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\(n_{C_2H_2}=\dfrac{6.72}{22.4}=0.3\left(mol\right)\)
\(n_{O_2}=\dfrac{11.2}{22.4}=0.5\left(mol\right)\)
\(C_2H_2+\dfrac{5}{2}O_2\underrightarrow{t^0}2CO_2+H_2O\)
\(Bđ:0.3.......0.5\)
\(Pư:0.2........0.5.........0.4.........0.2\)
\(Kt:0.1..........0..........0.4...........0.2\)
\(V_{CO_2}=0.4\cdot22.4=8.96\left(l\right)\)
\(V_{C_2H_2\left(dư\right)}=0.1\cdot22.4=2.24\left(l\right)\)
a) \(n_P=\dfrac{18,6}{31}=0,6\left(mol\right)\)
\(n_{O_2}=\dfrac{33,6}{22,4}.\dfrac{1}{5}=0,3\left(mol\right)\)
PTHH: 4P + 5O2 --to--> 2P2O5
Xét tỉ lệ: \(\dfrac{0,6}{4}>\dfrac{0,3}{5}\) => P dư, O2 hết
PTHH: 4P + 5O2 --to--> 2P2O5
0,24<-0,3-------->0,12
=> mP(dư) = (0,6 - 0,24).31 = 11,16 (g)
b) mP2O5 = 0,12.142 = 17,04 (g)
nP = 18,6 : 0,6 (mol)
nO2 = (33,6 : 22,4 ) . 21% = 0,315 (mol)
pthh : 4P +5O2 -t-> 2P2O5
LTL :
0,6 / 4 < 0,315 / 5
=> P dư
nP (pư) = nO2 = 0,315 (mol)
nP(d) = nP(bđ) - nP (pư) = 0,6 - 0,315 = 0,285 (mol)
=> mP (dư ) = 0,285 . 31 = 8,935 (g)
theo pthh nP2O5 = 2/5 nO2 = 0,126 ( mol)
=> mP2O5 = 0,126 . 142 = 17,892 (g)
Cảm ơn bạn @anayuiky đã nhắc lỗi sai. Mình sửa lại ý c):
PTHH: \(2KMnO_4\rightarrow^{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
Theo phương trình \(n_{KMnO_4}=n_{O_2}.2=0,25.2=0,5mol\)
\(\rightarrow m_{KMnO_4}=0,5.\left(39+55+16.4\right)=79g\)
a. \(n_{H_2}=\frac{V}{22,4}=\frac{11,2}{22,4}=0,5mol\)
\(n_{O_2}=\frac{V}{22,4}=\frac{10,08}{22,4}=0,45mol\)
PTHH: \(2H_2+O_2\rightarrow^{t^o}2H_2O\)
Ban đầu: 0,5 0,45 mol
Trong pứng: 0,5 0,25 0,5 mol
Sau pứng: 0 0,2 0,5 mol
\(\rightarrow M_{O_2\left(dư\right)}=n.M=0,2.32=6,4g\)
b. Theo phương trình \(n_{H_2O}=n_{H_2}=0,5mol\)
\(\rightarrow m_{H_2O}=n.M=0,5.18=9g\)
c. PTHH: \(2KMnO_4\rightarrow^{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
0,9 0,45 mol
\(\rightarrow n_{KMnO_4}=\frac{2}{1}n_{O_2}=\frac{0,45.2}{1}=0,9mol\)
\(\rightarrow m_{KMnO_4}=n.M=0,9.158=142,2g\)
a) \(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
\(n_{O_2}=\dfrac{10,08}{22,4}=0,45\left(mol\right)\)
PTHH: 2H2 + O2 --to--> 2H2O
Xét tỉ lệ: \(\dfrac{0,5}{2}< \dfrac{0,45}{1}\) => H2 hết, O2 dư
PTHH: 2H2 + O2 --to--> 2H2O
0,5-->0,25----->0,5
=> \(m_{O_2\left(dư\right)}=\left(0,45-0,25\right).32=6,4\left(g\right)\)
b) \(m_{H_2O}=0,5.18=9\left(g\right)\)
c)
PTHH: 2KMnO4 --to--> K2MnO4 + MnO2 + O2
0,5<-----------------------------------0,25
=> \(m_{KMnO_4}=0,5.158=79\left(g\right)\)
\(n_{H_2}=\dfrac{V_{H_2}}{22,4}=\dfrac{2,4}{22,4}\approx0,11\left(mol\right)\)
\(n_{O_2}=\dfrac{V_{O_2}}{22,4}=\dfrac{1,6}{22,4}\approx0,07\)
\(2H_2+O_2\rightarrow2H_2O\)
2 mol-1mol---2 mol
Ta có: \(\dfrac{n_{H_2}}{2}=\dfrac{0,11}{2}\)
\(\dfrac{n_{O_2}}{1}=\dfrac{0,07}{1}\)
\(\Rightarrow\dfrac{n_{H_2}}{2}< \dfrac{n_{O_2}}{1}\)
Vậy \(O_2\) dư
Số mol O2 dư:
\(n_{O_2}=\dfrac{0,07.1}{2}=0,035\left(mol\right)\)
Khối lượng O2 dư
\(m_{O_2}=0,035.32=1,12\left(g\right)\)
Khối lượng nước thu được:
\(n_{H_2O}=\dfrac{0,07.2}{2}=0,07\left(mol\right)\)
\(\Rightarrow m_{H_2O}=n_{H_2O}.M_{H_2O}=0,07.18=1,26\left(g\right)\)
a, Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
\(n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PT: \(2H_2+O_2\underrightarrow{t^o}2H_2O\)
Xét tỉ lệ: \(\dfrac{0,3}{2}< \dfrac{0,2}{1}\), ta được O2 dư.
