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nH2=0.56:22,4=0,025 mol
Fe+H2SO4----->FeSO4+H2
2AL+3H2SO4----->AL2(SO4)3 +3H2
Gọi x,y làn lượt là số mol Fe và AL
ta có hệ pt
mFe=0,01.56=0,56 g
mAl=0,83-0,56=0,27 g
%mFe=(0,56:0,83).100=67,47%
%mAl=100-67,47=32,53%
a) Gọi `n_{Al} = a (mol); n_{Fe} = b (mol)`
PTHH:
`2Al + 3H_2SO_4 -> Al_2(SO_4)_3 + 3H_2`
`Fe + H_2SO_4 -> FeSO_4 + H_`
b) `n_{H_2} = (0,56)/(22,4) = 0,025 (mol)`
Theo PT: `n_{H_2} = n_{Fe} + 3/2 n_{Al}`
`=> b + 1,5a = 0,025`
Giải hpt \(\left\{{}\begin{matrix}27a+56b=0,83\\1,5a+b=0,025\end{matrix}\right.\Leftrightarrow a=b=0,01\)
=> \(\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,01.27}{0,83}.100\%=32,53\%\\\%m_{Fe}=100\%-32,53\%=67,47\%\end{matrix}\right.\)
\(\text{Đặt }\left\{{}\begin{matrix}n_{Al}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\\ n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ a,PTHH:\left\{{}\begin{matrix}2Al+6HCl\rightarrow2AlCl_3+3H_2\\Fe+2HCl\rightarrow FeCl_2+H_2\end{matrix}\right.\\ b,\text{Theo đề ta có HPT: }\left\{{}\begin{matrix}27x+56y=8,3\\\dfrac{3}{2}x+y=0,25\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,1\left(mol\right)\\y=0,1\left(mol\right)\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}\%_{Al}=\dfrac{0,1\cdot27}{8,3}\approx32,53\%\\\%_{Fe}\approx67,47\%\end{matrix}\right.\)
\(c,\left\{{}\begin{matrix}n_{AlCl_3}=0,1\left(mol\right)\\n_{FeCl_2}=0,1\left(mol\right)\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}m_{AlCl_3}=0,1\cdot133,5=13,35\left(g\right)\\m_{FeCl_2}=0,1\cdot127=12,7\left(g\right)\end{matrix}\right.\\ \Rightarrow\sum m_{muối}=13,35+12,7=26,05\left(g\right)\)
a, PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
b, Giả sử: \(\left\{{}\begin{matrix}n_{Al}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow27x+56y=16,6\left(1\right)\)
Ta có: \(n_{H_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
Theo PT: \(\Sigma n_{H_2}=\dfrac{3}{2}n_{Al}+n_{Fe}=\dfrac{3}{2}x+y\left(mol\right)\)
\(\Rightarrow\dfrac{3}{2}x+y=0,05\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=\\y=\end{matrix}\right.\)
Tới đây ra số mol âm, bạn xem lại đề nhé!
nH2=0.56:22,4=0,025 mol
Fe+H2SO4----->FeSO4+H2
2AL+3H2SO4----->AL2(SO4)3 +3H2
Gọi x,y làn lượt là số mol Fe và AL
ta có hệ pt
\(\begin{cases}56x+27y=0,83\\x+1,5y=0,025\end{cases}\)
\(\begin{cases}x=0,01mol\\y=0,01mol\end{cases}\)
mFe=0,01.56=0,56 g
mAl=0,83-0,56=0,27 g
%mFe=(0,56:0,83).100=67,47%
%mAl=100-67,47=32,53%
a)
$2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$
$Fe + H_2SO_4 \to FeSO_4 + H_2$
b)
Gọi $n_{Al} = a(mol) ; n_{Fe} = b(mol) \Rightarrow 27a + 56b = 0,83(1)$
Theo PTHH : $n_{H_2} = 1,5a + b = \dfrac{0,56}{22,4} = 0,025(2)$
Từ (1)(2) suy ra : a = 0,01; b = 0,01
$\%m_{Al} = \dfrac{0,01.27}{0,84}.100\% = 32,1\%$
$\%m_{Fe} = 100\% - 32,1\% = 67,9\%$
\(n_{H_2}=\dfrac{0,56}{22,4}=0,025(mol)\\ n_{Fe}=x(mol);n_{Al}=y(mol)\\ \Rightarrow 56x+27y=0,83(1)\\ Fe+H_2SO_4\to FeSO_4+H_2\\ 2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\\ \Rightarrow x+1,5y=0,025(2)\\ (1)(2)\Rightarrow \begin{cases} x=0,01(mol)\\ y=0,01(mol) \end{cases}\Rightarrow \begin{cases} \%_{Fe}=\dfrac{0,01.56}{0,83}.100\%=67,47\%\\ \%_{Al}=100\%-67,47\%=32,53\% \end{cases}\)
Đặt : \(n_{Al}=a\left(mol\right),n_{Fe}=b\left(mol\right)\)
\(m_{hh}=27a+56b=6.95\left(g\right)\left(1\right)\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(n_{H_2}=1.5a+b=\dfrac{3.92}{22.4}=0.175\left(mol\right)\left(2\right)\)
\(\left(1\right),\left(2\right):a=0.05,b=0.1\)
\(\%Al=\dfrac{0.05\cdot27}{6.95}\cdot100\%=19.42\%\)
\(\%Fe=100-19.42=80.58\%\)
\(n_{H_2}=\dfrac{3,92}{22,4}=0,175(mol)\\ a,PTHH:2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\\ Fe+H_2SO_4\to FeSO_4+H_2\\b,n_{Al}=x(mol);n_{Fe}=y(mol)\\ \Rightarrow 27x+56y=6,95;1,5x+y=0,175\\ \Rightarrow x=0,05(mol);y=0,1(mol)\\ \Rightarrow \%_{Al}=\dfrac{0,05.27}{6,95}.100\%=19,42\%\\ \Rightarrow \%_{Fe}=100\%-19,42\%=80,58\% \)