}=0,1.65=6,5\left(g\right)\\ b,\%,m_{Mg}=\dfrac{12}{18,5}.100\approx64,865\%\Rightarrow\%m_{Zn}\approx35,135\%\\ c,n_{H_2SO_4}=n_{H_2}=0,6\left(mol\right)\\ \Rightarrow C_{MddH_2SO_4}=\dfrac{0,6}{0,245}=\dfrac{120}{49}\left(M\right)\\ d,m_{MgSO_4}=120a=120.0,5=60\left(g\right)\\ m_{ZnSO_4}=161b=161.0,1=16,1\left(g\right)\)
e) Câu e cho thêm cái D nữa nha em!
- Thấy Cu không phản ứng với HCl .
\(\Rightarrow m_{cr}=m_{Cu}=6,4\left(g\right)\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
.x.......................................1,5x.........
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
.y....................................y.............
Theo bài ra ta có hệ : \(\left\{{}\begin{matrix}27x+56y+6,4=17,4\\1,5x+y=0,4\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\) ( mol )
\(\Rightarrow\left\{{}\begin{matrix}m_{Al}=5,4\\m_{Fe}=5,6\end{matrix}\right.\) ( g )
b, \(FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_2+2NaCl\)
.......0,1.........0,2...............................
\(AlCl_3+3NaOH\rightarrow Al\left(OH\right)_3+3NaCl\)
...0,2.......0,6..........................
\(\Rightarrow n_{NaOH}=0,2+0,6=0,8< 1\)
=> Trong B còn có HCl dư .
\(NaOH+HCl\rightarrow NaCl+H_2O\)
...0,2..........0,2....................
=> Dư 0,2 mol HCl .
\(\Rightarrow n_{HCl}=2n_{H_2}+0,2=1\left(mol\right)\)
\(\Rightarrow m_{ddB}=17,4+250-6,4-0,8=260,2\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{HCl}=\dfrac{0,2.36,5}{260,2}.100\%\approx2,8\%\\C\%_{FeCl_2}\approx4,88\%\\C\%_{AlCl_3}\approx10,26\%\end{matrix}\right.\)
Vậy ....
\(a.n_{CaCl_2}=0,1\left(mol\right)\\ CaCl_2+2AgNO_3\rightarrow Ca\left(NO_3\right)_2+2AgCl\\ n_{AgCl}=2n_{CaCl_2}=0,2\left(mol\right)\\ \Rightarrow m_{AgCl}=0,2.143,5=28,7\left(g\right)\\ b.n_{Ca\left(NO_3\right)_2}=n_{CaCl_2}=0,1\left(mol\right)\\ \Rightarrow CM_{CaCl_2}=\dfrac{0,1}{0,1}=1M\)
a) CaCO3 + 2HCl --> CaCl2 + CO2 + H2O
b) \(n_{CaCO_3}=\dfrac{10}{100}=0,1\left(mol\right)\)
CaCO3 + 2HCl --> CaCl2 + CO2 + H2O
_0,1---->0,2------->0,1----->0,1
=> mCaCl2 = 0,1.111 = 11,1 (g)
=> VCO2 = 0,1.22,4 = 2,24 (l)
c) \(a=C_{M\left(HCl\right)}=\dfrac{0,2}{0,4}=0,5M\)
d) \(C_{M\left(CaCl_2\right)}=\dfrac{0,1}{0,4}=0,25M\)
a) Na2SO3 + 2HCl --> 2NaCl + SO2 + H2O
b) nHCl = 0,2.1 = 0,2 (mol)
Na2SO3 + 2HCl --> 2NaCl + SO2 + H2O
_0,1<------0,2------->0,2----->0,1
mNaCl = 0,2.58,5 = 11,7(g)
VSO2 = 0,1.22,4 = 2,24 (l)
c) mNa2SO3 = 0,1.126 = 12,6 (g)
d) \(C_{M\left(NaCl\right)}=\dfrac{0,2}{0,2}=1M\)
a ,
Na2O + H2O -> 2NaOH
0,05.......................0,1 (mol)
b ,nNa2O = 0,05 (mol)
A là bazo
CM (A) = 0,1/1=0,1 (M)
c, 2NaOH + H2SO4 -> Na2SO4 + 2H2O
0,1............0,05 (mol)
m dung dịch H2SO4 = \(\frac{0,05.98}{9,6\%}\approx51,042\left(g\right)\)
V = \(\frac{51,042}{1,05}\approx48,61\left(ml\right)\)
NaBr + AgNO3 \(\rightarrow\)AgBr + NaNO3
NaCl + AgNO3 \(\rightarrow\) AgCl + NaNO3
\(C_M=0,5M\Rightarrow n_{AgNO_3}=0,025\left(mol\right)\)
Gọi x, y lần lượt là số mol NaBr và NaCl
Ta có : x + y = 0,025
103x - 58,5y = 0
\(\Rightarrow x=9,0557.10^{-3};y=0,01594\)
\(\Rightarrow C\%=\frac{0,594.58,5}{50}.100\%=1,865\%\)
NaBr + AgNO3 →→AgBr + NaNO3
NaCl + AgNO3 →→ AgCl + NaNO3
CM=0,5M⇒nAgNO3=0,025(mol)CM=0,5M⇒nAgNO3=0,025(mol)
Gọi x, y lần lượt là số mol NaBr và NaCl
Ta có : x + y = 0,025
103x - 58,5y = 0
⇒x=9,0557.10−3;y=0,01594⇒x=9,0557.10−3;y=0,01594
⇒C%=0,594.58,550.100%=1,865%⇒C%=0,594.58,550.100%=1,865%
Na2O +H2O\(\rightarrow\) 2NaOH
0,5________________1
nNa2O=\(\frac{31}{\text{23.2+16}}\)=0,5mol
500ml=0,5lit
CM NaOH=\(\frac{1}{0,5}\)=2M
2NaOH +H2SO4 \(\rightarrow\)Na2SO4 +2H2O
1__________0,5____0,5
mH2SO4=n.M=0,5.(2+32+16.4)=49g
C%H2SO4=m/mdd. 100
\(\rightarrow\) 20=\(\frac{49}{mdd}\).100
\(\Leftrightarrow\)mddH2SO4=245g
Ta có mddH2SO4=Vdd. D
\(\Leftrightarrow\)245=Vdd.1,14
\(\Leftrightarrow\)VddH2SO4=215ml
215ml=0,215lit
CM Na2SO4=\(\frac{0,5}{0,215}\)=2,3M