Theo PT: \(n_{O_2\left(pư\right)}=\dfrac{1}{2}n_{H_2}=0,15\left(mol\right)\)
\(\Rightarrow n_{O_2\left(dư\right)}=0,05\left(mol\right)\Rightarrow m_{O_2\left(dư\right)}=0,05.32=1,6\left(g\right)\)
b, \(n_{H_2O}=n_{H_2}=0,3\left(mol\right)\)
\(\Rightarrow m_{H_2O}=0,3.18=5,4\left(g\right)\)
c, PT: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
_______0,3_______________________0,15 (mol)
\(\Rightarrow m_{KMnO_4}=0,3.158=47,4\left(g\right)\)
Bạn tham khảo nhé!
\(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\\ n_{O_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ PTHH:4P+5O_2\underrightarrow{t^o}2P_2O_5\\ LTL:\dfrac{0,2}{4}< \dfrac{0,4}{5}\Rightarrow O_2dư\)
\(n_{O_2\left(pư\right)}=\dfrac{5}{4}n_P=\dfrac{5}{4}.0,2=0,25\left(mol\right)\\ n_{O_2\left(dư\right)}=0,4-0,25=0,15\left(mol\right)\)
\(n_{P_2O_5\left(lt\right)}=\dfrac{1}{2}n_P=\dfrac{1}{2}.0,2=0,1\left(mol\right)\\ m_{P_2O_5\left(lt\right)}=0,1.142=14,2\left(g\right)\\ m_{P_2O_5\left(tt\right)}=0,1.142.80\%=11,36\left(g\right)\)
a, PTHH: S + O2 -> (t°) SO2
b, nS = 6,4/32 = 0,2 (mol)
nO2 = 6,72/22,4 = 0,3 (mol)
LTL: 0,2 < 0,3 => O2 dư
nO2 (pư) = nSO2 = nS = 0,2 (mol)
mO2 (dư) = (0,3 - 0,2) . 32 = 3,2 (g)
c, mSO2 = 64 . 0,2 = 12,8 (g)
a, \(S+O_2\underrightarrow{t^o}SO_2\)
\(nS=\dfrac{6,4}{32}=0,2\left(mol\right)\)
\(nO_2=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
\(\dfrac{0,2}{1}< \dfrac{0,3}{1}\) => oxi dư
\(nO_{2\left(dư\right)}=0,1\left(mol\right)\)
\(mO_{2\left(dư\right)}=0,1.32=3,2\left(g\right)\)
\(nSO_2=nS=0,2\left(mol\right)\)
\(mSO_2=0,2.64=12,8\left(g\right)\)
\(n_{H_2}=\dfrac{33,6}{22,4}=1,5\left(mol\right)\\ n_{O_2}=\dfrac{33,6}{22,4}=1,5\left(mol\right)\)
PTHH: 2H2 + O2 --to--> 2H2O
LTL: \(\dfrac{1,5}{2}< 1,5\rightarrow O_2\) dư
Theo pt: \(\left\{{}\begin{matrix}n_{O_2\left(pư\right)}=\dfrac{1}{2}n_{H_2}=\dfrac{1}{2}.1,5=0,75\left(mol\right)\\n_{H_2O}=n_{H_2}=1,5\left(mol\right)\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}m_{O_2\left(dư\right)}=\left(1,5-0,75\right).32=24\left(g\right)\\V_{O_2}\left(1,5-0,75\right).22,4=16,8\left(l\right)\\m_{H_2O}=1,5.18=27\left(g\right)\end{matrix}\right.\)
\(n_{H_2}=n_{O_2}=\dfrac{33,6}{22,4}=1,5\left(MOL\right)\)
pthh: \(2H_2+O_2\underrightarrow{t^O}2H_2O\)
LTL : \(\dfrac{1,5}{2}< \dfrac{1,5}{1}\)
=> O2 dư , H2 hết
theo pthh: nH2O = nH2 = 1,5 (mol)
=> \(m_{H_2O}=1,5.18=27\left(g\right)\)